The Physics and Chemistry of Aqueous Ionic Solutions

The Physics and Chemistry of Aqueous Ionic Solutions PDF

Author: M.C. Bellissent-Funel

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 479

ISBN-13: 9400939116

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J.E. Enderby At the last NATO-ASI on liquids held in Corsica, (August 1977),Professor de Gennes, in his summary of that meeting, suggested that the next ASI should concentrate on some specific aspect of the subject and mentioned explicitly ionic solutions as one possibility. The challenge was taken up by Marie-Claire Bellissent-Funel and George Neilson; I am sure that all the participants would wish to congratulate our two colleagues for putting together an outstanding programme of lectures, round tables and poster session. The theory which underlies the subject was covered by four leading authorities: J.-P. Hansen (Paris) set out the general framework in terms of the statistical mechanics of bulk and surface properties; H.L. Friedman (Stony Brook) focused attention on ionic liquids at equilibrium, and J.B. Hubbard considered non-equilibrium properties such as the electrical conductivity and ionic friction coefficients. Finally, the basic theory of polyelectrolytes treated as charged linear polymers in aqueous solution was presented by J.M. Victor (Paris).

Aqueous Solutions of Simple Electrolytes

Aqueous Solutions of Simple Electrolytes PDF

Author: Felix Franks

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 482

ISBN-13: 1468429558

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The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes "classical." Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

Aqueous Solutions of Simple Electrolytes

Aqueous Solutions of Simple Electrolytes PDF

Author: Felix Franks

Publisher: Springer

Published: 2012-07-15

Total Pages: 472

ISBN-13: 9781468429565

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The chapters making up this volume had originally been planned to form part of a single volume covering solid hydrates and aqueous solutions of simple molecules and ions. However, during the preparation of the manu scripts it became apparent that such a volume would turn out to be very unwieldy and I reluctantly decided to recommend the publication of sepa rate volumes. The most sensible way of dividing the subject matter seemed to lie in the separation of simple ionic solutions. The emphasis in the present volume is placed on ion-solvent effects, since a number of excellent texts cover the more general aspects of electrolyte solutions, based on the classical theories of Debye, Huckel, On sager, and Fuoss. It is interesting to speculate as to when a theory becomes "classical." Perhaps this occurs when it has become well known, well liked, and much adapted. The above-mentioned theories of ionic equilibria and transport certainly fulfill these criteria. There comes a time when the refinements and modifications can no longer be related to physical significance and can no longer hide the fact that certain fundamental assumptions made in the development of the theory are untenable, especially in the light of information obtained from the application of sophisticated molecular and thermodynamic techniques.

The Physical Chemistry of Aqueous Systems

The Physical Chemistry of Aqueous Systems PDF

Author: Robert Kay

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 263

ISBN-13: 1461345111

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Conformation and Hydration of Sugars and Related Compounds in Dilute Aqueous Solution.- Studies of Hydrophobic Bonding in Aqueous Alcohols: Enthalpy Measurements and Model Calculations.- Structure in Aqueous Solutions of Nonpolar Solutes from the Standpoint of Scaled-Particle Theory.- Raman Spectra from Partially Deuterated Water and Ice VI to 10.1 kbar at 28°C.- Solvation Equilibria in Very Concentrated Electrolyte Solutions.- Ionic Association in Hydrogen-Bonding Solvents.- The Role of Solvent Structure in Ligand Substitution and Solvent Exchange at Some Divalent Transition-Metal Cations.- N.

Electrolytes at Interfaces

Electrolytes at Interfaces PDF

Author: S. Durand-Vidal

Publisher: Springer Science & Business Media

Published: 2006-04-11

Total Pages: 347

ISBN-13: 0306469405

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The aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces.

An Introduction to Aqueous Electrolyte Solutions

An Introduction to Aqueous Electrolyte Solutions PDF

Author: Margaret Robson Wright

Publisher: John Wiley & Sons

Published: 2007-06-05

Total Pages: 603

ISBN-13: 0470842938

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An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.

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