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Physical Chemistry of Polymer Solutions

Author: K. Kamide

Publisher: Elsevier

Published: 2000-10-16

Total Pages: 675

ISBN-13: 0080538886

This book is mainly concerned with building a narrow but secure ladder which polymer chemists or engineers can climb from the primary level to an advanced level without great difficulty (but by no means easily, either). This book describes some fundamentally important topics, carefully chosen, covering subjects from thermodynamics to molecular weight and its distribution effects. For help in self-education the book adopts a "Questions and Answers" format. The mathematical derivation of each equation is shown in detail. For further reading, some original references are also given. Numerous physical properties of polymer solutions are known to be significantly different from those of low molecular weight solutions. The most probable explanation of this obvious discrepancy is the large molar volume ratio of solute to solvent together with the large number of consecutive segments that constitute each single molecule of the polymer chains present as solute. Thorough understanding of the physical chemistry of polymer solutions requires some prior mathematical background in its students. In the original literature, detailed mathematical derivations of the equations are universally omitted for the sake of space-saving and simplicity. In textbooks of polymer science only extremely rough schemes of the theories and then the final equations are shown. As a consequence, the student cannot learn, unaided, the details of the theory in which he or she is interested from the existing textbooks; however, without a full understanding of the theory, one cannot analyze actual experimental data to obtain more basic and realistic physical quantities. In particular, if one intends to apply the theories in industry, accurate understanding and ability to modify the theory are essential.

Polymer Solutions

Author: Iwao Teraoka

Publisher: John Wiley & Sons

Published: 2004-04-07

Total Pages: 355

ISBN-13: 0471460761

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Polymer Solutions: An Introduction to Physical Properties offers a fresh, inclusive approach to teaching the fundamentals of physical polymer science. Students, instructors, and professionals in polymer chemistry, analytical chemistry, organic chemistry, engineering, materials, and textiles will find Iwao Teraoka’s text at once accessible and highly detailed in its treatment of the properties of polymers in the solution phase. Teraoka’s purpose in writing Polymer Solutions is twofold: to familiarize the advanced undergraduate and beginning graduate student with basic concepts, theories, models, and experimental techniques for polymer solutions; and to provide a reference for researchers working in the area of polymer solutions as well as those in charge of chromatographic characterization of polymers. The author’s incorporation of recent advances in the instrumentation of size-exclusion chromatography, the method by which polymers are analyzed, renders the text particularly topical. Subjects discussed include: Real, ideal, Gaussian, semirigid, and branched polymer chains Polymer solutions and thermodynamics Static light scattering of a polymer solution Dynamic light scattering and diffusion of polymers Dynamics of dilute and semidilute polymer solutions Study questions at the end of each chapter not only provide students with the opportunity to test their understanding, but also introduce topics relevant to polymer solutions not included in the main text. With over 250 geometrical model diagrams, Polymer Solutions is a necessary reference for students and for scientists pursuing a broader understanding of polymers.

Thermodynamics of Polymer Solutions

Author: Kenji Kamide

Publisher: Elsevier Publishing Company

Published: 1990

Total Pages: 672

ISBN-13:

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This is the first self-contained book on the thermodynamics and critical phenomena of polymer solutions, ranging from the rather elementary level to the advanced and up-to-date level. The book covers the rigorous theories of phase equilibrium, computer experiments based on these theories, as well as actual experiments, molecular fractionation and application to membrane and fiber production. An extensive list of references and literature data on the thermodynamic interaction x-parameter, critical point, fractionation and polymer blends is also provided. This book should prove invaluable for courses on polymer science, thermodynamics and polymer solutions at graduate, university and polytechnic level.

The Fractal Physical Chemistry of Polymer Solutions and Melts

Author: G. V. Kozlov

Publisher: CRC Press

Published: 2013-12-12

Total Pages: 336

ISBN-13: 1926895819

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This book provides an important structural analysis of polymer solutions and melts, using fractal analysis. The book covers the theoretical fundamentals of macromolecules fractal analysis. It then goes on to discuss the fractal physics of polymer solutions and the fractal physics of melts. The intended audience of the book includes specialists in chemistry and physics of polymer synthesis and those in the field of polymers and polymer composites processing.

New Trends in Physics and Physical Chemistry of Polymers

Author: Lieng-Huang Lee

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 640

ISBN-13: 1461305438

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Between June 6-10, 1988, the Third Chemical Congress of North America was held at the Toronto Convention Center. At this rare gathering, fifteen thousand scientists attended various symposia. In one of the symposia, Professor Pierre-Gilles de Gennes of College de France was honored as the 1988 recipient of the Amer ican Chemical Society Polymer Chemistry Award, sponsored by Mobil Chemical Corporation. For Professor de Gennes, this international setting could not be more fitting. For years, he has been a friend and a lecturer to the world scientific community. Thus, for this special occasion, his friends came to recount many of his achievements or report new research findings mostly derived from his theories or stimulated by his thoughts. In this volume of Proceedings, titled New Trends in Physics and Physical Chemistry of Polymers, we are glad to present the revised papers for the Symposium and some contributed after the Symposium. In addition, we intend to include most of the lively discussions that took plaGe during the conference. This volume contains a total of thirty-six papers divided into six parts, primarily according to the nature of the subject matter: • Adsorption of Colloids and Polymers. • Adhesion, Fractal and Wetting of Polymers. • Dynamics and Characterization of Polymer Solutions. • Diffusion and Interdiffusion of Polymers. • Entanglement and Reptation of Polymer Melts and Networks. • Phase Transitions and Gel Electrophoresis.

CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures

Author: Christian Wohlfarth

Publisher: CRC Press

Published: 2005-01-27

Total Pages: 652

ISBN-13: 1420037692

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This handbook provides the only complete collection of high-pressure thermodynamic data that is essential for understanding polymer solutions. It contains data on vapor-liquid equilibria and gas solubilities, liquid-liquid equilibria, high-pressure fluid phase equilibria for polymer systems in supercritical fluids, enthalpic and volumetric data, as well as second virial coefficients all at elevated pressures. It covers all areas needed by researchers and engineers who handle polymer systems in supercritical fluids; materials science and technological applications such as computerized predictive packages; and chemical and biochemical processes, such as synthesis and characterization, fractionation, separation, purification, and finishing of polymers and related materials.

Polymer Solutions

Author: Iwao Teraoka

Publisher: Wiley-Interscience

Published: 2002-03-07

Total Pages: 370

ISBN-13:

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A broad examination of the physical properties of solutions Polymer Solutions: An Introduction to Physical Properties offers a fresh, inclusive approach to teaching the fundamentals of physical polymer science. Students, instructors, and professionals in polymer chemistry, analytical chemistry, organic chemistry, engineering, materials, and textiles will find Iwao Teraoka's text at once accessible and highly detailed in its treatment of the properties of polymers in the solution phase. Teraoka's purpose in writing Polymer Solutions is twofold: to familiarize the advanced undergraduate and beginning graduate student with basic concepts, theories, models, and experimental techniques for polymer solutions; and to provide a reference for researchers working in the area of polymer solutions as well as those in charge of chromatographic characterization of polymers. The author's incorporation of recent advances in the instrumentation of size-exclusion chromatography, the method by which polymers are analyzed, renders the text particularly topical. Subjects discussed include: * Real, ideal, Gaussian, semirigid, and branched polymer chains * Polymer solutions and thermodynamics * Static light scattering of a polymer solution * Dynamic light scattering and diffusion of polymers * Dynamics of dilute and semidilute polymer solutions Study questions at the end of each chapter not only provide students with the opportunity to test their understanding, but also introduce topics relevant to polymer solutions not included in the main text. With over 250 geometrical model diagrams, Polymer Solutions is a necessary reference for students and for scientists pursuing a broader understanding of polymers.

Physical Chemistry of Polymers

Author: Sebastian Seiffert

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2020-04-20

Total Pages: 267

ISBN-13: 3110672847

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This book introduces the concepts of physical chemistry of polymers. It provides a basis to bridge polymer chemistry, which targets microscopic chain structures, and polymer engineering, which targets macroscopic material properties and functions. Topics covered are single chain statistics, multi-chain interactions, and chain dynamics, both from a viewpoint of structure, properties (mostly mechanical ones), and their interrelation. In all that, the author encourages the reader to think conceptually.

Polymers in Solution

Author: Jacques des Cloizeaux

Publisher: OUP Oxford

Published: 2010-08-19

Total Pages: 944

ISBN-13: 0199588937

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This book is devoted to the static properties of flexible polymers in solution. It presents the progress made by both theory and experiment in the years up to its original publication in 1990, and remains one of the most advanced books available on the subject.

Polymer Solutions

Author: H. Fujita

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 388

ISBN-13: 0444596631

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Remarkable progress has been made in the last two decades in the study of concentrated polymer solutions leading to many new concepts, theories, and techniques in the field of polymer science. Any description of the theory of polymer solutions is now insufficient unless both concentrated and dilute solutions are given equal attention. This book reviews recent developments in the study of dilute and concentrated polymer solutions, emphasizing mainly the typical equilibrium and steady-state dynamic properties of linear homopolymers. The author strives to clarify the gap which still remains open between current theories and well-documented experimental results, thereby stimulating further efforts toward a more accurate understanding of polymer solutions. The book contains a collection of typical experimental data and their comparison with current theories, molecular or phenomenological, a summary of recent advances in the physics of concentrated polymer solutions and melts, and an elementary account of the renormalization group theory as applied to dilute solutions. Polymer Solutions should prove invaluable as a reference work for graduate students and specialists in this field.