Organic Redox Systems

Organic Redox Systems PDF

Author: Tohru Nishinaga

Publisher: John Wiley & Sons

Published: 2015-11-25

Total Pages: 624

ISBN-13: 1118858727

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Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems Offers a useful guide for both academic and industrial chemists involved with organic electronic materials Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds

Organic Redox Systems

Organic Redox Systems PDF

Author: Tohru Nishinaga

Publisher: John Wiley & Sons

Published: 2015-12-30

Total Pages: 624

ISBN-13: 1118858743

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Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems Offers a useful guide for both academic and industrial chemists involved with organic electronic materials Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds

Redox Systems Under Nano-Space Control

Redox Systems Under Nano-Space Control PDF

Author: Toshikazu Hirao

Publisher: Springer Science & Business Media

Published: 2006-08-02

Total Pages: 302

ISBN-13: 3540295801

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The generation of novel redox systems under nano-space control is one of the most exciting fields in present organic, inorganic, and supramolecular chemistry. The authors have drawn together the newest information on the construction of such novel redox systems using nano-space control of complexation or molecular chain-induced spaces and metal- or self-assembled spaces through combining techniques in coordination, supramolecular, and bio-inspired chemistry. Such design on the nano level produces hybrid conjugated systems composed of transition and synthetic metals, metallohosts, redox-active self-assembled monolayers of helical peptides, DNA-directed metal arrays, photoactive antibody systems, chiral rotaxanes, and redox-active imprinted polymers. In the future, these systems will be the basis for novel selective electron-transfer reactions as well as new functional materials and catalysts.

Functionalized Redox Systems

Functionalized Redox Systems PDF

Author: Toshikazu Hirao

Publisher: Springer

Published: 2015-01-23

Total Pages: 158

ISBN-13: 4431553061

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In this book the authors describe how they reproduced the redox functions of biocatalysts artificially. It includes the introduction and discussion of synthetic reactions via electron transfer, hybrid π-conjugated systems, and biorganometallic conjugates as novel redox systems. The work was conducted in pioneering fields based on redox systems, in synthetic organic chemistry, synthetic materials chemistry, and bioorganometallic chemistry. The step-by-step process is illustrated by the three major parts of the book: redox reactions (selective synthetic methods using metal-induced redox reactions), redox systems (design and redox function of conjugated complexes with polyanilines or quinonediimines and molecular bowl sumanene), and design of bioorganometallic conjugates to induce chirality-organized structures (bio-related structurally controlled systems). This systematic and up-to-date description will be of special interest to graduate students who are meeting the new challenges of chemistry, as well as to post-doctoral researchers and other practicing chemists in both academic and industrial settings.

Design and Characterization of Organic Redox Molecules for Energy Applications

Design and Characterization of Organic Redox Molecules for Energy Applications PDF

Author: Patrick Timothy Sullivan

Publisher:

Published: 2023

Total Pages: 0

ISBN-13:

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My PhD research has focused on the design of organic redox materials for grid-scale energy applications. These organics, which can be produced from the existing petrochemical supply chain and eventually through a circular carbon economy, offer a more secure path than metals, which often present numerous sustainability concerns with international mining practices and limited reserves. Specially, I have focused on the application of these materials for redox flow battery, a promising technology to enable safe and scalable long-duration energy storage and support deep penetration of renewable solar and wind. Chapter One will focus on the historical development and fundamental principles of this emerging class of materials. Chapter Two and Chapter Three will demonstrate how the tunability of organic structures can be leveraged to design novel materials that overcome the historical performance and scalability challenges of conventional flow battery electrolytes. Finally, Chapter Four will demonstrate how organic molecules can also be used to enhance conventional redox systems. Overall, my research has paved the way for the widespread commercial application of organic redox materials and will hopefully spur additional innovation for the next generation of clean energy devices.

Fuel Cells Using Organic Redox Compounds

Fuel Cells Using Organic Redox Compounds PDF

Author: Jun Mizuguchi

Publisher:

Published: 1969

Total Pages: 24

ISBN-13:

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In living systems, hydrogen supplied from the TCA cycle is transferred to molecular oxygen and oxidized by the electron carrier system, thereby generating energy. It appears that the reversible redox system such as the electron carrier system has not yet been studied in vitro. It was considered that the system of cystine-cysteine containing ferric ion or that of quinone-hydroquinone containing an enzyme might act like the electron carrier system. The authors attempted to use the electron carrier system at the cathode of a fuel cell to obtain a greater amount of electric current. As a result, it has been demonstrated that a fuel cell, based on the model of carrier systems, shows the properties of larger current density and capacity than the ordinary fuel cell and following the model of the carrier system, oxidation and reduction can be repeated alternately without consumption of reactants.

Sustainable and Functional Redox Chemistry

Sustainable and Functional Redox Chemistry PDF

Author: Shinsuke Inagi

Publisher: Royal Society of Chemistry

Published: 2022-04-29

Total Pages: 403

ISBN-13: 1839162465

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Mimicking nature's efficiency and sustainability in organic chemistry is a major goal for future chemists; redox reactions are a key element in a variety of fields ranging from synthesis and catalysis to materials chemistry and analytical applications. Sustainability is increasingly becoming a consideration in synthesis and functional chemistry and an essential element for the next generation of chemistry in academia and industry. This book represents a compilation of the latest advancements in functional redox chemistry and demonstrates its importance in achieving a more sustainable future. This book is an ideal companion for any postgraduate students or researchers interested in sustainability in academia and industry.

Redox Polymers for Energy and Nanomedicine

Redox Polymers for Energy and Nanomedicine PDF

Author: Nerea Casado

Publisher: Royal Society of Chemistry

Published: 2020-10-20

Total Pages: 575

ISBN-13: 1788018710

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Redox Polymers for Energy and Nanomedicine highlights trends in the chemistry, characterization and application of polymers with redox properties.