Polymer Aging at the Cutting Edge

Polymer Aging at the Cutting Edge PDF

Author: Gennadiĭ Efremovich Zaikov

Publisher: Nova Publishers

Published: 2002

Total Pages: 186

ISBN-13: 9781590334447

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Twenty-one papers collected here report on the latest work in polymer ageing, looking at aspects including the ageing of polyester resin under moisture action, kinetic peculiarities of synthesis of Adamantan- containing polyamidoacids and polyimides, the influence of intensive mechanical treatment on decomposition of barium peroxide, and ecological aspects of manufacture and application of highly pure liquid substances. Biodegradable blends of starch and cellulose derivatives, the quantum chemical calculation of components of biosynthesis of adrenaline, low combustible poly(vinyl chloride) compositions with mixtures of plasticiSers, and inhibited oxidation of polypropylene melt are some other topics discussed.

Biodamage and Biodegradation of Polymeric Materials

Biodamage and Biodegradation of Polymeric Materials PDF

Author: Elena L Pekhtasheva

Publisher: Smithers Rapra

Published: 2012-08-31

Total Pages: 260

ISBN-13: 1847357539

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The issue of biodamages comprises a wide range of scientific and practical tasks associated with protection of raw materials and products against damage by bacteria, fungi, insects and rodents during long-term storage, production, transportation and operation. The biodegradation is used for degradation and utilization of worn-out materials and articles. This research is urgent for ecology and the struggle against environmental contamination. The biodamage problem is both scientifically complex and practically diverse. Scientifically, it is based on the knowledge of material science, biology and chemistry.The first objective of this book is to provide detailed information on the three interrelated parts: bacteria and fungi (the source of biodamages); insects and rodents (materials and products depredators); and materials and products damaged by living organisms. The most modern data on morphology and physiology of biodegrading microorganisms are presented. The second objective of this book is to provide the reader with a systematisation of biological degradation on both natural and synthetic materials and products (plastics, textile, fibres, leather and fur, wood and so on). Problems of utilisation of polymeric wastes using microorganisms are discussed and main protection methods and technology for raw materials and semi-products against biodamages are shown. Practical recommendation for struggle against biodamage of materials by insects (moth, leather beetles, wood-fretters, cockroaches and termites) and rodents (mice and rats) are given.Since 1960 the biodamage problem received the official status as a large international and practical direction at the junction of sciences and practice of mankind and pooling efforts of various specialists. The final objective of this book is to illustrate that the problem of biodamages is very real today because it is relevant to many aspects of our everyday lives.This volume is intended to be a practical guide on biodamage and biodegradation of polymeric materials and a quick reference to students and researchers from academia and the industry.

Key Engineering Materials, Volume 2

Key Engineering Materials, Volume 2 PDF

Author: François Kajzar

Publisher: CRC Press

Published: 2014-02-18

Total Pages: 430

ISBN-13: 1482224275

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This book provides innovative chapters on the growth of educational, scientific, and industrial research activities among chemists, biologists, and polymer and chemical engineers and provides a medium for mutual communication between international academia and the industry. It presents significant research and reviews reporting new methodologies and important applications in the fields of industrial chemistry, industrial polymers and biotechnology as well as includes the latest coverage of chemical databases and the development of new computational methods and efficient algorithms for chemical software and polymer engineering.

Bioscience Methodologies in Physical Chemistry

Bioscience Methodologies in Physical Chemistry PDF

Author: Alberto D'Amore

Publisher: CRC Press

Published: 2013-07-29

Total Pages: 514

ISBN-13: 1482206153

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The field of bioscience methodologies in physical chemistry stands at the intersection of the power and generality of classical and quantum physics with the minute molecular complexity of chemistry and biology. This book provides an application of physical principles in explaining and rationalizing chemical and biological phenomena. It does not stick to the classical topics that are conventionally considered as part of physical chemistry; instead it presents principles deciphered from a modern point of view, which is the strength of this book.

Progress in Chemometrics Research

Progress in Chemometrics Research PDF

Author: Alexey L. Pomerantsev

Publisher: Nova Publishers

Published: 2005

Total Pages: 342

ISBN-13: 9781594542572

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Chemometrics is the chemical discipline that uses mathematical, statistical and other methods employing formal logic: to design or select optimal measurement procedures and experiments, and -- to provide maximum relevant chemical information by analysing chemical data. Being conceived as a branch of analytical chemistry, chemometrics now is a general approach. It extracts relevant information out of measured data, regardless of their origin: chemical, physical, biological, etc. Chemometrics has been applied in different areas, and most successfully in multivariate calibration, pattern recognition, classification and discriminant analysis, multivariate modelling, and monitoring of processes. The main chemometric principle is a concept of hidden data structures that can be found using methods of multivariate data analysis. These are the well-known statistic tools such as partial least squares (PLS), soft independent modelling of class analogy (SIMCA), principal-component regression (PCR), wavelet analysis, and many others. Current activities of chemometricians fall into two main categories: (1) development of new methods for manipulating multivariate data and (2) new applications of the known chemometric techniques in different areas such as environment control, food industry, agriculture, medicine, and engineering.

Aging and Stabilization of Polymers

Aging and Stabilization of Polymers PDF

Author: M. B. Neiman

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 374

ISBN-13: 146158549X

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The need for a broad development of the production of polymer ma terials has become evident. All these materials are subject to various types of aging (destruction); hence, stabilizers which permit the stor age, reprocessing, and use of polymer materials without any appreci able change in their properties must be introduced into them. In recent years, this problem of stabilizing polymers has attracted the attention of many scientists and technologists, both in the USSR and abroad. The scientific basis of the foreign studies will be found in a number of theo retical premises, but chiefly the theory of chain reactions with un branched chains. In the Soviet Union, the concepts of Academician N. N. Semenov on chain reactions with degenerate branches have become the starting point of theoretical studies of the stabilization and destruction of polymers. Soviet scientists have developed a theory of critical concentrations of antioxidants and have shown that the processes of stabilization have a very complex chemical character. The nature of the polymers them selves greatly affects these processes and consequently, different stabil izers are required for polymers of different structures. In addition, it has been shown that the antioxidants used thus far can not only cause chain termination, but can also initiate oxidation and give rise to de generate branches.

Chemical Reactions in Liquid and Solid Phase

Chemical Reactions in Liquid and Solid Phase PDF

Author: Gennadiĭ Efremovich Zaikov

Publisher: Nova Publishers

Published: 2003

Total Pages: 212

ISBN-13: 9781590338544

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This collection examines the influence of liquid and solid states during radical, ionic, and molecular reactions, specifically how cage effect, diffusion hindrance, donor-acceptor interaction, electrostatic interaction, dispersion forces and other factors affect the rates, mechanism, and direction of chemical reactions. Topics of the 11 papers include spherical hydrogel particles for endovascular embolisation, the synthesis and thermal degradation of phenolic resins, mono-molecular chain termination in dimethacrylate postpolymerisation, and calculating the effect of chain deformation on macromolecule scission. Most of the researchers work in Russia.