Mobile Alternative Demilitarization Technologies

Mobile Alternative Demilitarization Technologies PDF

Author: F.W. Holm

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 285

ISBN-13: 9401155267

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FRANCIS W. HOLM 7102 Meadow Lane, Chevy Chase, MD 20815 The North Atlantic Treaty Organization (NATO) sponsored an Advanced Research Workshop (ARW) in Prague, Czech Republic, on 1-2 July 1996, to collect and study information on mobile alternative and supplemental demilitarization technologies and to report these fmdings. The mobile, or transportable, technologies identified for assessment at the workshop are alternatives to incineration technology for destruction of munitions, chemical warfare agent, and associated materials and debris. Although the discussion focused on the treatment of metal parts and explosive or energetic material, requirements for decontamination of other materials were discussed. The mobile alternative technologies are grouped into three categories based on process bulk operating temperature: low (0-200 C), medium (200-600 C), and high (600- 3,500 C). Reaction types considered include hydrolysis, biodegradation, electrochemical oxidation, gas-phase high-temperature reduction, stearn reforming, gasification, sulfur reactions, solvated electron chemistry, sodium reactions, supercritical water oxidation, wet air oxidation, and plasma torch technology. These categories represent a broad spectrum of processes, some of which have been studied only in the laboratory and some of which are in commercial use for destruction of hazardous and toxic wastes. Some technologies have been developed and used for specific commercial applications; however, in all cases, research, development, test, and evaluation (RDT &E) is necessary to assure that each technology application is effective for destroying chemical warfare materiel.

Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons

Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons PDF

Author: National Research Council

Publisher: National Academies Press

Published: 1999-12-24

Total Pages: 267

ISBN-13: 0309066395

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This report examines seven disposal technologies being considered by the U.S. government as alternative methods to the process of incineration for destroying mortars, rockets, land mines, and other weapons that contain chemical warfare agents, such as mustard gas. These weapons are considered especially dangerous because they contain both chemical warfare agent and explosive materials in an assembled package that must be disassembled for destruction. The study identifies the strengths and weaknesses and advantages and disadvantages of each technology and assesses their potential for full-scale implementation.

Effluents from Alternative Demilitarization Technologies

Effluents from Alternative Demilitarization Technologies PDF

Author: F.W. Holm

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 225

ISBN-13: 9401153108

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FRANCIS W. HOLM 30 Agua Sarca Road, Placitas, New Mexico 1. Overview The North Atlantic Treaty Organization (NATO) sponsored an Advanced Research in Prague, Czech Republic, on October 13-15, 1997, to collect and Workshop (ARW) study information on effluents from alternative demilitarization technologies and to report on these fmdings. The effluents, orprocess residues, identified for assessment at the workshop are generated by systems that have been proposed as alternatives to incineration technology for destruction of munitions, chemical warfare agent, and associated materials and debris. The alternative technologies analyzed are grouped into three categories based on process bulk operating temperature: low (0-200 C), medium (200-600 C), and high (600-3,500 C). Reaction types considered include hydrolysis, biodegradation, electrochemical oxidation, gas-phase high-temperature reduction, steam reforming, gasification, sulfur reactions, solvated electron chemistry, sodium reactions, supercritical water oxidation, wet air oxidation, and plasma torch technology. These ofprocesses, some of which have been studied categories represent a broad spectrum only in the laboratory and some of which are in commercial use for destruction of hazardous and toxic wastes. Some technologies have been developed and used for specific commercial applications; however, in all cases, research, development, test, and evaluation (RDT&E) is necessary to assure that each technology application is effective for destroying chemical warfare materiel. Table 1 contains a list of more than 40 technologies from a recent report for the U.S. Army [1]. Many ofthe technologies in Table 1 are based on similar principles.

Scientific Advances in Alternative Demilitarization Technologies

Scientific Advances in Alternative Demilitarization Technologies PDF

Author: F.W. Holm

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 181

ISBN-13: 9400916833

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FRANCIS W. HOLM Science Applications International Corporation 7102 Meadow Lane, Chevy Chase, MD 20815 The North Atlantic Treaty Organization (NATO) sponsored an Advanced Research Workshop (ARW) in Warsaw, Poland on April 24-25, 1995, to collect and study information on alternative and supplemental demilitarization technologies. The conference included experienced scientists and engineers, who delivered presentations and provided written reports oftheir findings. Countries describing their technologies included: Poland (pre-processing, thermal oxidation, and instrumentation), Russia (molten salt oxidation, plasma, catalytic oxidation, supertoxicants, molten metal, fluid bed reactions, and hydrogenation), Germany (supercritical water oxidation and detoxification), the United Kingdom (electrochemical oxidation), the United States (wet air oxidation, detoxification and biodegradation), and the Czech Republic (biodegradation). The technologies identified for assessment at the workshop are alternatives to incineration technology for chemical warfare agent destruction. Treatment of metal parts and explosive or energetic material were considered as a secondary issue. The treatment of dunnage and problems associated with decontamination, while recognized as an element of demilitarization, received only limited discussion. The alternative technologies are grouped into three categories based on process bulk operating temperature: low (O-200°C), medium (200-600°C), and high (600-3,500°C). Reaction types considered include hydrolysis, oxidation, electrochemical, hydrogenation, and pyrolysis. These categories represent a broad spectrum of processes, some of which have been studied only in the laboratory and some of which are in commercial use for destruction of hazardous and toxic wastes. Some technologies have been developed and used for specific commercial applications.

Evaluation of Demonstration Test Results of Alternative Technologies for Demilitarization of Assembled Chemical Weapons

Evaluation of Demonstration Test Results of Alternative Technologies for Demilitarization of Assembled Chemical Weapons PDF

Author: National Research Council

Publisher: National Academies Press

Published: 2002-01-08

Total Pages: 66

ISBN-13: 030907634X

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By direction of Congress, the U.S. Department of Defense's (DoD's) program manager for the Assembled Chemical Weapons Assessment (PMACWA) asked the National Research Council (NRC) Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons: Phase II (the ACW II committee) to conduct an independent scientific and technical assessment of three alternative technologies (referred to as Demo II) under consideration for the destruction of assembled chemical weapons at U.S. chemical weapons storage sites. The three technologies are AEA Technologies Corporation's (AEA's) electrochemical oxidation process; the transpiring-wall supercritical water oxidation and gasphase chemical reduction processes of Foster Wheeler/Eco Logic/Kvaerner (FW/EL/K); and Teledyne-Commodore's solvated electron process. Each of these technologies represents an alternative to incineration for the complete destruction of chemical agents and associated energetic materials. The demonstration tests were approved by the PMACWA after an initial assessment of each technology. The results of that initial assessment were reviewed by an earlier NRC committee, the Committee on Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons (the ACW I committee). For the present review, the committee conducted an indepth examination of each technology provider's data, analyses, and demonstration test results for the critical components tested. This review report supplements the ACW I report and considers the demonstration performance of the Demo II candidate technologies and their readiness for advancement to pilot-scale implementation. Because testing in these areas is ongoing, the committee decided to cut short its fact-finding efforts for input to this report as of March 30, 2001.

Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Blue Grass Army Depot

Analysis of Engineering Design Studies for Demilitarization of Assembled Chemical Weapons at Blue Grass Army Depot PDF

Author: National Research Council

Publisher: National Academies Press

Published: 2002-10-27

Total Pages: 172

ISBN-13: 0309085284

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The U.S. Army is in the process of destroying the nation's stockpile of aging chemical weapons stored at eight locations in the continental United States and on Johnston Atoll in the Pacific. Originally, incineration was chosen for the destruction of these stores, but this method has met with public opposition, and Congress directed the Army to develop alternative technologies for destroying the stockpiles in Pueblo, CO and Richmond, KY. To assist the Army in this process, the NRC was asked to evaluate the engineering design study of the three Blue Grass candidates. This book presents an analysis of various issues pertaining to the proposed engineering design package for the Blue Grass facility.

Review and Evaluation of Alternative Chemical Disposal Technologies

Review and Evaluation of Alternative Chemical Disposal Technologies PDF

Author: National Research Council

Publisher: National Academies Press

Published: 1996-11-15

Total Pages: 272

ISBN-13: 030917550X

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In 1994 the National Research Council published Recommendations for the Disposal of Chemical Agents and Munitions, which assessed the status of various alternative destruction technologies in comparison to the Army's baseline incineration system. The volume's main finding was that no alternative technology was preferable to incineration but that work should continue on the neutralization technologies under Army consideration. In light of the fact that alternative technologies have evolved since the 1994 study, this new volume evaluates five Army-chosen alternatives to the baseline incineration system for the disposal of the bulk nerve and mustard agent stored in ton containers at Army sites located in Newport, Indiana, and Aberdeen, Maryland, respectively. The committee assessed each technology by conducting site visits to the locations of the technology proponent companies and by meeting with state regulators and citizens of the affected areas. This volume makes recommendations to the Army on which, if any, of the five technologies has reached a level of maturity appropriate for consideration for pilot-scale testing at the two affected sites.

Disposal of Neutralent Wastes

Disposal of Neutralent Wastes PDF

Author: National Research Council

Publisher: National Academies Press

Published: 2001-04-29

Total Pages: 78

ISBN-13: 0309072875

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Chemical warfare materiel (CWM) is a collection of diverse items that were used during 60 years of efforts by the United States to develop a capability for conducting chemical warfare. Nonstockpile CWM, which is not included in the current U.S. inventory of chemical munitions, includes buried materiel, recovered materiel, binary chemical weapons, former production facilities, and miscellaneous materiel. CWM that was buried in pits on former military sites is now being dug up as the land is being developed for other purposes. Other CWM is on or near the surface at former test and firing ranges. According to the Chemical Weapons Convention (CWC), which was ratified by the United States in April 1997, nonstockpile CWM items in storage at the time of ratification must be destroyed by 2007. The U.S. Army is the designated executive agent for destroying CWM. Nonstockpile CWM is being handled by the Non-Stockpile Chemical Materiel Program (NSCMP); stockpile CWM is the responsibility of the Chemical Stockpile Disposal Program. Because nonstockpile CWM is stored or buried in many locations, the Army is developing transportable disposal systems that can be moved from site to site as needed. The Army has plans to test prototypes of three transportable systems-the rapid response system (RRS), the munitions management device (MMD), and the explosive destruction system (EDS)-for accessing and destroying a range of nonstockpile chemical agents and militarized industrial chemicals. The RRS is designed to treat recovered chemical agent identification sets (CAIS), which contain small amounts of chemical agents and a variety of highly toxic industrial chemicals. The MMD is designed to treat nonexplosively configured chemical munitions. The EDS is designed to treat munitions containing chemical agents with energetics equivalent to three pounds of TNT or less. These munitions are considered too unstable to be transported or stored. A prototype EDS system has recently been tested in England by non-stockpile program personnel. Although originally proposed for evaluation in this report, no test data were available to the committee on the composition of wastes from the EDS. Therefore, alternative technologies for the destruction of EDS wastes will be discussed in a supplemental report in fall 2001. Treatment of solid wastes, such as metal munition bodies, packing materials, and carbon air filters, were excluded from this report. Review and Evaluation of the Army Non-Stockpile Chemical Materiel Disposal Program: Disposal of Neutralent Wastes evaluates the near-term (1999-2005) application of advanced (nonincineration) technologies, such as from the Army's Assembled Chemical Weapons Assessment Program and the Alternative Technologies and Approaches Project, in a semi-fixed, skid-mounted mode to process Rapid Response System, Munitions Management Device, and Explosive Destruction System liquid neutralization wastes.

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