Polymer-Solvent Molecular Compounds

Polymer-Solvent Molecular Compounds PDF

Author: Jean-Michel Guenet

Publisher: Elsevier

Published: 2010-07-07

Total Pages: 315

ISBN-13: 9780080555034

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Crystallisable polymers represent a large share of the polymers used for manufacturing a wide variety of objects, and consequently have received continuous attention from scientists these past 60 years. Molecular compounds from crystallisable polymers, particularly from synthetic polymers, are receiving growing interest due to their potential application in the making of new materials such as multiporous membranes capable of capturing large particles as well as small pollutant molecules. Polymer-Solvent Molecular Compounds gives a detailed description of these promising systems. The first chapter is devoted to the presentation of important investigational techniques and some theoretical approaches. The second chapter is devoted to biopolymers, the first polymers known to produce molecular compounds, chiefly with water. The third chapter deals with synthetic polymers where compound formation is either due to hydrogen-bonding or to electrostatic interactions. The fourth chapter describes intercalates and clathrates systems for which compound formation is mainly due to a molecular recognition process. First book on the subject Gives a short but exhaustive description of investigational tools Covers both biopolymers and synthetic polymers Uses temperature-concentration phase diagrams abundantly for describing the systems Describes systems from the nano to the microscopic level, including mechanical properties

Polymer-Solvent Complexes and Intercalates

Polymer-Solvent Complexes and Intercalates PDF

Author: Jean-Michel Guenet

Publisher: John Wiley & Sons

Published: 2001-08-15

Total Pages: 304

ISBN-13: 9783527303281

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This volume contains the proceedings of the 3rd International Conference on Polymer-Solvent Complexes and Intercalates held in Besancon, France in August 2000. As the reader will discover, results from various topics involving polymers, polyelectrolytes, polymer-like systems (self-assembling molecules, biological molecules), surfaces etc. were presented and discussed. They highlight the growing impact of this field on various scientific domains, and also the building of a scientific community concerned by the same questions.

The Science of Polymer Molecules

The Science of Polymer Molecules PDF

Author: Richard H. Boyd

Publisher: Cambridge University Press

Published: 1993

Total Pages: 436

ISBN-13: 9780521565080

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An introduction concerning the synthesis, structure and properties of the individual molecules constituting polymeric materials.

Macromolecular Solutions

Macromolecular Solutions PDF

Author: Raymond B. Seymour

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 244

ISBN-13: 1483154289

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Macromolecular Solutions: Solvent-Property Relationships in Polymers is a collection of papers presented at a symposium on Macromolecular Solutions, held New York City on August 23-28, 1981, sponsored by the American Chemical Society at its 182nd national meeting. This book is composed of 19 chapters and begins with discussions on the concept, application, and analysis of solubility parameters of polymers. The succeeding chapters deal with the role of solubility parameters in polymer coating design and stress cracking of nylon. Considerable chapters are devoted to the preparation, properties, reactions, and analysis of various polymers and copolymers. These topics are followed by surveys of the polymer-surfactant interaction effect on polymer solution properties and the effects of methanol-gasoline mixtures on elastomers. The final chapters describe the residual solvent content effect on dissolution kinetics of polymers; the application of excimer fluorescence to measure polymer-solvent interactions; and a general procedure for the calculation of thermodynamic properties of polymer solutions. This book will be of great value to polymer chemists, manufacturers, and researchers.

Polymer-Solvent Complexes and Intercalates II

Polymer-Solvent Complexes and Intercalates II PDF

Author: Gaetano Guerra

Publisher: John Wiley & Sons

Published: 1999-10-15

Total Pages: 272

ISBN-13: 9783527298068

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This book contains selected contributions of the symposium "Second International Conference on Polymer-Solvent Complexes and Intercalates" held in Ischia in August 1998. In detail many aspects of the polymer-solvent interactions and dynamics in solids, surfaces, gels and solutions are discussed. Polymer chemists and physicists will find this volume invaluable in updating their information and increasing their understanding in this important area.

π-Stacked Polymers and Molecules

π-Stacked Polymers and Molecules PDF

Author: Tamaki Nakano

Publisher: Springer Science & Business Media

Published: 2013-11-18

Total Pages: 280

ISBN-13: 4431541292

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This book covers broad aspects of the chemistry of π-stacked polymers and low-molecular-weight molecules, from synthesis through theory. It is intended for graduate students and researchers in academia and industry and consists of chapters written by renowned scientists who have made significant contributions to this field in the past decade. π-Stacked polymers and low-molecular-weight molecules are expected to replace main-chain conjugated polymers such as polyacetylenes and polythiophenes as organic conducting and energy-transferring substances that are important as materials for photo-electronic applications. π-Stacked polymers and molecules have significant advantages over main-chain conjugated polymers, i.e., high solubility in solvents, large freedom in molecular design, and colorless nature.

Solvent Crazing of Polymers

Solvent Crazing of Polymers PDF

Author: A.L. Volynskii

Publisher: Newnes

Published: 2012-12-02

Total Pages: 423

ISBN-13: 0444596569

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The problems related to crazing in polymers are of special interest to polymer scientists since only polymers display this universal phenomenon and no analogues are available for low-molecular-mass compounds. The important problems of solvent crazing and the development of a universal description of polymer structure and properties have received much attention from many leading scientists. Nevertheless, some aspects of polymer crazing are still unclear, and scientific activities in this area are in progress. This work provides an up-to-date account of scientific advances in the area of solvent crazing. The principal features and stages of solvent crazing (craze nucleation, craze tip advance, craze thickening, and craze collapse at high strains) are described. Additionally, the authors present information concerning the activities of Russian scientists in this area, which might have escaped the attention of their colleagues because of the language barrier.

Synthesis and Properties of Low- and High Molecular Compounds

Synthesis and Properties of Low- and High Molecular Compounds PDF

Author: Gennadiĭ Efremovich Zaikov

Publisher: Nova Publishers

Published: 2006

Total Pages: 362

ISBN-13: 9781594547164

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The main goal of this book is to describe the synthesis and properties of low and high-molecular compounds on the quantitative level. Special attention was given to composition materials based on polymers and dispersed wood, the mechanism of HCL elimination reactions via a four-centre transition state during PVC thermal destruction, swelling of the filled polymer compositions, structure and properties of combined systems based on butadiene-nitrile and ternary ethylene-propylene elastomers, intensification mass transfer processes in fast liquid-phase chemical reactions, the examples of hetero-nanophase kinetic description of photochemical reactions, the nanometric particle-like local structures and their implications in polymer behaviour, fractal physical chemistry of polymer solutions, modification of polycyanurates by polyethers, polyesters and polyurethanes, hybrid and interpenetrating polymer networks. This collection includes articles devoted to production of polymers, polymeric mixtures, composite and filled polymers, questions of expanding lifetime of polymeric articles, biologically active substances, modification of polymers and polymer-analogous transformations, fractal physical chemistry of polymer solutions, the study of structural transformations in polymers and some other questions. Of special attention are also production of pure substances and protection of the environment.

The Fractal Physical Chemistry of Polymer Solutions and Melts

The Fractal Physical Chemistry of Polymer Solutions and Melts PDF

Author: G. V. Kozlov

Publisher: CRC Press

Published: 2013-12-12

Total Pages: 336

ISBN-13: 1926895819

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This book provides an important structural analysis of polymer solutions and melts, using fractal analysis. The book covers the theoretical fundamentals of macromolecules fractal analysis. It then goes on to discuss the fractal physics of polymer solutions and the fractal physics of melts. The intended audience of the book includes specialists in chemistry and physics of polymer synthesis and those in the field of polymers and polymer composites processing.