Molecular Organometallic Materials for Optics

Molecular Organometallic Materials for Optics PDF

Author: Zuqiang Bian

Publisher: Springer Science & Business Media

Published: 2009-11-10

Total Pages: 236

ISBN-13: 3642018653

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Aimed at a multidisciplinary scientific readership, this publication covers a number of specific topics in what is now a rapidly developing field, including coordination and organometallic complexes as second-order nonlinear optical molecular materials.

Conducting and Magnetic Organometallic Molecular Materials

Conducting and Magnetic Organometallic Molecular Materials PDF

Author: Marc Fourmigué

Publisher: Springer Science & Business Media

Published: 2009-07-21

Total Pages: 199

ISBN-13: 3642004075

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For several years, the two parallel worlds of Molecular Conductors in one hand and Molecular Magnetism in the other have grown side by side, the former essentially based on radical organic molecules, the latter essentially based on the high spin properties of metal complexes. Over the last few years however, organometallic derivatives have started to play an increasingly important role in both worlds, and have in many ways contributed to open several passages between these two worlds. This volume recognizes this important emerging evolution of both research areas. It is not intended to give a comprehensive view of all possible organometallic materials, and polymers for example were not considered here. Rather we present a selection of the most recent research topics where organometallic derivatives were shown to play a crucial role in the setting of conducting and/or magnetic properties in crystalline materials. First, the role of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by Schlueter, while Kubo and Kato describe very recent ortho-metalated chelating ligands appended to the TTF core and their conducting salts. The combination of conducting and magnetic properties and the search for p–d interactions are analyzed in two comp- mentary contributions by Myazaki and Ouahab, while Valade focuses on the only class of metal bis(dithiolene) complexes to give rise to superconductive molecular materials, in association with organic as well as organometallic cations.

Conducting and Magnetic Organometallic Molecular Materials

Conducting and Magnetic Organometallic Molecular Materials PDF

Author: Marc Fourmigué

Publisher: Springer Science & Business Media

Published: 2009-06-17

Total Pages: 199

ISBN-13: 3642004083

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For several years, the two parallel worlds of Molecular Conductors in one hand and Molecular Magnetism in the other have grown side by side, the former essentially based on radical organic molecules, the latter essentially based on the high spin properties of metal complexes. Over the last few years however, organometallic derivatives have started to play an increasingly important role in both worlds, and have in many ways contributed to open several passages between these two worlds. This volume recognizes this important emerging evolution of both research areas. It is not intended to give a comprehensive view of all possible organometallic materials, and polymers for example were not considered here. Rather we present a selection of the most recent research topics where organometallic derivatives were shown to play a crucial role in the setting of conducting and/or magnetic properties in crystalline materials. First, the role of organometallic anions in tet- thiafulvalenium-based molecular conductors is highlighted by Schlueter, while Kubo and Kato describe very recent ortho-metalated chelating ligands appended to the TTF core and their conducting salts. The combination of conducting and magnetic properties and the search for p–d interactions are analyzed in two comp- mentary contributions by Myazaki and Ouahab, while Valade focuses on the only class of metal bis(dithiolene) complexes to give rise to superconductive molecular materials, in association with organic as well as organometallic cations.

Organometallics as Catalysts in the Fine Chemical Industry

Organometallics as Catalysts in the Fine Chemical Industry PDF

Author: Matthias Beller

Publisher: Springer

Published: 2012-08-31

Total Pages: 165

ISBN-13: 3642328334

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Johannes G. de Vries: Pd-catalyzed coupling reactions.- Gregory T. Whiteker and Christopher J. Cobley: Applications of Rhodium-Catalyzed Hydroformylation in the Pharmaceutical, Agrochemical and Fragrance Industries.- Philippe Dupau: Ruthenium-catalyzed Selective Hydrogenation for Flavor and Fragrance Applications.- Hans-Ulrich Blaser, Benoît Pugin and Felix Spindler: Asymmetric Hydrogenation.- Ioannis Houpis: Case Study: Sequential Pd-catalyzed Cross-Coupling Reactions; Challenges on Scale-up.- Adriano F. Indolese: Pilot Plant Scale Synthesis of an Aryl-Indole - Scale up of a Suzuki Coupling.- Per Ryberg: Development of a Mild and Robust Method for Palladium Catalysed Cyanation on Large Scale.- Cheng-yi Chen: Application of Ring Closing Metathesis Strategy to the Synthesis of Vaniprevir (MK-7009), a 20-Membered Macrocyclic HCV Protease Inhibitor.

Nonlinear Optics of Organic Molecules and Polymers

Nonlinear Optics of Organic Molecules and Polymers PDF

Author: Hari Singh Nalwa

Publisher: CRC Press

Published: 2020-07-09

Total Pages: 896

ISBN-13: 0429611617

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The field of nonlinear optics emerged three decades ago with the development of the first operating laser and the demonstration of frequency doubling phenomena. These milestone discoveries not only generated much interest in laser science, but also set the stage for future work on nonlinear optics. This book presents an excellent overview of the exciting new advances in nonlinear optical (NLO) materials and their applications in emerging photonics technologies. It is the first reference source available to cover every NLO material published through 1995. All theoretical approaches, measurement techniques, materials, technologies, and applications are covered. With more than 1,800 bibliographic citations, 324 figures, 218 tables, and 812 equations, this book is an invaluable reference source for graduate and undergraduate students, researchers, scientists and engineers working in academia and industries in chemistry, solid-state physics, materials science, optical and polymer engineering, and computational science.

Optical and Molecular Physics

Optical and Molecular Physics PDF

Author: Miguel A. Esteso

Publisher: CRC Press

Published: 2021-09-30

Total Pages: 507

ISBN-13: 1000351343

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Optical and Molecular Physics: Theoretical Principles and Experimental Methods addresses many important applications and advances in the field. This book is divided into 5 sections: Plasmonics and carbon dots physics with applications Optical films, fibers, and materials Optical properties of advanced materials Molecular physics and diffusion Macromolecular physics Weaving together science and engineering, this new volume addresses important applications and advances in optical and molecular physics. It covers plasmonics and carbon dots physics with applications; optical films, fibers, and materials; optical properties of advanced materials; molecular physics and diffusion; and macromolecular physics. This book looks at optical materials in the development of composite materials for the functionalization of glass, ceramic, and polymeric substrates to interact with electromagnetic radiation and presents state-of-the-art research in preparation methods, optical characterization, and usage of optical materials and devices in various photonic fields. The authors discuss devices and technologies used by the electronics, magnetics, and photonics industries and offer perspectives on the manufacturing technologies used in device fabrication.

Organometallic Pincer Chemistry

Organometallic Pincer Chemistry PDF

Author: Gerard van Koten

Publisher: Springer

Published: 2012-09-17

Total Pages: 363

ISBN-13: 3642310818

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Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

Organometallics and Renewables

Organometallics and Renewables PDF

Author: Michael A.R. Meier

Publisher: Springer

Published: 2012-05-26

Total Pages: 239

ISBN-13: 3642282881

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Lucas Montero de Espinosa and Michael A. R. Meier: Olefin Metathesis of Renewable Platform Chemicals.- Pieter C. A. Bruijnincx, Robin Jastrzebski, Peter J. C. Hausoul, Robertus J. M. Klein Gebbink, and Bert M. Weckhuysen: Pd-Catalysed Telomerisation of 1,3-Dienes with Multifunctional Renewable Substrates - Versatile Routes for the Valorisation of Biomass-Derived Platform Molecules.- A Behr, A. J. Vorholt: Hydroformylation and related reactions of renewable resources.- Ties J. Korstanje, Robertus J.M. Klein Gebbink: Catalytic oxidation and deoxygenation of renewables with rhenium complexes.- Antoine Buchard, Clare M. Bakewell, Jonathan Weiner and Charlotte K. Williams: Recent Developments In Catalytic Activation Of Renewable Resources For Polymer Synthesis.

Electroactive Materials

Electroactive Materials PDF

Author: Jürgen O. Besenhard

Publisher: Springer Science & Business Media

Published: 2001-05-03

Total Pages: 154

ISBN-13: 9783211836552

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Electroactive materials are playing an ever increasing role in science and technology. At present the wide range of applications for these materials include electrodes and membranes for electrochemical energy conversion and storage, electroceramic devices and sensors, organic diodes, magnetic and optical devices, and photoresists. The book summarizes the results of the special research program ‘Electroactive Materials’ established by the Austrian Science Fund. Contributions deal with plastic solar cells (invited review); conjugated polymers and organosilanes; thin-film zinc/manganese dioxide electrodes; the anode/electrolyte interface in lithium ion batteries; a novel technique for manufacturing highly conductive composite materials; a new method for conductivity relaxation measurements on mixed conductors; the application of surface science to thin films and interfaces of electroactive organic materials; preparation and radical oligomerisation of an Fe(II) complex without loss of spin-crossover properties; phase gratings in photoreactive polymers as a way to optically pumped organic lasers; and high-spatial resolution elemental analysis and mapping by analytical electron microscopy.

Photophysics of Organometallics

Photophysics of Organometallics PDF

Author: Alistair J. Lees

Publisher: Springer Science & Business Media

Published: 2010-02-04

Total Pages: 245

ISBN-13: 3642047289

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Arvind Kumar, Shih-Sheng Sun, and Alistair J. Lees: Photophysics and Photochemistry of Organometallic Rhenium Diimine Complexes; Conor Long: Photophysics of CO Loss from Simple Metal Carbonyl Complexes; Antonín Vlcek Jr: Ultrafast Excited-State Processes in Re(I) Carbonyl-Diimine Complexes: From Excitation to Photochemistry; Kenneth Kam-Wing Lo: Exploitation of Luminescent Organometallic Rhenium(I) and Iridium(III) Complexes in Biological Studies; Maria L. Muro , Aaron A. Rachford , Xianghuai Wang, and Felix N. Castellano: Platinum II Acetylide Photophysics; Andreas F. Rausch, Herbert H. H. Homeier, and Hartmut Yersin: Organometallic Pt(II) and Ir(III) Triplet Emitters for OLED Applications and the Role of Spin–Orbit Coupling: A Study Based on High-Resolution Optical Spectroscopy.