Phase Diagrams for Geoscientists

Phase Diagrams for Geoscientists PDF

Author: Tibor Gasparik

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 467

ISBN-13: 3540383522

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The book summarizes the author's experimental studies of phase relations in the chemical systems relevant to Earth, carried out in a time period of over 20 years using piston-cylinder and multi-avil presses. A summary of the research at high pressures and temperatures carried out by many other experimental petrologists is also included. The data was used to develop an internally consistent thermodynamic model, which was then used to calculate phase diagrams. This produced the largest collection of the calculated phase diagrams published so far, encompassing for the first time the temperature and pressure ranges corresponding to the whole upper mantle.

Phase Diagrams for Geoscientists

Phase Diagrams for Geoscientists PDF

Author: Tibor Gasparik

Publisher: Springer Science & Business Media

Published: 2013-08-13

Total Pages: 467

ISBN-13: 1461457769

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The book summarizes the results of the experimental studies of phase relations in the chemical systems relevant to Earth, carried out by the author in a time period of over 20 years between 1979 and 2001. It is based on 1000 piston-cylinder experiments at pressures up to 4 GPa, and close to 700 experiments carried out with a multi-anvil apparatus at pressures up to 24 GPA. This is the largest published collection of calculated phase diagrams for the chemical systems relevant to Earth. This is also the first time that the phase relations at the relatively low pressures of the lithospheric mantle, mainly applicable to the experimental thermobarometry of metamorphic rocks and mantle xenoliths, are seamlessly integrated with the phase relations of the sublithospheric upper mantle and the uppermost lower mantle, primarily applicable to inclusions in diamond and schocked meteorites. "Tibor Gasparik has devoted his career to determining the high-pressure, high-temperature phase relations of the geologically important Sodium-Calcium-Magnesium-Aluminium-Silicon (NCMAS) oxide system. This book is his opus magnum, summarizing more than 1700 experiments in over 120 figures. ... I have found Phase Diagrams for Geoscientists to be a useful first port-of-call for finding the P-T stability fields ... and I can recommend the book as a reference for geoscientists requiring an overview of the stable phase assemblages in the top 700 km of the Earth." (David Dobson, Geological Magazine, Vol. 142 (2), 2005)

Phase Theory

Phase Theory PDF

Author: H.A.J. Oonk

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 284

ISBN-13: 0444599339

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Studies in Modern Thermodynamics, 3: Phase Theory: The Thermodynamics of Heterogeneous Equilibria focuses on the processes, methodologies, principles, and approaches employed in the determination of the thermodynamics of heterogeneous equilibria. The publication first elaborates on thermodynamic background, phase rule, and general relations for binary equilibria. Discussions focus on linear contributions, G-curves and phase diagram, function changes, Clapeyron's equation, derivation of phase rule, pressure and temperature, heat capacity, enthalpy, and Gibbs energy. The manuscript then examines demixing, isothermal liquid-vapor equilibria, isobaric equilibria between two mixed states, and isobaric equilibria between unmixed solid and mixed liquid state. Topics include phase diagrams, pure solid component with liquid mixture, equilibrium between two ideal states, calculation of phase diagrams, and types of phase diagram. The text ponders on the interpretation of TX phase diagrams and retrograde equilibrium curves, including retrograde solubility, regions of demixing, excess parameters, and eutectic systems. The publication is a valuable reference for researchers wanting to dig deeper into the thermodynamics of heterogeneous equilibria.

Polymer Phase Diagrams

Polymer Phase Diagrams PDF

Author: Ronald Koningsveld

Publisher: Oxford University Press, USA

Published: 2001

Total Pages: 372

ISBN-13: 9780198556350

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Polymeric materials include plastics, gels, synthetic fibres, and rubbers. They are all-important both in industry and in daily life. Unlike liquid water, ice, or sugar solution, polymers are not homogeneous. They are said to consist of two or more phases, and their production and processing, as well as their properties and uses, depend on an understanding of the transitions that take place between these phases. This new textbook uses fundamental principles to classify phase separation phenomena in polymer systems, and describes simple molecular models explaining the observed behaviour.

Basalts and Phase Diagrams

Basalts and Phase Diagrams PDF

Author: S.A. Morse

Publisher: Springer

Published: 1980-10-15

Total Pages: 493

ISBN-13: 9780387904771

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The science of igneous petrology is founded on astute observation of rocks, guided by the rigorous principles of physical chemistry. It is, perhaps, the wedding of fallible observation with rigorous theory that makes this such a delicious science. In view of this, it is appropriate to study rocks and phase diagrams hand in hand. Good books on petrography abound, but there are few introductory books on phase diagrams, and none that illustrate in detail the quantitative analysis of fractional and equilibrium crystalliza tion and melting, the four limiting processes capable of rigorous discussion. This book is an attempt to remedy the deficiency. Basalts underlie some 70 percent of the earth' s surface and represent the most abundant magma type on both the earth and the moon. It is therefore fitting to address their origin in some detail. As it happens, most of the interesting principles of phase equilibrium diagrams as applied to igneous rocks can be illustrated with basalts. I have therefore tied the exposition of phase diagrams to the larger story, still unfolding, of the origin and fate of the basaltic magma. In so doing, one neglects many interesting rocks, but their origins can be studied using the principles developed here.

Ternary Phase Diagrams in Materials Science

Ternary Phase Diagrams in Materials Science PDF

Author: D. R. F. West

Publisher: CRC Press

Published: 2020-08-26

Total Pages: 290

ISBN-13: 1000161161

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This book provides an introductory treatment of ternary equilibrium diagrams. It presents case studies in the field of metallurgy and material science. It is useful for undergraduates and postgraduates and scientists, who wish to acquire an understanding of ternary phase diagrams.

Methods for Phase Diagram Determination

Methods for Phase Diagram Determination PDF

Author: Ji-Cheng Zhao

Publisher: Elsevier

Published: 2011-05-05

Total Pages: 520

ISBN-13: 9780080549965

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Phase diagrams are "maps" materials scientists often use to design new materials. They define what compounds and solutions are formed and their respective compositions and amounts when several elements are mixed together under a certain temperature and pressure. This monograph is the most comprehensive reference book on experimental methods for phase diagram determination. It covers a wide range of methods that have been used to determine phase diagrams of metals, ceramics, slags, and hydrides. * Extensive discussion on methodologies of experimental measurements and data assessments * Written by experts around the world, covering both traditional and combinatorial methodologies * A must-read for experimental measurements of phase diagrams

Basalts and Phase Diagrams

Basalts and Phase Diagrams PDF

Author: Stearns A. Morse

Publisher: Springer

Published: 2024-03-24

Total Pages: 0

ISBN-13: 9783030978808

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In this newly revised and expanded edition the reader finds both an introduction to igneous petrology and an exposition of the quantitative use of phase diagrams in understanding the origin and crystallization history of basic magmas. The book provides a step-by- step analysis of crystallization and melting in a limited number of geologically significant phase diagrams. The limiting processes of fractional and equilibrium melting and fractional and equilibrium crystallization are rigorously examined. Examples of the use of phase diagrams are drawn from the literature of layered intrusions, redox equilibria in iron-bearing systems, and the high pressure equilibria of melting in the mantle.