Oxidation of Organic Compounds

Oxidation of Organic Compounds PDF

Author: N. M. Emanuel

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 628

ISBN-13: 1483145115

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Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.

Basic Principles of Organic Chemistry

Basic Principles of Organic Chemistry PDF

Author: John D. Roberts

Publisher:

Published: 1977

Total Pages: 1596

ISBN-13: 9780805383218

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Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Metal-Catalyzed Oxidations of Organic Compounds

Metal-Catalyzed Oxidations of Organic Compounds PDF

Author: Roger Sheldon

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 447

ISBN-13: 0323150047

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Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Oxidation of Organic Compounds by Dioxiranes

Oxidation of Organic Compounds by Dioxiranes PDF

Author: Waldemar Adam

Publisher: John Wiley & Sons

Published: 2009-04-27

Total Pages: 684

ISBN-13: 0470454075

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A Comprehensive Monograph on Dioxirane Oxidations The oxidation of organic compounds is one of the most important methods for the introduction and manipulation of functional groups. Among the most modern of these transformations is the use of the fascinating family of oxidants known as dioxiranes. A dioxirane can, by transferring one of its oxygen atoms to organic substrates, effect a remarkable array of oxidative processes such as epoxidation, C-H insertion, and heteroatom (N, S, P, I) oxidation. In addition to their versatility, dioxiranes can be generated catalytically under mild conditions and produce no toxic waste stream as part of the oxidation process. Moreover, some of the most exciting recent developments involve the enantioselective introduction of oxygen atoms via chiral dioxiranes. This book represents the first single volume dedicated to the comprehensive coverage of the myriad of oxidations of organic compounds performed by dioxiranes. The contents of this book are extracted from comprehensive reviews of the topics contained in the Organic Reactions series and cover the oxidation of alkenes and the oxidation of all other organic substrates. In addition, updated lists of references for each of the chapters are provided, bringing the literature coverage up to June 2008. The authors of these chapters are among the pioneers of dioxirane chemistry and draw on extensive firsthand knowledge of the subject. As with all Organic Reactions content, the presentation emphasizes the preparative aspects of the reactions and pays particular attention throughout to substrate scope, limitations, structural and electronic influences, and stereochemical aspects. For the student or experienced practitioner, both general guidelines for carrying out the reactions as well as detailed experimental procedures are provided. Most importantly, all known examples of dioxirane oxidations have been compiled in easy-to-scan tables covering over 500 pages. Oxidation of Organic Compounds by Dioxiranes is an indispensable working resource for organic and medicinal chemists as well as anyone wishing to own the definitive treatise on this fascinating and useful class of oxidants.

Oxidation in Organic Synthesis

Oxidation in Organic Synthesis PDF

Author: V. K. Ahluwalia

Publisher: CRC Press

Published: 2012-02-13

Total Pages: 323

ISBN-13: 9781466506015

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Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions.

Oxidation and Antioxidants in Organic Chemistry and Biology

Oxidation and Antioxidants in Organic Chemistry and Biology PDF

Author: Evgeny T. Denisov

Publisher: CRC Press

Published: 2005-03-29

Total Pages: 1020

ISBN-13: 142003085X

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Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information

Chromium Oxidations in Organic Chemistry

Chromium Oxidations in Organic Chemistry PDF

Author: G. Cainelli

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 272

ISBN-13: 3642693628

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Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .

Design of Thermal Oxidation Systems for Volatile Organic Compounds

Design of Thermal Oxidation Systems for Volatile Organic Compounds PDF

Author: David A Lewandowski

Publisher: CRC Press

Published: 2017-12-14

Total Pages: 364

ISBN-13: 1351455710

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Controlling the emission of volatile organic compounds (VOC) became a very prominent environmental issue with the passage of the 1990 Clean Air Act Amendments, and will continue to be an environmental priority through the next decade. No single technology has played as important a role in the control of VOC emissions as thermal oxidation. It has the ability to destroy VOCs in a one-step process that produces innocuous by-products. Design of Thermal Oxidation Systems for Volatile Organic Compounds provides all the information needed for developing a thermal oxidation design in a single reference. It covers design, operation, and maintenance as well as the principles behind the classification of volatile organic compounds as hazardous waste. The author explores the primary purpose of thermal oxidizers and discusses their limitations. The book provides: practical, complete, and concise thermal oxidizer design principles an outline of state-of-the-art design principles a practical rather than theoretical approach real industrial examples in each chapter With the new regulations that affect VOC emissions, engineers from such diverse fields as oil refining, chemical distillation and separation processes, and pharmaceutical industries will need to design and implement thermal oxidation systems. Design of Thermal Oxidation Systems for Volatile Organic Compounds provides a reference to the entire design process, from conceptualization to operation and maintenance.

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