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Thermodynamics of Polymer Blends, Volume I

Author: Anatoly E. Nesterov

Publisher: CRC Press

Published: 2020-02-03

Total Pages: 465

ISBN-13: 1000717666

Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.

Polymer Thermodynamics

Author: Kal Renganathan Sharma

Publisher: CRC Press

Published: 2011-10-10

Total Pages: 371

ISBN-13: 1439826404

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Polymer Thermodynamics: Blends, Copolymers and Reversible Polymerization describes the thermodynamic basis for miscibility as well as the mathematical models used to predict the compositional window of miscibility and construct temperature versus volume-fraction phase diagrams. The book covers the binary interaction model, the solubility parameter

Polymer Blends Volume 1

Author: Donald R Paul

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 520

ISBN-13: 0323138896

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Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.

Polymer Thermodynamics

Author: Sabine Enders

Publisher: Springer

Published: 2011-01-18

Total Pages: 434

ISBN-13: 3642176828

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Making Flory-Huggins Practical: Thermodynamics of Polymer-Containing Mixtures, by B. A. Wolf * Aqueous Solutions of Polyelectrolytes: Vapor-Liquid Equilibrium and Some Related Properties, by G. Maurer, S. Lammertz, and L. Ninni Schäfer * Gas-Polymer Interactions: Key Thermodynamic Data and Thermophysical Properties, by J.-P. E. Grolier, and S. A.E. Boyer * Interfacial Tension in Binary Polymer Blends and the Effects of Copolymers as Emulsifying Agents, by S. H. Anastasiadis * Theory of Random Copolymer Fractionation in Columns, by Sabine Enders * Computer Simulations and Coarse-Grained Molecular Models Predicting the Equation of State of Polymer Solutions, by K. Binder, B. Mognetti, W. Paul, P. Virnau, and L. Yelash * Modeling of Polymer Phase Equilibria Using Equations of State, by G. Sadowski

Polymer Blends

Author: D.R. Paul

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 454

ISBN-13: 0323149774

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Polymer Blends, Volume 2 aims to show the importance of mixed polymer systems as a major branch of macromolecular science and provides a broad background of principles and practices in this field. Starting from where the first volume left off, the book covers topics in the area of polymer blends in Chapters 11-23. Areas of coverage include interpenetrating polymer networks; interfacial agents for polymer blends; rubber modification of plastics; fracture phenomena; coextruded multilayer polymer films and sheets; polymeric plasticizers; and polyolefin blends and their applications. The book is recommended for scientists, technologists, and engineers in the academe, research, and related industry, especially those who wish to be updated with its advances as a science.

High Temperature Polymer Blends

Author: Mark T. DeMeuse

Publisher: Elsevier

Published: 2014-03-25

Total Pages: 233

ISBN-13: 0857099019

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Polymer blends offer properties not easily obtained through the use of a single polymer, including the ability to withstand high temperatures. High Temperature Polymer Blends outlines the characteristics, developments, and use of high temperature polymer blends. The first chapter introduces high temperature polymer blends, their general principles, and thermodynamics. Further chapters go on to deal with the characterization of high temperature polymer blends for specific uses, such as fuel cells and aerospace applications. The book discusses different types of high temperature polymer blends, including liquid crystal polymers, polysulfones, and polybenzimidazole polymer blends and their commercial applications. High Temperature Polymer Blends provides a key reference for material scientists, polymer scientists, chemists, and plastic engineers, as well as academics in these fields. Reviews characterization methods and analysis of the thermodynamic properties of high temperature polymer blends Reviews the use of materials such as liquid crystals as reinforcements as well as applications in such areas as energy and aerospace engineering

Concepts in Polymer Thermodynamics, Volume II

Author: Menno A. van Dijk

Publisher: CRC Press

Published: 2023-04-14

Total Pages: 220

ISBN-13: 1000940330

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Concepts in Polymer Thermodynamics

Author: Menno A. van Dijk

Publisher: CRC Press

Published: 1998-01-14

Total Pages: 224

ISBN-13: 9781566766234

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Thermodynamics of Systems Containing Flexible-Chain Polymers

Author: V.J. Klenin

Publisher: Elsevier

Published: 1999-06-03

Total Pages: 851

ISBN-13: 0080542832

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This book deals with the problems of the thermodynamics of systems containing flexible-chain polymers as the basis of polymer material science. The main thermodynamic quantities and concepts are introduced and discussed in the order of the objects getting more and more complicated: gases, magnets, low-molecular-weight substances and mixtures, and finally, polymers and polymer blends. All topics are considered in a common clue, using the principle of universality. The stability conditions for the one-phase state of multi-component systems are given. Phase separation is regarded as a result of loss in stability. The critical state of a system, with the one-phase state being close to the boundary of stability conditions breaking, is discussed in detail. The effects of both light scattering (elastic and dynamic) and diffusion, as directly depending on the thermodynamic parameters characterizing the one-phase state stability, are considered in detail. One of the versions of colloid scattering, namely, the turbidity spectrum method, is described as useful for the characterization of various heterogeneous structures and for the phase analysis of polymer systems. In the approximation of mean field theories and advanced field theory, formalisms expound the following divisions of the thermodynamics of binary and polynary systems with flexible-chain polymers: conformation of the polymer coil, composition fluctuations, elastic and dynamic light scattering, diffusion in the one-phase state (including the critical range), phase separation, polymer fractionation, the coil-globule transition, phase equilibrium and separation in the system network polymer + low-molecular-weight liquid, polymer blends and multiphase separation.

Compatibilization of Polymer Blends

Author: Ajitha A. R

Publisher: Elsevier

Published: 2019-10-10

Total Pages: 640

ISBN-13: 0128162880

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Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends Draws on novel studies and state-of-the-art research, discussing the latest issues and developments