The Physics of Glassy Polymers

The Physics of Glassy Polymers PDF

Author: R. N. Haward

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 635

ISBN-13: 9401023557

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This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.

The Physics of Glassy Polymers

The Physics of Glassy Polymers PDF

Author: R. N. Haward

Publisher: Springer

Published: 2011-12-09

Total Pages: 620

ISBN-13: 9789401023573

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This work sets out to provide an up-to-date account of the physical properties and structure of polymers in the glassy state. Properties measured above the glass transition temperature are therefore included only in so far as is necessary for the treatment of the glass transition process. This approach to the subject therefore excludes any detailed account of rubber elasticity or melt rheology or of the structure and conformation of the long chain molecule in solution, although knowledge derived from this field is assumed where required. Major emphasis is placed on structural and mechanical properties, although a number of other physical properties are included. Naturally the different authors contributing to the book write mainly from their own particular points of view and where there are several widely accepted theoretical approaches to a subject, these are sometimes provided in different chapters which will necessarily overlap to a significant extent. For example, the main theoretical presentation on the subject of glass transition is given in Chapter 1. This is supplemented by accounts of the free volume theory in Chapter 3 and in the Introduction, and a short account of the work of Gibbs and DiMarzio, also in Chapter 3. Similarly, there is material on solvent cracking in Chapters 7 and 9, though the two workers approach the subject from opposite directions. Every effort has therefore been made to encourage cross-referencing between different chapters.

Structure and Properties of Glassy Polymers

Structure and Properties of Glassy Polymers PDF

Author: Martin R. Tant

Publisher:

Published: 1998

Total Pages: 486

ISBN-13:

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In twenty-nine chapters by leading authorities, Structure and Properties of Glassy Polymers provides readers with comprehensive coverage of basic and applied research on glass polymers as well as a wealth of information on current topics such as molecular modeling, characterization, polymer glasses in confined spaces, and conducting glass polymers. The characterization techniques presented include temperature-modulated differential scanning calorimetry, dielectric loss spectroscopy, photochemical hole burning, positron annihilation lifetime spectroscopy, and transient current generation.

Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers

Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers PDF

Author: L. Volynskii

Publisher: CRC Press

Published: 2018-09-03

Total Pages: 526

ISBN-13: 1315362112

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Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers explores the role of various surface phenomena in the structural and mechanical behaviour of amorphous and semicrystalline polymers. This book: Discusses the development of the interfacial surface in the deformation of polymers Examines the healing of interfacial surfaces in polymers Inspects the structure and properties of polymers in thin films and surface layers Evaluates the mechanism of inelastic deformation in glassy amorphous polymers Investigates strain softening and the phenomena taking place upon deformation of polymers in active liquid media Covers the Rehbinder effect, or the adsorption reduction of the strength of solids Describes the properties of polymers in environmental or solvent crazing Analyses the interaction of the highly developed surface of crazed polymers with diverse low- and high-molecular mass components Addresses the instability and self-organisation of surface layers in polymers and diverse polymer systems Presents theoretical speculations concerning the structurally mechanical behaviour of ‘a rigid coating on a soft substratum’ (RCSS) systems Assesses the stress–strain properties of the thin surface layers of polymers and the nanometric coatings deposited on their surfaces Highlights the efficacy of the approaches developed for RCSS systems for the analysis and description of natural phenomena Details the applied aspects of surface phenomena in the structurally mechanical behaviour of polymers Thus, Surface Phenomena in the Structural and Mechanical Behaviour of Solid Polymers provides a useful framework for the development of new and innovative polymer-based materials.

Mechanical Properties and Testing of Polymers

Mechanical Properties and Testing of Polymers PDF

Author: G.M. Swallowe

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 313

ISBN-13: 9401592314

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This volume represents a continuation of the Polymer Science and Technology series edited by Dr. D. M. Brewis and Professor D. Briggs. The theme of the series is the production of a number of stand alone volumes on various areas of polymer science and technology. Each volume contains short articles by a variety of expert contributors outlining a particular topic and these articles are extensively cross referenced. References to related topics included in the volume are indicated by bold text in the articles, the bold text being the title of the relevant article. At the end of each article there is a list of bibliographic references where interested readers can obtain further detailed information on the subject of the article. This volume was produced at the invitation of Derek Brewis who asked me to edit a text which concentrated on the mechanical properties of polymers. There are already many excellent books on the mechanical properties of polymers, and a somewhat lesser number of volumes dealing with methods of carrying out mechanical tests on polymers. Some of these books are listed in Appendix 1. In this volume I have attempted to cover basic mechanical properties and test methods as well as the theory of polymer mechanical deformation and hope that the reader will find the approach useful.

Mechanical Properties of Solid Polymers

Mechanical Properties of Solid Polymers PDF

Author: Ian M. Ward

Publisher: John Wiley & Sons

Published: 2012-10-22

Total Pages: 480

ISBN-13: 1119967112

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Providing an updated and comprehensive account of the propertiesof solid polymers, the book covers all aspects of mechanicalbehaviour. This includes finite elastic behavior, linearviscoelasticity and mechanical relaxations, mechanical anisotropy,non-linear viscoelasicity, yield behavior and fracture. New to thisedition is coverage of polymer nanocomposites, and molecularinterpretations of yield, e.g. Bowden, Young, and Argon. The book begins by focusing on the structure of polymers,including their chemical composition and physical structure. It goes on to discuss the mechanical properties and behaviour ofpolymers, the statistical molecular theories of the rubber-likestate and describes aspects of linear viscoelastic behaviour, itsmeasurement, and experimental studies. Later chapters cover composites and experimental behaviour,relaxation transitions, stress and yielding. The book concludeswith a discussion of breaking phenomena.

The Physics of Deformation and Fracture of Polymers

The Physics of Deformation and Fracture of Polymers PDF

Author: A. S. Argon

Publisher: Cambridge University Press

Published: 2013-03-07

Total Pages: 535

ISBN-13: 0521821843

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A physical, mechanism-based presentation of the plasticity and fracture of polymers, covering industrial scale applications through to nanoscale biofluidic devices.

Relaxation in Physical and Mechanical Behavior of Polymers

Relaxation in Physical and Mechanical Behavior of Polymers PDF

Author: Maxim Arzhakov

Publisher: CRC Press

Published: 2019-01-30

Total Pages: 183

ISBN-13: 0429534736

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Explores the nature of relaxation phenomena in polymers on the basis of time-temperature equivalence. Its role in the physical and mechanical behavior of polymers materials and fundamentals of thermoplastics processing are discussed. Four appendixes detail thermo-mechanical methods to study relaxation in polymers, structure of both amorphous and semi-crystalline polymers, and unified approach to describe deformation of polymeric materials.