Author: Thomas Onak
Publisher: Elsevier
Published: 2012-12-02
Total Pages: 373
ISBN-13: 0323153615
DOWNLOAD EBOOK →Organoborane Chemistry deals with the chemistry of organoboranes, with emphasis on compounds containing a carbon-boron bond. The structure and physical properties of organoboranes are discussed, along with the reactions of three-coordinate and four-coordinate organoboranes, organodiboranes, and other organopolyboranes such as organotetraboranes and organopentaborane compounds. Comprised of seven chapters, this book begins with an overview of multistep synthetic or degradative reactions involving organoboron compounds, along with the nomenclature for such compounds. The next chapter examines the structure and physical properties of organoboranes, with emphasis on boron-carbon bond lengths, electronic transitions, and molecular orbital calculations. Subsequent chapters focus on three-coordinate and four-coordinate organoboranes, together with their synthesis, reactions, and properties; hydroboration and dehydroboration of organodiboranes; and the synthesis, reactions, and physical properties of other organopolyboranes such as organotetraboranes, organopentaborane compounds, and organodecaborane compounds. The final chapter is devoted to cyclic boron-carbon systems and the applications of organoboron compounds. This monograph should be of interest to organic chemists.
Author: R. J. Brotherton
Publisher: Elsevier
Published: 2016-10-12
Total Pages: 401
ISBN-13: 1483146359
DOWNLOAD EBOOK →Progress in Boron Chemistry, Volume 3 discusses the chemistry and applications of boron and its compounds. This book offers a detailed treatment of five areas of boron chemistry. Organized into five chapters, this volume begins with an overview of the use of boric acid to favor alcohol formation in the air oxidation of hydrocarbons. This text then explains the standard procedure for hydrocarbon oxidation, which consists of passing air or a dilute oxygen in nitrogen stream via a suspension of boric acid in the heated substrate. Other chapters describe the radical-catalyzed addition of carbon tetrachloride to dibutyl vinylboronate and examine the growing interest in boron–nitrogen chemistry. This book discusses as well the polar addition of hydrogen bromide to unsaturated boronic esters. The final chapter deals with the chemical properties of organic boron–sulfur compounds. This book is a valuable resource for chemists, organic chemists, students, and research workers.
Author: H. Steinberg
Publisher: Elsevier
Published: 2013-09-03
Total Pages: 499
ISBN-13: 1483224899
DOWNLOAD EBOOK →Progress in Boron Chemistry, Volume I is a 10-chapter text that covers the advances in the chemistry of various boron compounds and their applications. The opening chapter deals with the chemistry of compounds containing boron-boron bonds, followed by a brief overview of some aspects of the coordination chemistry of boron. The subsequent chapters discuss the molecular structures of boron hydrides and the chemotherapeutic potential of boron compounds. Other chapters explore the chemistry of other boron compounds, including heteroaromatic boron compounds, organoperoxyboranes, organoboron heterocycles, and boronic acids. The concluding chapter describes the NMR studies of boron compounds. This book is of value to organic, inorganic, and analytical chemists.
Author: Matthew G Davidson
Publisher: Royal Society of Chemistry
Published: 2007-10-31
Total Pages: 555
ISBN-13: 1847550649
DOWNLOAD EBOOK →The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.
Author: Elena Fernández
Publisher: Thieme Chemistry
Published: 2020
Total Pages: 0
ISBN-13: 9783132429710
DOWNLOAD EBOOK →The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.
Author: Elena Fernández
Publisher: Springer
Published: 2015-03-04
Total Pages: 334
ISBN-13: 3319130544
DOWNLOAD EBOOK →The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.