Photostabilization of Polymers

Photostabilization of Polymers PDF

Author: J.F. Rabek

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 607

ISBN-13: 9400907478

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During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40-60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. Increasing the stability of polymers and plastics towards heat, light, atmospheric oxygen and other environmental agents and weathering conditions has always been a very important problem. The photochemical instability of most of polymers limits them to outdoor application, where they are photo degraded fast over periods ranging from months to a few years. To the despair of technologists and consumers alike, photodegrada tion and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In many cases, improved methods of preparation and purification of both monomers and polymers yield products of better quality and higher resistance to heat and light. However, without stabilization of polymers by applica tion of antioxidants (to decrease thermal oxidative degradation) and photostabilizers (to decrease photo-oxidative degradation) it would be impossible to employ polymers and plastics in everyday use.

Polymer Photodegradation

Polymer Photodegradation PDF

Author: J.F. Rabek

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 679

ISBN-13: 9401112746

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During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40~60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. The photochemical instability of most polymers limits their outdoor application as they are photodegraded quickly over periods from months to a few years. To the despair of technologists and consumers alike, photodegradation and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In order to improve polymer photostability there has been a very big effort during the last 30 years to understand the mechanisms involved in photodegradation and environmental ageing. This book represents the author's attempt, based on his 25 years' experience in research on photodegradation and photo stabilization, to collect and generalize a number of available data on the photodegradation of polymers. The space limitation and the tremendous number of publications in the past two decades have made a detailed presentation of all important results and data difficult. The author apologizes to those whose work has not been quoted or widely presented in this book. Because many published results are very often contradictory, it has been difficult to present a fully critical review of collected knowledge, without antagonizing authors. For that reason, all available theories, mechanisms and different suggestions have been presented together, and only practice can evaluate which of them are valid.

Photodegradation of Polymers

Photodegradation of Polymers PDF

Author: Jan F. Rabek

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 222

ISBN-13: 3642800904

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In this book on physical characteristics and practical aspects of polymer photodegradation Rabek emphasizes the experimental work on the subject. The most important feature of the book is the physical interpretation of polymer degradation, e.g. mechanism of UV/light absorption, formation of excited states, energy transfer mechanism, kinetics, dependence on physical properties of macromolecules and polymer matrices, formation of mechanical defects, practics during environmental ageing. He includes also some aspects of polymer photodegradation in environmental and space condition.

Polypropylene

Polypropylene PDF

Author: J. Karger-Kocsis

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 988

ISBN-13: 9401144214

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My heart sank when I was approached by Dr Hastings and by Professor Briggs (Senior Editor of Materials Science and Technology and Series Editor of Polymer Science and Technology Series at Chapman & Hall, respectively) to edit a book with the provisional title Handbook of Poly propylene. My reluctance was due to the fact that my former book [1] along with that of Moore [2], issued in the meantime, seemed to cover the information demand on polypropylene and related systems. Encour aged, however, by some colleagues (the new generation of scientists and engineers needs a good reference book with easy information retrieval, and the development with metallocene catalysts deserves a new update!), I started on this venture. Having some experience with polypropylene systems and being aware of the current literature, it was easy to settle the titles for the book chapters and also to select and approach the most suitable potential contributors. Fortunately, many of my first-choice authors accepted the invitation to contribute. Like all editors of multi-author volumes, I recognize that obtaining contributors follows an S-type curve of asymptotic saturation when the number of willing contributors is plotted as a function of time. The saturation point is, however, never reached and as a consequence, Dear Reader, you will also find some topics of some relevance which are not explicitly treated in this book (but, believe me, I have considered them).

Plastics Additives

Plastics Additives PDF

Author: G. Pritchard

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 650

ISBN-13: 9401158622

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Although plastics are extremely successful commercially, they would never reach acceptable performance standards either in properties or processing without the incorporation of additives. With the inclusion of additives, plastics can be used in a variety of areas competing directly with other materials, but there are still many challenges to overcome. Some additives are severely restricted by legislation, others interfere with each other-in short their effectiveness varies with circumstances. Plastics Additives explains these issues in an alphabetical format making them easily accessible to readers, enabling them to find specific information on a specific topic. Each additive is the subject of one or more articles, providing a suffinct account of each given topic. An international group of experts in additive and polymer science, from many world class companies and institutes, explain the recent rapid changes in additive technology. They cover novel additives (scorch inhibitors, compatibilizers, surface-modified particulates etc.), the established varieties (antioxidants, biocides, antistatic agents, nucleating agents, fillers, fibres, impact modifiers, plasticizers) and many others, the articles also consider environmental concerns, interactions between additives and legislative change. With a quick reference guide and introductory articles that provide the non-specialist and newcomer with relevant information, this reference book is essential reading for anyone concerned with plastics and additives.

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