Metal-Catalyzed Oxidations of Organic Compounds

Metal-Catalyzed Oxidations of Organic Compounds PDF

Author: Roger Sheldon

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 447

ISBN-13: 0323150047

DOWNLOAD EBOOK →

Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.

Metal-catalyzed Oxidations of Organic Compounds

Metal-catalyzed Oxidations of Organic Compounds PDF

Author: Roger A. Sheldon

Publisher:

Published: 1981

Total Pages: 424

ISBN-13: 9780124312067

DOWNLOAD EBOOK →

Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation-reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds.

Biomimetic Oxidations Catalyzed By Transition Metal Complexes

Biomimetic Oxidations Catalyzed By Transition Metal Complexes PDF

Author: Bernard Meunier

Publisher: World Scientific

Published: 2000-03-08

Total Pages: 697

ISBN-13: 1783262389

DOWNLOAD EBOOK →

Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with.This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students.

Metalloporphyrins Catalyzed Oxidations

Metalloporphyrins Catalyzed Oxidations PDF

Author: F. Montanari

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 364

ISBN-13: 9401722471

DOWNLOAD EBOOK →

Oxidative catalysis by metalloporphyrin systems occupies a prominent role in the current research in the fields of chemical and biological catalysis. Our particular interest and approach has been to collect in the same volume papers dealing with both the chemical and biological aspects of the reactivity of heme systems because of the realization that a better understanding of the complementary discipline can be extremely useful for the researchers from either field. The current progress of the research on synthetic metalloporphyrin catalysts has led to the development of several systems that are able to reproduce the heme-enzyme mediated oxygenation and oxidation reactions, at least in terms of reaction types, mechanisms and often rates. These achievements have stimulated the of creating metalloporphyrin catalysts which are both ambitious project efficient and stable enough to become competitive for large-scale industrial processes. Although this project is still far from being realized, the efforts in this direction parallel those aimed at the application of heme enzymes to chemical technologies, e. g. for the mild, selective oxidation of organics or the detoxification of pollutants. Both the two approaches will be advantageous because while the enzyme systems can achieve selectivities which are probably unattainable by synthetic catalysts, the latter can be active under experimental conditions that would readily inactivate the enzymes.

Catalytic Oxidations with Hydrogen Peroxide as Oxidant

Catalytic Oxidations with Hydrogen Peroxide as Oxidant PDF

Author: G. Strukul

Publisher: Springer Science & Business Media

Published: 2013-03-14

Total Pages: 287

ISBN-13: 940170984X

DOWNLOAD EBOOK →

Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.

Transition Metal Catalysis in Aerobic Alcohol Oxidation

Transition Metal Catalysis in Aerobic Alcohol Oxidation PDF

Author: Francesca Cardona

Publisher: Royal Society of Chemistry

Published: 2015

Total Pages: 304

ISBN-13: 1849738238

DOWNLOAD EBOOK →

This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.

Catalytic Oxidation in Organic Synthesis

Catalytic Oxidation in Organic Synthesis PDF

Author: Kilian Muñiz

Publisher: Thieme Chemistry

Published: 2018

Total Pages: 0

ISBN-13: 9783132012417

DOWNLOAD EBOOK →

The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. "Science of Synthesis: Catalytic Oxidation in Organic Synthesis" includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Chemical Changes in Food during Processing

Chemical Changes in Food during Processing PDF

Author: Thomas Richardson

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 520

ISBN-13: 1461322650

DOWNLOAD EBOOK →

This volume results from the Eighth Basic Symposium held by the Institute of Food Technologists in Anaheim, California on June 8-9, 1984. The theme of the symposium was "Chemical Changes in Food during Processing." The speakers included a mix of individuals from academic institu tions, governmental agencies, and the food industry. Twenty speakers discussed topics ranging from the basic chemistry relating to food constituents to the more applied aspects of chemical changes in food components during food processing. It was the intent of the organizers to bring together a group of speakers who could address the chemistry of changes in food compo nents during processing from a mechanistic point of view. As a con sequence, the proceedings of this symposium emphasize the basic chemistry of changes in food constituents from a generic perspective which is intended to provide the reader with a background to address more specific problems that may arise.

Lanterna Rally - Theme by Grace Themes