Hydrotreatment and Hydrocracking of Oil Fractions

Hydrotreatment and Hydrocracking of Oil Fractions PDF

Author: B. Delmon

Publisher: Elsevier

Published: 1997-01-20

Total Pages: 594

ISBN-13: 008053435X

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The symposium on Hydrotreatment and Hydrocracking of Oil Fractions aims to provide a global perspective and an inspection of the state-of-the-art of these processes. New American, European and Japanese environmental regulations call for advanced hydrotreatment processes for HDS and HDN for the removal of S- and Ni-components from oil fractions. These will alter the product slate of the oil refineries and the hydrocarbon composition of these products. Hydrocracking will play an important part in this shift. Adapting the operating conditions will not suffice to reach the desired product specifications and yields. Adequate catalysts will have to be developed. Powerful tools are now available for this, e.g. surface science techniques, molecular modeling and new types of reactors operated in a nonsteady mode. Another instrument in the improvement of hydrotreatment and hydrocracking units is the availability of more realistic kinetic models. These are based on a judicious insight into the reaction mechanism, also provided by the above-mentioned tools. Progress in the analytical techniques has allowed the reduction of the lumping of components in these kinetic models and first order kinetic equations are gradually replaced by equations accounting for the adsorption of the various components. More detailed and more realistic reactor models are now based on rigorous hydrodynamic models and their application has become possible through the rapidly increasing possibilities of computers.

Hydrotreatment and Hydrocracking of Oil Fractions

Hydrotreatment and Hydrocracking of Oil Fractions PDF

Author: B. Delmon

Publisher: Elsevier

Published: 1999-11-03

Total Pages: 459

ISBN-13: 0080534260

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The 2nd International Symposium on Hydrotreatment and Hydrocracking of Oil Fractions, which is also the 7th in the series of European Workshops on Hydrotreatment, took place in Antwerpen, Belgium from November 14 to 17. The Symposium emphasized how oil refining faces increasingly severe environmental regulations. These and the increasing application of heavier crudes containing more S-, N- and metal components call for more efficient hydrotreatment and hydrocracking processes. It is clear from the keynote lectures, the oral contributions and the posters of this meeting that adapting the operating conditions will not suffice. Adequate catalysts need to be developed, with different composition and structure. Surface science techniques and molecular modeling are now well established tools for such a development. They should be of help in widely different aspects, like the role of precursors in the preparation or the modifications undergone by the catalyst under reaction conditions. The improvement of hydrotreatment and hydrocracking also needs accurate modeling of the chemical reactor. This requires more representative hydrodynamics and kinetic models whose validity extends to the very low S- and N-contents. These areas should be vigorously developed.

Multiphase Catalytic Reactors

Multiphase Catalytic Reactors PDF

Author: Zeynep Ilsen Önsan

Publisher: John Wiley & Sons

Published: 2016-06-09

Total Pages: 399

ISBN-13: 1119248469

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Provides a holistic approach to multiphase catalytic reactors from their modeling and design to their applications in industrial manufacturing of chemicals Covers theoretical aspects and examples of fixed-bed, fluidized-bed, trickle-bed, slurry, monolith and microchannel reactors Includes chapters covering experimental techniques and practical guidelines for lab-scale testing of multiphase reactors Includes mathematical content focused on design equations and empirical relationships characterizing different multiphase reactor types together with an assortment of computational tools Involves detailed coverage of multiphase reactor applications such as Fischer-Tropsch synthesis, fuel processing for fuel cells, hydrotreating of oil fractions and biofuels processing

Hydrotreating and Hydrocracking Processes in Refining Technology

Hydrotreating and Hydrocracking Processes in Refining Technology PDF

Author: James G. Speight

Publisher: CRC Press

Published: 2023-09-29

Total Pages: 307

ISBN-13: 1000957861

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Written by an industry expert with over 50 years of experience, this book details the various solvent processes that are used in crude oil refineries. Providing an in-depth exploration of the different types of processes, as well as the types of feedstocks that can be used with them, this book prepares readers for changes as the industry evolves. Key Features: Describes feedstock evaluation and the effects of elemental, chemical, and fractional composition. Contains an extensive glossary of all related concepts in hydrotreating and hydrocracking processes. Considers next-generation processes and developments. This book is an essential guide for engineers, scientists, and students in the field of petroleum processing and refining technology, including professionals, technicians, management personnel, and academics.

Handbook of Petroleum Processing

Handbook of Petroleum Processing PDF

Author: Steven A. Treese

Publisher: Springer

Published: 2015-08-04

Total Pages: 0

ISBN-13: 9783319145280

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This extensively updated second edition of the already valuable reference targets research chemists and engineers who have chosen a career in the complex and essential petroleum industry, as well as other professionals just entering the industry who seek a comprehensive and accessible resource on petroleum processing. The handbook describes and discusses the key components and processes that make up the petroleum refining industry. Beginning with the basics of crude oils and their nature, it continues with the commercial products derived from refining and with related issues concerning their environmental impact. More in depth coverage of many topics previously covered in the first edition, such as hydraulic fracturing or fracking as it is often termed, help ensure this reference remains a relevant and up-to- date resource. At its core is a complete overview of the processes that make up a modern refinery, plus a brief history of the development of processes. Also described in detail are design techniques, operations and in the case of catalytic units, the chemistry of the reaction routes. These discussions are supported by calculation procedures and examples, which enable readers to use today’s simulation-software packages. The handbook also covers off-sites and utilities, as well as environmental and safety aspects relevant to the industry. The chapter on refinery planning covers both operational planning and the decision making procedures for new or revamped processes. Major equipment used in the industry is reviewed along with details and examples of the process specifications for each. An extensive glossary and dictionary of the terms and expressions used in petroleum refining, plus appendices supplying data such as converging factors and selected crude oil assays, as well as an example of optimizing a refinery configuration using linear programming are all included to aid the reader. The 2nd edition of the Handbook of Petroleum Processing is an indispensable desk reference for chemists and engineers as well as an essential part of the libraries of universities with a chemical engineering faculty and oil refineries and engineering firms performing support functions or construction.

Modeling and Simulation of Catalytic Reactors for Petroleum Refining

Modeling and Simulation of Catalytic Reactors for Petroleum Refining PDF

Author: Jorge Ancheyta

Publisher: John Wiley & Sons

Published: 2011-04-20

Total Pages: 449

ISBN-13: 1118002164

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Modeling and Simulation of Catalytic Reactors for Petroleum Refining deals with fundamental descriptions of the main conversion processes employed in the petroleum refining industry: catalytic hydrotreating, catalytic reforming, and fluid catalytic cracking. Common approaches for modeling of catalytic reactors for steady-state and dynamic simulations are also described and analyzed. Aspects such as thermodynamics, reaction kinetics, process variables, process scheme, and reactor design are discussed in detail from both research and commercial points of view. Results of simulation with the developed models are compared with those determined at pilot plant scale as well as commercial practice. Kinetics data used in the reactor model are either taken from the literature or obtained under controlled experiments at the laboratory.

Experimental Methods for Evaluation of Hydrotreating Catalysts

Experimental Methods for Evaluation of Hydrotreating Catalysts PDF

Author: Jorge Ancheyta

Publisher: John Wiley & Sons

Published: 2020-06-08

Total Pages: 429

ISBN-13: 1119517990

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Presents detailed information and study cases on experiments on hydrotreating catalysts for the petroleum industry Catalytic hydrotreating (HDT) is a process used in the petroleum refining industry for upgrading hydrocarbon streams—removing impurities, eliminating metals, converting asphaltene molecules, and hydrocracking heavy fractions. The major applications of HDT in refinery operations include feed pretreatment for conversion processes, post-hydrotreating distillates, and upgrading heavy crude oils. Designing HDT processes and catalysts for successful commercial application requires experimental studies based on appropriate methodologies. Experimental Methods for Evaluation of Hydrotreating Catalysts provides detailed descriptions of experiments in different reaction scales for studying the hydrotreating of various petroleum distillates. Emphasizing step-by-step methodologies in each level of experimentation, this comprehensive volume presents numerous examples of evaluation methods, operating conditions, reactor and catalyst types, and process configurations. In-depth chapters describe experimental setup and procedure, analytical methods, calculations, testing and characterization of catalyst and liquid products, and interpretation of experiment data and results. The text describes experimental procedure at different levels of experimentation—glass reactor, batch reactor, continuous stirred tank reactor, and multiple scales of tubular reactors—using model compounds, middle distillates and heavy oil. This authoritative volume: Introduces experimental setups used for conducting research studies, such as type of operation, selection of reactor, and analysis of products Features examples focused on the evaluation of different reaction parameters and catalysts with a variety of petroleum feedstocks Provides experimental data collected from different reaction scales Includes experiments for determining mass transfer limitations and deviation from ideality of flow pattern Presents contributions from leading scientists and researchers in the field of petroleum refining Experimental Methods for Evaluation of Hydrotreating Catalysts is an indispensable reference for researchers and professionals working in the area of catalytic hydrotreating, as well as an ideal textbook for courses in fields such as chemical engineering, petrochemical engineering, and biotechnology.

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