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Open Quantum Systems Far from Equilibrium

Author: Gernot Schaller

Publisher: Springer

Published: 2014-01-07

Total Pages: 215

ISBN-13: 331903877X

This monograph provides graduate students and also professional researchers aiming to understand the dynamics of open quantum systems with a valuable and self-contained toolbox. Special focus is laid on the link between microscopic models and the resulting open-system dynamics. This includes how to derive the celebrated Lindblad master equation without applying the rotating wave approximation. As typical representatives for non-equilibrium configurations it treats systems coupled to multiple reservoirs (including the description of quantum transport), driven systems and feedback-controlled quantum systems. Each method is illustrated with easy-to-follow examples from recent research. Exercises and short summaries at the end of every chapter enable the reader to approach the frontiers of current research quickly and make the book useful for quick reference.

Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis

Author: V. Parmon

Publisher: Elsevier

Published: 2009-09-26

Total Pages: 340

ISBN-13: 0080931960

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Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis consists of materials adapted from lectures on the thermodynamics of nonequilibrium processes that have been taught at the Department of Natural Sciences of Novosibirsk State University since 1995. The thermodynamics of nonequilibrium processes traditionally required students to have a strong background in physics. However, the materials featured in this volume allow anyone with knowledge in classical thermodynamics of equilibrium processes and traditional chemical kinetics to understand the subject. Topics discussed include systems in the thermodynamics of irreversible processes; thermodynamics of systems that are close to and far from equilibrium; thermodynamics of catalysts; the application of nonequilibrium thermodynamics to material science; and the relationship between entropy and information. This book will be helpful for research into complex chemical transformations, particularly catalytic transformations. Applies simple approaches of non-equilibrium thermodynamics to analyzing properties of chemically reactive systems Covers systems far from equilibrium, allowing the consideration of most chemically reactive systems of a chemical or biological nature This approach resolves many complicated problems in the teaching of chemical kinetics

Systems Far from Equilibrium

Author: Luis Garrido

Publisher: Springer

Published: 1980

Total Pages: 440

ISBN-13:

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Far-from-equilibrium Dynamics

Author: Yasumasa Nishiura

Publisher: American Mathematical Soc.

Published: 2002

Total Pages: 340

ISBN-13: 9780821826256

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This book is devoted to the study of evolution of nonequilibrium systems. Such a system usually consists of regions with different dominant scales, which coexist in the space-time where the system lives. In the case of high nonuniformity in special direction, one can see patterns separated by clearly distinguishable boundaries or interfaces. The author considers several examples of nonequilibrium systems. One of the examples describes the invasion of the solid phase into the liquidphase during the crystallization process. Another example is the transition from oxidized to reduced states in certain chemical reactions. An easily understandable example of the transition in the temporal direction is a sound beat, and the author describes typical patterns associated with thisphenomenon. The main goal of the book is to present a mathematical approach to the study of highly nonuniform systems and to illustrate it with examples from physics and chemistry. The two main theories discussed are the theory of singular perturbations and the theory of dissipative systems. A set of carefully selected examples of physical and chemical systems nicely illustrates the general methods described in the book.

Statistical Thermodynamics of Nonequilibrium Processes

Author: Joel Keizer

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 517

ISBN-13: 1461210542

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The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.

Out-of-Equilibrium (Supra)molecular Systems and Materials

Author: Nicolas Giuseppone

Publisher: John Wiley & Sons

Published: 2021-03-30

Total Pages: 448

ISBN-13: 3527821988

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A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.

Self-Organization

Author: V.I. Krinsky

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 271

ISBN-13: 3642702104

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According to its definition, Synergetics is concerned with systems that produce macroscopic spatial, temporal, or functional structures. Autowaves are·a specific, yet very important, case of spatio-temporal structures. The term "autowave" was coined in the Soviet Union in analogy to the term "auto-oscillator". This is - perhaps too literal - translation of the Russian word "avto-ostsillyatory" (= self oscillator) which in its proper translation means "self-sustained oscillator". These are oscillators, e. g. , clocks, whose internal energy dissipation is compensa ted by a (more or less) continuous power input. Simi larly, the term "autowaves" de notes propagation effects - including waves - in active media, which provide spa tially distributed energy sources and thus may compensate dissipation. An example which is now famous is represented by spiral or concentric waves in a chemically active medium, undergoing the Belousov-Zhabotinsky reaction. This book provides the reader with numerous further examples from physics, chem istry, and biology - e. g. , autowaves of the heart. While the Belousov-Zhabotinsky reaction is now widely known, a number of very important results obtained in the Soviet Union are perhaps less well known. I am particularly glad that this book may help to make readers outside the Soviet Union acquainted with these important exper imental and theoretical findings which are presented in a way which elucidates the common principles underlying this kind of propagation effects. Professor V.

Beyond Equilibrium Thermodynamics

Author: Hans Christian Öttinger

Publisher: John Wiley & Sons

Published: 2005-05-13

Total Pages: 651

ISBN-13: 0471727911

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Beyond Equilibrium Thermodynamics fills a niche in the market by providing a comprehensive introduction to a new, emerging topic in the field. The importance of non-equilibrium thermodynamics is addressed in order to fully understand how a system works, whether it is in a biological system like the brain or a system that develops plastic. In order to fully grasp the subject, the book clearly explains the physical concepts and mathematics involved, as well as presenting problems and solutions; over 200 exercises and answers are included. Engineers, scientists, and applied mathematicians can all use the book to address their problems in modelling, calculating, and understanding dynamic responses of materials.

Non-Equilibrium Phase Transitions

Author: Malte Henkel

Publisher: Springer Science & Business Media

Published: 2011-01-19

Total Pages: 562

ISBN-13: 9048128692

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“The importance of knowledge consists not only in its direct practical utility but also in the fact the it promotes a widely contemplative habit of mind; on this ground, utility is to be found in much of the knowledge that is nowadays labelled ‘useless’. ” Bertrand Russel, In Praise of Idleness, London (1935) “Why are scientists in so many cases so deeply interested in their work ? Is it merely because it is useful ? It is only necessary to talk to such scientists to discover that the utilitarian possibilities of their work are generally of secondary interest to them. Something else is primary. ” David Bohm, On creativity, Abingdon (1996) In this volume, the dynamical critical behaviour of many-body systems far from equilibrium is discussed. Therefore, the intrinsic properties of the - namics itself, rather than those of the stationary state, are in the focus of 1 interest. Characteristically, far-from-equilibrium systems often display - namical scaling, even if the stationary state is very far from being critical. A 1 As an example of a non-equilibrium phase transition, with striking practical c- sequences, consider the allotropic change of metallic ?-tin to brittle ?-tin. At o equilibrium, the gray ?-Sn becomes more stable than the silvery ?-Sn at 13. 2 C. Kinetically, the transition between these two solid forms of tin is rather slow at higher temperatures. It starts from small islands of ?-Sn, the growth of which proceeds through an auto-catalytic reaction.

Propagation in Systems Far from Equilibrium

Author: Jose E. Wesfreid

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 431

ISBN-13: 3642738613

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Macroscopic physics provides us with a great variety of pattern-forming systems displaying propagation phenomena, from reactive fronts in combustion, to wavy structures in convection and to shear flow instabilities in hydrodynamics. These proceedings record progress in this rapidly expanding field. The contributions have the following major themes: - The problems of velocity selection and front morphology of propagating interfaces in multiphase media, with emphasis on recent theoretical and experimental results on dendritic crystal growth, Saffman-Taylor fingering, directional solidification and chemical waves. - The "unfolding" of large-scale, low-frequency behavior in weakly confined homogeneous systems driven far from equilibrium, and more specifically, the envelope approach to the mathematical description of textures in different cases: steady cells, propagating waves, structural defects, and phase instabilities. - The implications of the presence of global downstream transport in open flows for the nature, convective or absolute, of shear flow instabilities, with applications to real boundary layer flows or shear layers, as reported in contributions covering experimental situations of fundamental and/or engineering interest.