Chemistry of Zeolites and Related Porous Materials

Chemistry of Zeolites and Related Porous Materials PDF

Author: Ruren Xu

Publisher: John Wiley & Sons

Published: 2009-05-29

Total Pages: 616

ISBN-13: 0470822368

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Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.

Zeolites: Science and Technology

Zeolites: Science and Technology PDF

Author: Fernando Ramôa Ribeiro

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 698

ISBN-13: 9400961286

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Zeolites have been the focus of intensive activity and growth in applications over the past 25 years in ion exchange, in adsorp tion and in catalytic process technology. Beginning with the syn thetic zeolites A,X and Y, continuing into the emerging ZSM series, and including selected natural zeolites, applications span the range from large-scale purification and separation to such major petroleum and petrochemical processes as catalytic cracking and aromatics alkylation. The future promises several new areas of signiciant use as our energy resource base is expanded. As a result, a NATO Advanced Study Institute on Zeolites was held in Alcabideche, Portugal, May 1-12, 1983. Its purpose was to summarize the state-of-the-art in zeolite science and technology, with particular emphasis on recent developments. This summary is intended to complement presentations of the latest research results at the 1983 International Zeolites Association meeting in .Reno, Nevada - USA. Both the fundamentals concepts and industrial applications are addressed in the lectures of the Institute. Individual chapters cover historical development, structure, crystallography and synthesis techniques. Basic principles of adsorption, diffusion, ion exchange and acidity are reviewed. A section on catalysis addresses shape selectivity, transition metals, bifunctional catalysis and "methanol to-gasoline". Included in the section on industrial applications are chapters on reactor and adsorber design, catalytic cracking, xylene and n -paraffins isomerization, as well as ion exchange and adsorption.

Zeolite Synthesis

Zeolite Synthesis PDF

Author: Mario L. Occelli

Publisher:

Published: 1989

Total Pages: 672

ISBN-13:

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This volume is a complete progress report on the various aspects of zeolite synthesis on a molecular level. It provides many examples that illustrate how zeolites can be crystallized and what the important parameters are that control crystallization. Forty-two chapters cover such topics as: crystallization techniques; gel chemistry; crystal size and morphology; the role of organic compounds; and novel synthesis procedures. It offers a complete review of zeolite synthesis as well as the latest finding in this important field. Contains benchmark contributions from many notable pioneers in the field, including R.M. Barrer, H. Robson, and Robert Milton.

Zeolites in Sustainable Chemistry

Zeolites in Sustainable Chemistry PDF

Author: Feng-Shou Xiao

Publisher: Springer

Published: 2015-09-28

Total Pages: 485

ISBN-13: 366247395X

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This book is devoted to the new development of zeolitic catalysts with an emphasis on new strategies for the preparation of zeolites, novel techniques for their characterization and emerging applications of zeolites as catalysts for sustainable chemistry, especially in the fields of energy, biomass conversion and environmental protection. Over the years, energy and the environment have become the most important global issues, while zeolitic catalysts play important roles in addressing them. With individual chapters written by leading experts, this book offers an essential reference work for researchers and professionals in both academia and industry. Feng-Shou Xiao is a Professor at the Department of Chemistry, Zhejiang University, China. Xiangju Meng is an Associate Professor at the Department of Chemistry, Zhejiang University, China.

Handbook of Hydrothermal Technology

Handbook of Hydrothermal Technology PDF

Author: K. Byrappa

Publisher: William Andrew

Published: 2012-12-31

Total Pages: 796

ISBN-13: 1437778364

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Quartz, zeolites, gemstones, perovskite type oxides, ferrite, carbon allotropes, complex coordinated compounds and many more -- all products now being produced using hydrothermal technology. Handbook of Hydrothermal Technology brings together the latest techniques in this rapidly advancing field in one exceptionally useful, long-needed volume.The handbook provides a single source for understanding how aqueous solvents or mineralizers work under temperature and pressure to dissolve and recrystallize normally insoluble materials, and decompose or recycle any waste material. The result, as the authors show in the book, is technologically the most efficient method in crystal growth, materials processing, and waste treatment. The book gives scientists and technologists an overview of the entire subject including: À Evolution of the technology from geology to widespread industrial use. À Descriptions of equipment used in the process and how it works.À Problems involved with the growth of crystals, processing of technological materials, environmental and safety issues.À Analysis of the direction of today's technology. In addition, readers get a close look at the hydrothermal synthesis of zeolites, fluorides, sulfides, tungstates, and molybdates, as well as native elements and simple oxides. Delving into the commercial production of various types, the authors clarify the effects of temperature, pressure, solvents, and various other chemical components on the hydrothermal processes. Gives an overview of the evolution of Hydrothermal Technology from geology to widespread industrial use Describes the equipment used in the process and how it works Discusses problems involved with the growth of crystals, processing of technological materials, and environmental and safety issues

Natural Zeolites

Natural Zeolites PDF

Author: David L. Bish

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2018-12-17

Total Pages: 668

ISBN-13: 150150911X

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Volume 45 of Reviews in Mineralogy and Geochemistry is a new and expanded update of Volume 4 from 1977. Most of the material in this volume is entirely new, and Natural Zeolites: Occurrence, Properties, Applications presents a fresh and expanded look at many of the subjects contained in Volume 4. There has been an explosion in our knowledge of the crystal chemistry and structures of natural zeolites (Chapters 1 and 2), due in part to the now-common Rietveld method that allows treatment of powder diffraction data. Studies on the geochemistry of natural zeolites have also greatly increased, partly as a result of the interests related to the disposal of radioactive wastes, and Chapters 3, 4, 5, 13, and 14 detail the latest results in this important area. Until the latter part of the 20th century, zeolites were often looked upon as a geological curiosity, but they are now known to be widespread throughout the world in sedimentary and igneous deposits and in soils (Chapters 6-12). The application of natural zeolites has greatly expanded since the first zeolite volume. Chapter 15 details the use of natural zeolites for removal of ammonium ions, heavy metals, radioactive cations, and organic molecules from natural waters, wastewaters, and soils. Similarly, Chapter 16 describes the use of natural zeolites as building blocks and cements in the building industry, Chapter 17 outlines their use in solar energy storage, heating, and cooling applications, and Chapter 18 describes their use in a variety of agricultural applications, including as soil conditioners, slow-release fertilizers, soil-less substrates, carriers for insecticides and pesticides, and remediation agents in contaminated soils.

Fly Ash Zeolites

Fly Ash Zeolites PDF

Author: Bhagwanjee Jha

Publisher: Springer

Published: 2016-05-27

Total Pages: 211

ISBN-13: 9811014043

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This book presents a thorough review of the state-of-knowledge and recent innovations in the synthesis of pure and improved grades of fly ash zeolites (FAZ). Addressing improvements to conventional methods, it also showcases a novel technique for the synthesis of high cation exchangers from fly ash and detailed characterization techniques for the products obtained. In addition, it examines in detail various areas of specific applications of fly ash zeolites. Over the years, several methods such as hydrothermal, fusion prior to hydrothermal, microwave assisted hydrothermal and molten salt techniques for producing FAZ have been developed. However, one-step and two-step reactions between the fly ash and alkali usually generate alkaline wastes that may cause environmental contamination. In addition, the separation of FAZ from the partially activated fly ash (the impurities) remains a major concern for researchers and industrialists alike. /divIn view of these challenges, this book presents a novel technique for three-step activation (TSA), which focuses on recycling the fly ash-NaOH-water reaction by-products until zeolitic residue is formed. The FAZ (the final residue after third step reactions) synthesized in this manner exhibits exceptionally high cation exchange capacity, specific surface area and pore area. This book offers a comprehensive compendium of reading material on fly ash and its recycled product, the zeolites. Students at both undergraduate and graduate levels, researchers, and practicing engineers will all find this book to be a valuable guide in their respective fields.

Mesoporous Zeolites

Mesoporous Zeolites PDF

Author: Javier García-Martínez

Publisher: John Wiley & Sons

Published: 2015-05-14

Total Pages: 608

ISBN-13: 3527673989

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Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.

Zeolites in Catalysis

Zeolites in Catalysis PDF

Author: Jiří Čejka

Publisher: Royal Society of Chemistry

Published: 2017-06-07

Total Pages: 547

ISBN-13: 1782627847

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Covering the breadth of zeolite chemistry and catalysis, this book provides the reader with a complete introduction to field, covering synthesis, structure, characterisation and applications. Beginning with the history of natural and synthetic zeolites, the reader will learn how zeolite structures are formed, synthetic routes, and experimental and theoretical structure determination techniques. Their industrial applications are covered in-depth, from their use in the petrochemical industry, through to fine chemicals and more specialised clinical applications. Novel zeolite materials are covered, including hierarchical zeolites and two-dimensional zeolites, showcasing modern developments in the field. This book is ideal for newcomers who need to get up to speed with zeolite chemistry, and also experienced researchers who will find this a modern, up-to-date guide.