Electrochemistry at Metal and Semiconductor Electrodes

Electrochemistry at Metal and Semiconductor Electrodes PDF

Author: Norio Sato

Publisher: Elsevier

Published: 1998-10-09

Total Pages: 413

ISBN-13: 0080530737

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Electrochemisty at Metal and Semiconductor Electrodes covers the structure of the electrical double layer and charge transfer reactions across the electrode/electrolyte interface. The purpose of the book is to integrate modern electrochemistry and semiconductor physics, thereby, providing a quantitative basis for understanding electrochemistry at metal and semiconductor electrodes. Electrons and ions are the principal particles which play the main role in electrochemistry. This text, therefore, emphasizes the energy level concepts of electrons and ions rather than the phenomenological thermodynamic and kinetic concepts on which most of the classical electrochemistry texts are based. This rationalization of the phenomenological concepts in terms of the physics of semiconductors should enable readers to develop more atomistic and quantitative insights into processes that occur at electrodes. The book incorporates many traditional disciplines of science and engineering such as interfacial chemistry, biochemistry, enzyme chemistry, membrane chemistry, metallurgy, modification of solid interfaces, and materials' corrosion. The text is intended to serve as an introduction for the study of advanced electrochemistry at electrodes and is aimed towards graduates and senior undergraduates studying materials and interfacial chemistry or those beginning research work in the field of electrochemistry.

Electrochemistry at Semiconductor and Oxidized Metal Electrodes

Electrochemistry at Semiconductor and Oxidized Metal Electrodes PDF

Author: Stanley Roy Morrison

Publisher: Springer

Published: 1980-11-30

Total Pages: 424

ISBN-13:

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The objective of the present volume is to develop the theory and practice of nonmetal electrochemistry from first principles, emphasizing energy level models, in particular the fluctuating energy level model of Marcus and Gerischer. A single volume emphasizing these models. and the in terpretation of experiments based on these models, has not been available. Yet this area of electrochemical technology, where the use of such models is required, has developed a great deal of interest. This is not only because of the interest in photoelectrochemical solar cells, but also because of the importance of the concepts in corrosion, sensors, coated metal electrodes, and, indeed, to the general theory of electrode reactions. This book is an attempt to fill the void-to develop in a single volume the basic description of electrode reactions on nonmetallic electrodes and oxide-covered metal electrodes. The development of the fluctuating energy level model to describe electrode reactions on nonmetals (as described in Chapters I through 3) has permitted a significant forward step in the understanding of such re actions. The power of the model is illustrated by the simple methods available to determine the energy levels of interest-the conduction and valence bands of the nonmetals (Chapter 5), and their relation to the energy levels of oxidizing or reducing agents in solution. In Chapter 6, we illustrate the ability of the simple models. based on these parameters, to describe successfully electrode reactions at an inert electrode.

Handbook of Electrochemistry

Handbook of Electrochemistry PDF

Author: Cynthia G. Zoski

Publisher: Elsevier

Published: 2007-02-07

Total Pages: 935

ISBN-13: 0444519580

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Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Semiconductor Electrodes

Semiconductor Electrodes PDF

Author: Harry O. Finklea

Publisher: Elsevier Publishing Company

Published: 1988

Total Pages: 552

ISBN-13:

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Semiconductors have been studied as electrodes in electrochemical systems since the mid-1950's. However, it was not until the 1970's that the search for alternative energy sources, especially solar energy, led to an enormous expansion in semiconductor electrode research. One attractive option for solar energy conversion is the semiconductor liquid-junction solar cell, which can be designed to produce either electrical power or fuel such as hydrogen. Consequently the number of papers published concerning semiconductor electrodes has rapidly increased. Previous books have principally focused on the underlying theory (largely from solid state physics) and principles of operation of all semiconductor electrodes. It therefore seemed both useful and appropriate to review the field with the intention of collating information for each semiconductor or family of semiconductors, with contributions from authors who are all recognized experts in their field. Each chapter is devoted to critically assessing the recent literature on a particular semiconductor or family of semiconductors.

Electrochemistry of Metal Chalcogenides

Electrochemistry of Metal Chalcogenides PDF

Author: Mirtat Bouroushian

Publisher: Springer Science & Business Media

Published: 2010-04-23

Total Pages: 365

ISBN-13: 3642039677

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The author provides a unified account of the electrochemical material science of metal chalcogenide (MCh) compounds and alloys with regard to their synthesis, processing and applications. Starting with the chemical fundamentals of the chalcogens and their major compounds, the initial part of the book includes a systematic description of the MCh solids on the basis of the Periodic Table in terms of their structures and key properties. This is followed by a general discussion on the electrochemistry of chalcogen species, and the principles underlying the electrochemical formation of inorganic compounds/alloys. The core of the book offers an insight into available experimental results and inferences regarding the electrochemical preparation and microstructural control of conventional and novel MCh structures. It also aims to survey their photoelectrochemistry, both from a material-oriented point of view and as connected to specific processes such as photocatalysis and solar energy conversion. Finally, the book illustrates the relevance of MCh materials to various applications of electrochemical interest such as (electro)catalysis in fuel cells, energy storage with intercalation electrodes, and ion sensing.

Electrochemistry for Materials Science

Electrochemistry for Materials Science PDF

Author: Walfried Plieth

Publisher: Elsevier

Published: 2008-01-08

Total Pages: 433

ISBN-13: 0080556256

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This book introduces the principles of electrochemistry with a special emphasis on materials science. This book is clearly organized around the main topic areas comprising electrolytes, electrodes, development of the potential differences in combining electrolytes with electrodes, the electrochemical double layer, mass transport, and charge transfer, making the subject matter more accessible.In the second part, several important areas for materials science are described in more detail. These chapters bridge the gap between the introductory textbooks and the more specialized literature. They feature the electrodeposition of metals and alloys, electrochemistry of oxides and semiconductors, intrinsically conducting polymers, and aspects of nanotechnology with an emphasis on the codeposition of nanoparticles.This book provides a good introduction into electrochemistry for the graduate student. For the research student as well as for the advanced reader there is sufficient information on the basic problems in special chapters. The book is suitable for students and researchers in chemistry, physics, engineering, as well as materials science. - Introduction into electrochemistry- Metal and alloy electrodeposition- Oxides and semiconductors, corrosion- Intrinsically conducting polymers- Codeposition of nanoparticles, multilayers

Interfacial Electrochemistry

Interfacial Electrochemistry PDF

Author: Wolfgang Schmickler

Publisher: Springer Science & Business Media

Published: 2010-08-26

Total Pages: 273

ISBN-13: 3642049370

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Electrochemistry is an old branch of physical chemistry. Due to the development of surface sensitive techniques, and a technological interest in fuel cells and batteries, it has recently undergone a rapid development. This textbook treats the field from a modern, atomistic point of view while integrating the older, macroscopic concepts. The increasing role of theory is reflected in the presentation of the basic ideas in a way that should appeal to experimentalists and theorists alike. Special care is taken to make the subject comprehensible to scientists from neighboring disciplines, especially from surface science. The book is suitable for an advanced course at the master or Ph.D. level, but should also be useful for practicing electrochemists, as well as to any scientist who wants to understand modern electrochemistry.

Semiconductor Electrochemistry

Semiconductor Electrochemistry PDF

Author: Rüdiger Memming

Publisher: John Wiley & Sons

Published: 2008-09-26

Total Pages: 409

ISBN-13: 3527613072

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Semiconductor electrochemistry deals with many aspects, ranging from fundamental semiconductor physics to complex effects, such as charge transfer processes at semiconductor-liquid surfaces or photoreactions at semiconductor particles. Its applications cover important fields of present and future technology including solar energy conversion or semiconductor device technology, micromachining, and nanotechnology. Providing both an introduction and an up-to-date survey to the whole field, this text captivates by its clear style and inspiring, yet solid presentation. Rudger Memming, an acknowledged expert, primarily addresses physical chemists and electrochemists, but materials scientists, physicists, and engineers dealing with semiconductor technology and its applications will also benefit greatly from this text.

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