Cluster Chemistry

Cluster Chemistry PDF

Author: Guillermo Gonzalez-Moraga

Publisher: Springer Science & Business Media

Published: 2013-11-09

Total Pages: 310

ISBN-13: 3642859267

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Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Transition Metal Carbonyl Cluster Chemistry

Transition Metal Carbonyl Cluster Chemistry PDF

Author: Paul J. Dyson

Publisher: CRC Press

Published: 2018-10-03

Total Pages: 180

ISBN-13: 1482283077

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Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Ligated Transition Metal Clusters in Solid-state Chemistry

Ligated Transition Metal Clusters in Solid-state Chemistry PDF

Author: Jean-François Halet

Publisher: Springer Nature

Published: 2019-08-29

Total Pages: 201

ISBN-13: 3030251241

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This volume dedicated to the memory of Marcel Sergent who was a leader in this field for many years, addresses past achievements and recent developments in this vibrant area of research. Large classes of ligated transition metal clusters are produced either exclusively or most reliably by means of high-temperature solid-state reactions. Among them, the Chevrel-Sergent phases and related materials have generated enormous interest since their discovery in 1971. Today, these materials and their numerous derivatives still constitute a vivid area of research finding some applications not only in superconductivity, but also in catalysis, optics or thermoelectricity to mention a few.

The Chemistry of Metal Cluster Complexes

The Chemistry of Metal Cluster Complexes PDF

Author: Duward F. Shriver

Publisher: Wiley-VCH

Published: 1990

Total Pages: 456

ISBN-13:

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Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR

Progress in the Physics of Clusters

Progress in the Physics of Clusters PDF

Author: Gennady N. Chuev

Publisher: World Scientific

Published: 1999

Total Pages: 524

ISBN-13: 9789810236601

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The findings reported in this book on the methods of cluster measurements will lead to new avenues using nondestructive mass spectrometry and dipole mass isomers. Much attention is given to the physics and chemistry of fullerenes and nanotubes, including the problems surrounding the formation and growth of nanotubes, electron characteristics of fullerenes, the influence of solvents, simulation of the properties of carbon clusters, etc. Some unique experimental data on the conversion of aerosols into aerogels with the formation of fractal structures is provided. In addition, the book covers one of the most interesting subjects of modern physics -- fractal clusters.

Molecular Clusters

Molecular Clusters PDF

Author: Thomas Fehlner

Publisher: Cambridge University Press

Published: 2007-07-05

Total Pages: 388

ISBN-13: 1107320836

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Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.

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