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Supramolecular Coordination Complexes

Author: Sankarasekaran Shanmugaraju

Publisher: Elsevier

Published: 2022-10-28

Total Pages: 498

ISBN-13: 0323907059

Supramolecular Coordination Complexes: Design, Synthesis, and Applications discusses the growth of the field and explores the advantages, opportunities and latest applications of supramolecular complexes. Beginning with an introduction to design principles, synthetic methods, and post-synthetic functionalization of supramolecular complexes, the book goes on to compile the different analytical and computational modeling methods used to understand the structure and functional properties of supramolecular structures. Applications of supramolecular complexes in biomedicine, sensing, catalysis and materials are then explored in detail. Drawing on the knowledge of a global team of experts, this book provides a wealth of interesting information for students and researchers working in the design, synthesis or application of such complexes. Discusses cutting-edge approaches for the investigation of supramolecular coordination chemistry Summarizes a varied range of supramolecular coordination, complex designs and applications Highlights the interdisciplinary connections between supramolecular chemistry and the fields of biology and materials science

Supramolecular Assemblies of Cucurbit[n]urils with Metal Ions

Author: Xin-Long Ni

Publisher: Springer

Published: 2015-03-21

Total Pages: 102

ISBN-13: 3662466295

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This book shows the various porous structures and supramolecular architectures that result from the cucurbituril-based coordination, hydrogen bonding, ion-dipole interactions, π∙∙∙π stacking and C–H∙∙∙π processes. It includes two chapters presenting essential examples of these cucurbituril-based structures, depending on the types of non covalent interactions and inducer species. It also includes one chapter dealing with the utilization of cucurbiturils as a molecular container in supramolecular chemistry and demonstrating a wide range of potential applications of supramolecular assemblies with cucurbiturils in catalysis, separation, absorption and polymer materials. The book offers an interesting and valuable guide for readers working in the areas of supramolecular chemistry and materials.

Anion Coordination Chemistry

Author: Kristin Bowman-James

Publisher: John Wiley & Sons

Published: 2012-03-27

Total Pages: 644

ISBN-13: 3527639519

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Building on the pioneering work in supramolecular chemistry from the last 20 years or so, this monograph addresses new and recent approaches to anion coordination chemistry. Synthesis of receptors, biological receptors and metallareceptors, the energetics of anion binding, molecular structures of anion complexes, sensing devices are presented and computational studies addressed to aid with the understanding of the different driving forces responsible for anion complexation. The reader is promised an actual picture of the state of the art for this exciting and constantly evolving field of supramolecular anion coordination chemistry. The topics range from ion channels to selective sensors, making it attractive to all researchers and PhD students with an interest in supramolecular chemistry.

Transition Metals in Supramolecular Chemistry

Author: L. Fabbrizzi

Publisher: Springer Science & Business Media

Published: 2013-03-09

Total Pages: 445

ISBN-13: 9401583803

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Since the pioneering publications on coordination chemistry by Lehn and Pedersen in the late 1960s, coupled with the more orthodox interest from the transition metal chemists on template reactions (Busch, 1964), the field of supramolecular chemistry has grown at an astonishing rate. The use of transition metals as essential constituents of multi-component assemblies has been especially sharp in recent years, since the metals are prone to quick and reversible redox changes, and there is a wide variety of metal--ligand interactions. Such properties make supramolecular complexes of transition metal ions suitable candidates for exploration as light--energy converters and signal processors. Transition Metals in Supramolecular Chemistry focuses on the following main topics: (1) metal controlled organization of novel molecular assemblies and shapes; (2) design of molecular switches and devices operating through metal centres; (3) supramolecular catalysts that mimic metalloenzymes; (4) metal-containing sensory reagents and supramolecular recognition; and (5) molecular materials that display powerful electronic, optoelectronic and magnetic properties.

Perspectives in Coordination Chemistry

Author: Alan Francis Williams

Publisher:

Published: 1992

Total Pages: 510

ISBN-13:

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In the hundred years since Alfred Werner proposed his theory of coordination compounds, coordination chemistry has grown to occupy a central position in chemical science. This book contains a selection of essays illustrating the state of the subject as it enters its second century. In addition to methods of synthesis and studies of structure and reactivity, particular attention is paid to the applications of coordination chemistry in fields as varied as biochemistry and medicine, organometallic chemistry, solid state chemistry, catalysis, and molecular receptors and devices.

Metallomacrocycles

Author: Hai-Bo Yang

Publisher: Royal Society of Chemistry

Published: 2018-10-05

Total Pages: 290

ISBN-13: 1782628584

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The metal-ligand coordination of metallomacrocycles allows for the production of both discrete and infinite metallosupramolecular structures with high-degrees of complexity. In recent years, coordination-driven self-assembly has emerged as a powerful noncovalent synthetic strategy to build discrete supramolecular architectures with diverse coordination moieties such as a well-defined shape, size, and geometry. The dynamic features of the metal-ligand bonds result in structures with intriguing properties allowing for a diverse range of applications in host-guest chemistry, sensing, drug delivery and catalysis. This book provides a comprehensive summary of current research in metallomacrocycles. Starting with an introduction to metallomacrocycles constructed via coordination-driven self-assembly, the book then goes on to explore design principles and self-organization. Subsequent chapters then discuss examples of complex and functional metallosupramolecular systems based on metallomacrocycles such as chiral systems and mechanically interlocked architectures. Finally, the book discusses the applications of metallomacrocycles. An essential resource for students and researchers looking to design and construct new metallosupramolecular systems and extend their applications in biological and materials science.

Macromolecules Containing Metal and Metal-Like Elements, Volume 9

Author: Alaa S. Abd-El-Aziz

Publisher: John Wiley & Sons

Published: 2009-11-19

Total Pages: 552

ISBN-13: 0470527048

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Volume 9 in a scientific research series, covering macromolecules This book, Macromolecules Containing Metal and Metal-like Elements, presents research developments in the study of: supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies. The topics addressed involve materials containing metals and metal-like elements as well as the possible applications of hybrid materials. The volume offers a broad series of coverage with conclusions and perspectives for the various areas covered.

Coordination Chemistry of Silicon

Author: Prof. Dr. Shigeyoshi Inoue

Publisher: MDPI

Published: 2019-03-04

Total Pages: 228

ISBN-13: 3038976385

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The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.

Supramolecular Chemistry in Corrosion and Biofouling Protection

Author: Viswanathan S. Saji

Publisher: CRC Press

Published: 2021-12-23

Total Pages: 608

ISBN-13: 1000516717

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Supramolecular chemistry, "the chemistry beyond the molecule", is a fascinating realm of modern science. The design of novel supramolecular structures, surfaces, and techniques are at the forefront of research in different application areas, including corrosion and biofouling protection. A team of international experts provide a comprehensive view of the applications and potential of supramolecular chemistry in corrosion and biofouling prevention. Chapter topics include types and fundamentals of supramolecules, supramolecular polymers and gels, host-guest inclusion compounds, organic-inorganic hybrid materials, metallo-assemblies, cyclodextrins, crown ethers, mesoporous silica and supramolecular structures of graphene and other advances. Additional Features include: Focuses on different aspects of supramolecular chemistry in corrosion and biofouling prevention. Comprehensively covers supramolecular interactions that can provide better corrosion and biofouling protection. Provides the latest developments in self-healing coatings. Explores recent research advancements in the suggested area. Includes case studies specific to industries. The different supramolecular approaches being investigated to control corrosion and biofouling are gathered in one well-organized reference to serve senior undergraduate and graduate students, research students, engineers, and researchers in the fields of corrosion science & engineering, biofouling, and protective coatings.

Organic Nanostructures

Author: Jerry L. Atwood

Publisher: John Wiley & Sons

Published: 2008-09-08

Total Pages: 370

ISBN-13: 3527622519

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Filling the need for a volume on the organic side of nanotechnology, this comprehensive overview covers all major nanostructured materials in one handy volume. Alongside metal organic frameworks, this monograph also treats other modern aspects, such as rotaxanes, catenanes, nanoporosity and catalysis. Detailed attention is paid to the chemistry, physics and materials science throughout, making this a definite must for all chemists.