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Soft Matter at Aqueous Interfaces

Author: Peter Lang

Publisher: Springer

Published: 2015-12-24

Total Pages: 556

ISBN-13: 3319245023

This book covers the science of interfaces between an aqueous phase and a solid, another liquid or a gaseous phase, starting from the basic physical chemistry all the way to state-of-the-art research developments. Both experimental and theoretical methods are treated thanks to the contributions of a distinguished list of authors who are all active researchers in their respective fields. The properties of these interfaces are crucial for a wide variety of processes, products and biological systems and functions, such as the formulation of personal care and food products, paints and coatings, microfluidic and lab-on-a-chip applications, cell membranes, and lung surfactants. Accordingly, research and expertise on the subject are spread over a broad range of academic disciplines and industrial laboratories. This book brings together knowledge from these different places with the aim of fostering education, collaborations and research progress.

Emulsions, Microemulsions and Foams

Author: Dominique Langevin

Publisher: Springer Nature

Published: 2020-12-21

Total Pages: 354

ISBN-13: 3030556816

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This book takes an interface science approach to describe and understand the behavior of the dispersions we call emulsions, microemulsions and foams. The one thing all these dispersions have in common is the presence of surface-active species (surfactants) adsorbed at the interfaces between the two fluid phases that make up the emulsions, microemulsions or foams. The interfacial layers formed by the surfactants control most of the properties of the dispersions. The book describes the properties of interfacial layers, thin films and bulk fluids used in the elaboration of the various dispersions and it explains how such properties relate to the dispersion properties of these soft matter systems: structure, rheology and stability. These dispersion properties are far from being fully understood, in particular foam and emulsion stability. In discussing the state of the art of the current knowledge, the author draws interesting parallels between emulsions, microemulsions and foams that enlighten the interpretation of previous observations and point to a deeper understanding of the behavior of these materials in the future.

Ion Correlations at Electrified Soft Matter Interfaces

Author: Nouamane Laanait

Publisher: Springer Science & Business Media

Published: 2013-07-30

Total Pages: 122

ISBN-13: 3319009001

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Ion Correlations at Electrified Soft Matter Interfaces presents an investigation that combines experiments, theory, and computer simulations to demonstrate that the interdependency between ion correlations and other ion interactions in solution can explain the distribution of ions near an electrified liquid/liquid interface. The properties of this interface are exploited to vary the coupling strength of ion-ion correlations from weak to strong while monitoring their influence on ion distributions at the nanometer scale with X-ray reflectivity and on the macroscopic scale with interfacial tension measurements. This thesis demonstrates that a parameter-free density functional theory that includes ion-ion correlations and ion-solvent interactions is in agreement with the data over the entire range of experimentally tunable correlation coupling strengths. The reported findings represent a significant advance towards understanding the nature and role of ion correlations in charged soft-matter. Ion distributions underlie many scientific phenomena and technological applications, including electrostatic interactions between charged biomolecules and the efficiency of energy storage devices. These distributions are determined by interactions dictated by the chemical properties of the ions and their environment, as well as the long-range nature of the electrostatic force. The presence of strong correlations between ions is responsible for counterintuitive effects such as like-charge attraction.

Ionic Soft Matter: Modern Trends in Theory and Applications

Author: Douglas Henderson

Publisher: Springer Science & Business Media

Published: 2006-06-30

Total Pages: 418

ISBN-13: 1402036590

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Recently there have been profound developments in the understanding and interpretation of liquids and soft matter centered on constituents with sho- range interactions. Ionic soft matter is a class of conventional condensed soft matter with prevailing contribution from electrostatics and, therefore, can be subject to possible long-range correlations among the components of the - terial and in many cases crucially affecting its physical properties. Among the most popular representatives of such a class of materials are natural and synthetic saline environments, like aqueous and non-aqueous electrolyte - lutions and molten salts as well as variety of polyelectrolytes and colloidal suspensions. Equally well known are biological systems of proteins. All these systems are examples of soft matter strongly in?uenced, if not dominated, by long-range forces. For more than half of century the classical theories by Debye and Hückel as well as by Derjaguin, Landau, Verwey and Owerbeek (DLVO) have been at the basis of theoretical physical chemistry and chemical engineering. The substantial progress in material science during last few decades as well as the advent of new instrumentation and computational techniques made it apparent that in many cases the classical theories break down. New types of interactions (e.g. hydrodynamic, entropic) have been discovered and a number of questions have arisen from theoretical and experimental studies. Many of these questions still do not have de?nite answers.

Soft Interfaces

Author: Lydéric Bocquet

Publisher: Oxford University Press

Published: 2017-09-22

Total Pages: 528

ISBN-13: 0192506404

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Many of the distinctive and useful phenomena of soft matter come from its interaction with interfaces. Examples are the peeling of a strip of adhesive tape, the coating of a surface, the curling of a fiber via capillary forces, or the collapse of a porous sponge. These interfacial phenomena are distinct from the intrinsic behavior of a soft material like a gel or a microemulsion. Yet many forms of interfacial phenomena can be understood via common principles valid for many forms of soft matter. Our goal in organizing this school was to give students a grasp of these common principles and their many ramifications and possibilities. The Les Houches Summer School comprised over fifty 90-minute lectures over four weeks. Four four-lecture courses by Howard Stone, Michael Cates, David Nelson and L. Mahadevan served as an anchor for the program. A number of shorter courses and seminars rounded out the school. This volume collects the lecture notes of the school.

Soft Matter Physics

Author: Mohamed Daoud

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 335

ISBN-13: 3662038455

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In a liquid crystal watch, the molecules contained within a thin film of the screen are reorientated each second by extremely weak electrical signals. Here is a fine example of soft matter: molecular systems giving a strong response to a very weak command signal. They can be found almost everywhere. Soft magnetic materials used in transformers exhibit a strong magnetic moment under the action of a weak magnetic field. Take a completely different domain: gelatin, formed from col lagen fibres dissolved in hot water. When we cool below 37°C, gelation occurs, the chains joining up at various points to form a loose and highly deformable network. This is a natural example of soft matter. Going further, rather than consider a whole network, we could take a single chain of flexible polymer, such as polyoxyethylene [POE = (CH CH O)N, 2 2 5 where N rv 10 ], for example, in water. Such a chain is fragile and may break under flow. Even though hydrodynamic forces are very weak on the molecular scale, their cumulated effect may be significant. Think of a rope pulled from both ends by two groups of children. Even if each girl and boy cannot pull very hard, the rope can be broken when there are enough children pulling.

Fluids, Colloids and Soft Materials

Author: Alberto Fernandez-Nieves

Publisher: John Wiley & Sons

Published: 2016-05-09

Total Pages: 444

ISBN-13: 111806562X

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This book presents a compilation of self-contained chapters covering a wide range of topics within the broad field of soft condensed matter. Each chapter starts with basic definitions to bring the reader up-to-date on the topic at hand, describing how to use fluid flows to generate soft materials of high value either for applications or for basic research. Coverage includes topics related to colloidal suspensions and soft materials and how they differ in behavior, along with a roadmap for researchers on how to use soft materials to study relevant physics questions related to geometrical frustration.

Inner and Outer Interfaces in Soft Matter Systems

Author: Christine M. Papadakis

Publisher:

Published: 2003

Total Pages: 50

ISBN-13:

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Non-equilibrium Soft Matter Physics

Author: Shigeyuki Komura

Publisher: World Scientific

Published: 2012-02-03

Total Pages: 435

ISBN-13: 9814458430

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Soft matter is a concept which covers polymers, liquid crystals, colloids, amphiphilic molecules, glasses, granular and biological materials. One of the fundamental characteristic features of soft matter is that it exhibits various mesoscopic structures originating from a large number of internal degrees of freedom of each molecule. Due to such intermediate structures, soft matter can easily be brought into non-equilibrium states and cause non-linear responses by imposing external fields such as an electric field, a mechanical stress or a shear flow. Volume 4 of the series in Soft Condensed Matter focuses on the non-linear and non-equilibrium properties of soft matter. It contains a collection of review articles on the current topics of non-equilibrium soft matter physics written by leading experts in the field. The topics dealt with in this volume includes rheology of polymers and liquid crystals, dynamical properties of Langmuir monolayers at the air/water interface, hydrodynamics of membranes and twisted filaments as well as dynamics of deformable self-propelled particles and migration of biological cells. This book serves both as an introduction to students as well as a useful reference to researchers.

Soft Matter

Author: Wim van Saarloos

Publisher: Princeton University Press

Published: 2024-03-26

Total Pages: 622

ISBN-13: 0691191301

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"Soft matter science is an interdisciplinary field at the interface of physics, biology, chemistry, engineering, and materials science. It encompasses colloids, polymers, and liquid crystals as well as rapidly emerging topics such as metamaterials, memory formation and learning in matter, bioactive systems, and artificial life. This textbook introduces key phenomena and concepts in soft matter from a modern perspective, marrying established knowledge with the latest developments and applications. The presentation integrates statistical mechanics, dynamical systems, and hydrodynamic approaches, emphasizing conservation laws and broken symmetries as guiding principles while paying attention to computational and machine learning advances. The book features introductory chapters on fluid mechanics, elasticity, and stochastic phenomena and also covers advanced topics such as pattern formation and active matter. it discusses technological applications as well as relevant phenomena in the life sciences and offers perspectives on emerging research directions"--