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Organic Mechanochemistry and Its Practical Applications

Author: Zory Vlad Todres

Publisher: CRC Press

Published: 2006-03-06

Total Pages: 190

ISBN-13: 9780849340789

Organic Mechanochemistry and Its Practical Applications gathers physical and organic chemistry-based molecular principles, evolving interpretations of scientific data, and real world applications to demonstrate the synthetic advantages of mechanically initiated organic reactions. This book considers transformations of organic substances upon mechanical actions and explains how mechanical energy is transformed into chemical driving force. The author, a renowned expert in physical and organic chemistry, carefully examines the concurrent chemical and physical processes—particularly polymerization and dynamic shearing—that involve organic substances and inorganic surfaces during lubrication. Dr. Todres discusses the various factors that affect boundary lubrication, such as material properties, chemical reactivity, pressure, and temperature. The book describes conformational transformations and structural phase transitions of organic molecules and working materials that take place under mechanical forces, such as drilling, grinding, friction, and shearing, and shock-waves. Other key topics include mechanochromism, tribopolymerization, mechanical activation of organic reactions, and the peculiarities of catalytic effects in organic mechanochemistry. Throughout the text, the author highlights novel technical applications of mechanochemical phenomena in a variety of fields, including lubrication, biomedical engineering, pharmaceutical drug formulation, environmental protection, and practical economy. Organic Mechanochemistry and Its Practical Applications reveals how mechanochemistry was inspired by principles in various disciplines to create innovative approaches for current challenges in these fields.

Mechanochemical Organic Synthesis

Author: Davor Margetic

Publisher: Elsevier

Published: 2016-04-23

Total Pages: 388

ISBN-13: 0128025255

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Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency. The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area. Features cutting-edge research in the field of mechanochemical organic synthesis for more sustainable reactions Integrates advances in green chemistry research into industrial applications and process development Focuses on designing techniques in organic synthesis directed toward mild reaction conditions Includes global coverage of mechanochemical synthetic protocols for the generation of organic compounds

Tribology in Engineering

Author: Hasim Pihtili

Publisher: BoD – Books on Demand

Published: 2013-05-08

Total Pages: 256

ISBN-13: 9535111264

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The main goal in preparing this book was to publish contemporary concepts, new discoveries and innovative ideas in the field of surface engineering, predominantly for the technical applications, as well as in the field of production engineering and to stress some problems connected with the use of various surface processes in modern manufacturing of different purpose machine parts. This book is an attempt to introduce science into the study of surface treatment processes. Tribology offers a good approach for describing abrasive machining and coating processes and offers the ability to predict some of the outputs of the processes. The study of friction, forces, and energy explores the importance of the various factors which govern the stresses and deformations of abrasion. The effects of grain shape, depth of penetration, and lubrication on the process forces are explored. The tribology of nanostructured surfaces involves many fundamental and scientific issues. More importantly, it has tremendous applications in industries. It is a powerful tool to regulate friction, adhesion, and wetting of surfaces by altering their geometric textures and material compositions at the nanoscale, and, hence, to control the tribological performance of the engineering surfaces.

Tribocatalysis, Tribochemistry, and Tribocorrosion

Author: Czeslaw Kajdas

Publisher: CRC Press

Published: 2018-05-11

Total Pages: 337

ISBN-13: 9814669695

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This book focuses on the triboemission of low-energy electrons from the freshly generated surface. These electrons play the most crucial role in the chemical reactions at the tribological interface. New models and TIP (thermodymanics of irreversible processes) describe in detail the behavior of emitted electrons which lower the activation energy of the chemical reactions. This book also highlights tribocatalysis phenomena as examples of the lowering of the activation energy. A book titled Tribocatalysis has never been published before this.

Advanced Electrode Materials

Author: Ashutosh Tiwari

Publisher: John Wiley & Sons

Published: 2016-11-04

Total Pages: 563

ISBN-13: 1119242843

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This book covers the recent advances in electrode materials and their novel applications at the cross-section of advanced materials. The book is divided into two sections: State-of-the-art electrode materials; and engineering of applied electrode materials. The chapters deal with electrocatalysis for energy conversion in view of bionanotechnology; surfactant-free materials and polyoxometalates through the concepts of biosensors to renewable energy applications; mesoporous carbon, diamond, conducting polymers and tungsten oxide/conducting polymer-based electrodes and hybrid systems. Numerous approaches are reviewed for lithium batteries, fuel cells, the design and construction of anode for microbial fuel cells including phosphate polyanion electrodes, electrocatalytic materials, fuel cell reactions, conducting polymer based hybrid nanocomposites and advanced nanomaterials.

High-Energy Ball Milling

Author: Małgorzata Sopicka-Lizer

Publisher: Elsevier

Published: 2010-05-24

Total Pages: 436

ISBN-13: 1845699440

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Mechanochemical processing is a novel and cost effective method of producing a wide range of nanopowders. It involves the use of a high energy ball mill to initiate chemical reactions and structural changes. High energy ball milling: Mechanochemical processing of nanopowders reviews the latest techniques in mechanochemistry and how they can be applied to the synthesis and processing of various high-tech materials.Part one discusses the basic science of mechanochemistry with chapters on such topics as the mechanism and kinetics of mechanochemical processes, kinetic behaviour in mechanochemically-induced structural and chemical transformations and materials design through mechanochemical processing. Part two reviews mechanochemical treatment of different materials including synthesis of complex ceramic oxides, production of intermetallic compound powders, synthesis of organic compounds, synthesis of metallic-ceramic composite powders and activation of covalent bond-based materials. Part three covers mechanochemical processes in metal powder systems and other applications with coverage of topics such as plating and surface modification using ultrasonic vibrations, activated powders as precursors for spark plasma sintering, titanium dioxide photocatalyst synthesis by mechanochemical doping and synthesis of materials for lithium-ion batteries.With its distinguished editor and international team of contributors, High energy ball milling: Mechanochemical processing of nanopowders is a standard reference for all those involved in the production of ceramic and metallic components using sintering and other powder metallurgy techniques to produce net shape components. Examines the latest techniques in mechanochemistry and how they can be applied to the synthesis and processing of various high-tech materials Discusses the basic science of mechanochemistry including kinetic behaviour, processes and mechanisms and materials design through mechanochemical processing Reviews mechanochemical treatment of different materials including synthesis of ceramic oxides, organic compounds and metallic-ceramic composite powders

Mechanochemistry

Author: Evelina Colacino

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2020-12-07

Total Pages: 114

ISBN-13: 3110608332

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Mechanochemistry has been recently ackwnoledged by IUPAC as one of the top ten emerging technologies in chemistry, answering to the increased demand for clean processes and sustainable reaction conditions. This book focuses on the rediscovery of mechanochemistry for inorganic, organic and organo-metallic materials. Focus on experimental techniques and equipment will show how to implement mechanochemistry as an innovative way to sustainability in academic laboratories. The contents are ideal for researchers starting off in industry and academia, as well as advanced students.

Chromic Phenomena 3rd Edition

Author: Peter Bamfield

Publisher: Royal Society of Chemistry

Published: 2018-08-24

Total Pages: 812

ISBN-13: 1782628150

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Chromic or colour related phenomena are produced in response to a chemical or physical stimulus. This new edition will update the information on all those areas where chemicals or materials interact with light to produce colour, a colour change, or luminescence especially in the imaging, analysis, lighting and display areas. The book has been restructured to show greater emphasis on applications where 'coloured' compounds are used to transfer energy or manipulate light in some way therefore reducing the details on classical dyes and pigments. In the past eight years, since the previous edition, there has been a remarkable increase in the number of papers and reviews being produced reflecting the growth of interest in this area. This ongoing research interest is matched by a large number of new technological applications gaining commercial value covering e.g. biomedical areas, energy, data storage, physical colour, bio-inspired materials and photonics. This book appeals to industrial chemists, professionals, postgraduates and as high level recommended reading for colour technology courses.

Current Developments in Biotechnology and Bioengineering

Author: Sunita Varjani

Publisher: Elsevier

Published: 2020-01-23

Total Pages: 518

ISBN-13: 0444643222

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Current Developments in Biotechnology and Bioengineering: Resource Recovery from Wastes includes the latest and innovative research and technological developments in the biotechnology and bioengineering pertaining to various resource(s) recovery from wastes. The contents are organized into two broader sections covering resource recovery from industrial wastewater and resource recovery from solid wastes. Sections cover energy, bioproducts, nutrients, municipal food wastes, electronic wastes, agricultural waste and others. The state-of-the-art situation, potential advantages and limitations are also provided, along with strategies to overcome limitations. This book is a useful guide into research demands in solid and liquid waste treatment and management for environmental/economic sustainability. Provides state-of-art information and applications on microbiological and biotechnological interventions for resource recovery Covers municipal food wastes, electronic wastes and agricultural wastes Reviews current information relating to bioremediation Contains recent information, clearly illustrated with tables, figures and pictures Outlines different technological and biological aspects of resource recovery from industrial waste and effluents

Handbook of Mechanical Nanostructuring

Author: Mahmood Aliofkhazraei

Publisher: John Wiley & Sons

Published: 2015-02-10

Total Pages: 816

ISBN-13: 3527674977

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Providing in-depth information on how to obtain high-performance materials by controlling their nanostructures, this ready reference covers both the bottom-up and the top-down approaches to the synthesis and processing of nanostructured materials. The focus is on advanced methods of mechanical nanostructuring such as severe plastic deformation, including high pressure torsion, equal channel angular processing, cyclic extrusion compression, accumulative roll bonding, and surface mechanical attrition treatment. As such, the contents are inherently application-oriented, with the methods presented able to be easily integrated into existing production processes. In addition, the structure-property relationships and ways of influencing the nanostructure in order to exhibit a desired functionality are reviewed in detail. The whole is rounded off by a look at future directions, followed by an overview of applications in various fields of structural and mechanical engineering. With its solutions for successful processing of complex-shaped workpieces and large-scale specimens with desired properties, this is an indispensable tool for purposeful materials design.