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Organic Solid-State Reactions

Author: Fumio Toda

Publisher: Springer Science & Business Media

Published: 2013-03-14

Total Pages: 279

ISBN-13: 9401700893

Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound. Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.

Organic Solid-State Chemistry—2

Author: M. D. Cohen

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 231

ISBN-13: 1483284697

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Organic Solid-State Chemistry–2 presents the solid state reactions in molecular crystals. This book discusses the correlations of the chemical structures of products from organic solid state reactions with the molecular packing in the reactant crystal structures. Organized into 10 chapters, this book begins with an overview of the molecular behavior after the chemical transition state. This text then examines the electron paramagnetic resonance methods, which offer many features in connection with the study of chemical reactions in which a paramagnetic species is a product or a reactant. Other chapters consider the interpretation of radiationless transitions, thermal reactions, and photochemical decompositions and rearrangements. The final chapter deals with the experimental results concerning electron and hole production in anthracene crystals, with emphasis on the relevance of these studies to the fundamental question of the nature of the excess electron states in these low mobility crystals. This book is a valuable resource for solid state chemists, photochemists, spectroscopists, scientists, and research workers.

Organic Solid State Chemistry

Author: Gautam R. Desiraju

Publisher: Elsevier Publishing Company

Published: 1987

Total Pages: 580

ISBN-13:

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With the growing recognition that many organic reactions may be conducted easily in the solid state and that organic solids may have unique optical/electronic properties, there has been much interest - in both academia and industry - in the subject of organic solid state chemistry. This book provides, for the first time, a coherent, unified view of the subject. It describes the packing of molecular crystals and how this packing influences chemical reactions in the solid state. It is concerned with various means of studying the chemistry and physics of molecules in constrained environments. Both experimental and theoretical approaches are discussed. Finally, it tackles the question of prediction of crystal packing, or crystal engineering'. The strength of the book lies in the twin approach adopted, namely that both conceptual and comprehensive chapters are present, in almost equal numbers.

Organic Solid-State Reactions

Author: Fumio Toda

Publisher:

Published: 2002-04-30

Total Pages: 284

ISBN-13: 9789401700900

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Green Organic Reactions

Author: Gopinathan Anilkumar

Publisher: Springer Nature

Published: 2021-03-27

Total Pages: 349

ISBN-13: 9813368977

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This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.

Reactions in the Solid State

Author: Michael E. Brown

Publisher: Elsevier

Published: 1980-01-01

Total Pages: 355

ISBN-13: 0080868169

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The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

Solvent-free Organic Synthesis

Author: Koichi Tanaka

Publisher: John Wiley & Sons

Published: 2009-03-02

Total Pages: 476

ISBN-13: 9783527322640

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In this second edition of a best-selling handbook all the chapters have been completely revised and updated, while four completely new chapters have been added. In order to meet the needs of the practitioner, emphasis is placed on describing precisely the technology and know-how involved. Adopting a didactic and comprehensible approach, the book guides the reader through theory and applications, thus ensuring its warm welcome among the scientific community. An excellent, essential and exhaustive overview.

Solid State Chemistry

Author: Aaron Wold

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 250

ISBN-13: 9401114765

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The subject matterofsolid state chemistry lies within the spheres ofboth physical and inorganic chemistry. In addition, there is a large overlap with solid state physics and materials engineering. However, solid state chemistry has still to be recognized by the general body ofchemists as a legitimate subfield ofchemistry. The discipline is not even well defined as to content and has many facets that make writing a textbook a formidable task. The early studies carried out in the United States by Roland Ward and his co workers emphasized the synthesisofnew materials and the determination oftheir structure. His work on doped alkaline earth sulfides formed the basis for the development of infrared phosphors and his pioneering studies on oxides were important in understanding the structural features of both the perovskite oxides as well as the magnetoplumbites. In 1945, A. F. Wells published the first edition of Structural Inorganic Chemistry. This work attempts to demonstrate that the synthesis, structure, and properties of solids form an important part of inorganic chemistry. Now, after almost 50 years during which many notable advances have been made in solid state chemistry, it is still evident that the synthesis, structure determination, and properties of solids receive little attention in most treatments of inorganic chemistry. The development of the field since the early studies of Roland Ward (early 1940s) has been rapid.

Organic Solid-state Chemistry 2

Author:

Publisher:

Published: 1971

Total Pages:

ISBN-13:

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New Trends in Green Chemistry

Author: V.K. Ahluwalia

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 279

ISBN-13: 1402031750

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Organic chemistry has played a vital role in the development of diverse molecules which are used in medicines, agrochemicals and polymers. Most ofthe chemicals are produced on an industrial scale. The industrial houses adopt a synthesis for a particular molecule which should be cost-effective. No attention is paid to avoid the release of harmful chemicals in the atmosphere, land and sea. During the past decade special emphasis has been made towards green synthesis which circumvents the above problems. Prof. V. K. Ahluwalia and Dr. M. Kidwai have made a sincere effort in this direction. This book discusses the basic principles of green chemistry incorporating the use of green reagents, green catalysts, phase transfer catalysis, green synthesis using microwaves, ultrasound and biocatalysis in detail. Special emphasis is given to liquid phase reactions and organic synthesis in the solid phase. I must congratulate both the authors for their pioneering efforts to write this book. Careful selection of various topics in the book will serve the rightful purpose for the chemistry community and the industrial houses at all levels. PROF. JAVED IQBAL, PhD, FNA Distinguished Research Scientist & Head Discovery Research Dr. Reddy's Laboratories Ltd.