Metal Speciation and Contamination of Soil

Metal Speciation and Contamination of Soil PDF

Author: Herbert E. Allen

Publisher: CRC Press

Published: 1994-11-29

Total Pages: 384

ISBN-13: 9780873716970

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Metal Speciation and Contamination of Soil provides a thorough overview of the biogeochemical processes governing the behavior, transport, and bioavailability of heavy metals in contaminated soils and suggests alternative approaches for effective remediation. This important new book contains contributions from experts in various disciplines who explore the issues from theoretical, experimental, and pragmatic perspectives. Topics include redox chemistry, kinetics of metal reactions, spectroscopic characterization of metal ion reactions at surface, modeling hydrologic transport phenomena and colloid-associated transport of metals through the soil profile to ground water, and remediation alternatives.

The Importance of Chemical “Speciation” in Environmental Processes

The Importance of Chemical “Speciation” in Environmental Processes PDF

Author: M. Bernhard

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 758

ISBN-13: 3642704417

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Report, the editors replaced the term "speciation" wherever it occurred by "identification and quantification," or "description of abundance," or "reactivity," or "transformation" of a chemical species, according to whichever one of the four meanings the author had evidently meant to convey. In line with the Dahlem Workshop Model, this Report comprises the background papers written in advance of the meeting on the current status of problems in environmental research and on advanced analytical tech niques for the identification and quantification of chemical species, as well as the group reports summarizing the results of the discussions held during the meeting. Each group report was prepared during the meeting by one "rapporteur" with the help of members of that group and finalized by the rapporteur (listed as the first author of the group report) after the meeting, taking into account both verbal comments made during the presentation of the reports in the plenary session at the end of the workshop and written comments received afterwards.

Heavy Metals Release in Soils

Heavy Metals Release in Soils PDF

Author: H. Magdi Selim

Publisher: CRC Press

Published: 2001-06-15

Total Pages: 266

ISBN-13: 9781420032611

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Understanding the mechanisms associated with metal complexes and the sequestering metal contaminants in the environment is essential for effective remediation. Heavy Metal Release in Soils describes and quantifies desorption/release kinetics and dissolution reactions in the release of heavy metals from soil. The book focuses on: New techniques - microscopic surface techniques, NMR and electrophoresis, XAFS, SFM, and time-resolved ATR-FTIR Theoretical analysis and kinetic approaches - adsorption/desorption hysteresis, competitive sorption and transport, multi-component models, speciation kinetics, isotherms and soil and metal parameters, and the role of soil properties on transport Applications - arsenic speciation and mobility in contaminated soils, modeling activity of CD, Zn, and Cu in contaminated soils, and in situ chemical immobilization A timely addition to the literature, this book highlights the desorption/release mechanisms for the purpose of resolving remediation dilemmas in contaminated environments. It gives you the added advantage of case studies at both the microscopic and macroscopic scales, and provides both experimental and numerical investigations. With contributions from an international panel of authors, Heavy Metals Release in Soils fills a gap in the current literature concerned with subsurface contaminant fate and transport processes.

Heavy Metals

Heavy Metals PDF

Author: Wim Salomons

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 409

ISBN-13: 3642793169

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"Heavy Metals: Problems and Solutions" is divided into three sections dealing with basic geochemical processes, remediation and case studies. The basic geochemical processes are discussed with respect to mobility in the environment and impact as well as methods to derive guidelines for heavy metals. Remediation focuses on currently available methods to treat contaminated sediments and soils. In addition, it considers the concept of geochemical engineering for remediation of large areas contaminated by metals. A number of case studies of polluted sediments and soils and their environmental impact highlight the principles discussed in the first two sections.

Effects of Accumulation of Air Pollutants in Forest Ecosystems

Effects of Accumulation of Air Pollutants in Forest Ecosystems PDF

Author: B. Ulrich

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 383

ISBN-13: 940096983X

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This volume is based on a workshop on "Effects of accumulation of air pollutants in forest ecosystems'; held in GOttingen, Federal Republic of Germany, from May 16-18, 1982. This work'shop was initiated and sponsored by the Environmental Agency of the Federal Republic of Germany (project officer: Dr. J. Pankrath) as part of a research contract (project leader: Dr. B. Ulrich). THE PROBLEM SEEN UNDER THE ASPECT OF ADMINISTRATION The problem of forest damage caused by air pollution is not new in Europe. Already in 1983 a comprehensive report from Schroeder and Reuss about vegetation damages by fume in the Harz mountains was published. In 1923, Prof. Dr. Julius Stocklasa of the Bohemian Technical Highschool in Prague was concerned with research of toxical effects of sulphur dioxide in his publication "The damage of vegetation by flue gas and exhalations of facili ties". This comprehensive and instructive work concludes with the sentence: "It is already high time for the governments of all cultural states to take legal, police and private measures in order to prevent damage by flue gases". In the neighbourhood of industries with high gaseous and dust emissions damages have been shown to occur for a long timei these deleterious effects have influenced the growth of trees and in extreme cases have even caused their early death.

Mineral-water Interfacial Reactions

Mineral-water Interfacial Reactions PDF

Author: Donald L. Sparks

Publisher:

Published: 1998

Total Pages: 460

ISBN-13:

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Clearly explains how to more effectively decipher and predict contaminant fate in the environment by combining kinetic methods and molecular-scale spectroscopic and microscopic techniques to analyze mineral/water interfacial reactions in situ. The book begins with a broad overview, then continues with three sections written by internationally known expert. The first deals specifically with spectroscopic/microscopic techniques that can be used in combination with macroscopic approaches to glean mechanistic information on mineral/water reactions and processes. The second section emphasizes computer models that are used to elucidate surface mediated reaction mechanisms. The remainder of the volume is organized around reaction type, including sorption/desorption of inorganic species, sorption/desorption of organic species, precipitation/dissolution processes, heterogeneous electron transfer reactions, photochemically driven reactions, and microbially mediated reactions. Mineral-Water Interfacial Reactions will be a valuable resource for environmental scientists, geochemists, soil chemists, microbiologists, and marine engineers who need to be familiar with the most current and effective methods for testing and controlling the mobility, speciation, and bioavailability of contaminants in the environment.

Chemistry of Marine Water and Sediments

Chemistry of Marine Water and Sediments PDF

Author: Antonio Gianguzza

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 513

ISBN-13: 366204935X

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The most important processes on the Earth`s surface occur in the Ocean where materials and energy are primarily exchanged. In the case of marine chemistry different fields of chemistry from organic to inorganic as well as thermodynamics and biochemistry are involved. Analytical Chemistry is a very important tool for the quantification of biogeochemical processes by providing correct and even more sophisticated methodologies. These are often directly applied 'in situ', in order to detect trace and ultra-trace natural and anthropogenic substances. Kinetic and thermodynamic studies allow us to establish whether the process occurs. Once discovered it is then possible to build up general models for environmental systems. This book gathers many aspects with the aim of creating a general picture of the chemical processes occurring in the marine environment