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Electro-Osmosis of Polymer Solutions

Author: Yuki Uematsu

Publisher: Springer

Published: 2017-01-11

Total Pages: 76

ISBN-13: 9811034249

This thesis focuses on the theoretical description of electro-osmosis of polymer solutions. In particular, it emphasizes the importance of considering non-uniform profiles of the solution viscosity and polymer concentration near a solid surface. The thesis begins with an introduction to fundamental theories and experimental observations for beginners in this field, concerning electrolyte solutions, electric double layers, and electrokinetics. In Chapter 2, the author discusses the linear response of electro-osmotic flow with respect to applied electric fields in aqueous polyelectrolyte solutions, and predicts a possibility of flow reversal caused by oppositely charged polyelectrolytes adsorbed on a charged surface. In Chapter 3, the author extends the discussion to non-linear electro-osmotic flow driven by applied electric fields in neutral polymer solutions. The dynamics of polymers are modeled and simulated using Brownian dynamics and kinetic theory. Finally, the thesis is summarized in Chapter 4. The introduction provides a comprehensive review of electrokinetics for graduate students and researchers interested in soft matter physics. An additional attraction is that readers can effectively learn various theoretical approaches to electro-osmosis.

Micro/Nano-Chip Electrokinetics, Volume III

Author: Xiangchun Xuan

Publisher: MDPI

Published: 2021-02-24

Total Pages: 228

ISBN-13: 3036500480

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Micro/nanofluidics-based lab-on-a-chip devices have found extensive applications in the analysis of chemical and biological samples over the past two decades. Electrokinetics is the method of choice in these micro/nano-chips for transporting, manipulating, and sensing various analyte species (e.g., ions, molecules, fluids, and particles). This book aims to highlight the recent developments in the field of micro/nano-chip electrokinetics, ranging from the fundamentals of electrokinetics to the applications of electrokinetics to both chemo- and bio-sample handling.

Capillary Electrophoresis

Author: S.F.Y. Li

Publisher: Elsevier

Published: 1992-07-31

Total Pages: 581

ISBN-13: 9780080858609

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Capillary Electrophoresis (CE) has had a very significant impact on the field of analytical chemistry in recent years as the technique is capable of very high resolution separations, requiring only small amounts of samples and reagents. Furthermore, it can be readily adapted to automatic sample handling and real time data processing. Many new methodologies based on CE have been reported. Rapid, reproducible separations of extremely small amounts of chemicals and biochemicals, including peptides, proteins, nucleotides, DNA, enantiomers, carbohydrates, vitamins, inorganic ions, pharmaceuticals and environmental pollutants have been demonstrated. A wide range of applications have been developed in greatly diverse fields, such as chemical, biotechnological, environmental and pharmaceutical analysis. This book covers all aspects of CE, from the principles and technical aspects to the most important applications. It is intended to meet the growing need for a thorough and balanced treatment of CE. The book will serve as a comprehensive reference work. Both the experienced analyst and the newcomer will find the text useful.

Physics of Polymer Gels

Author: Takamasa Sakai

Publisher: John Wiley & Sons

Published: 2020-04-20

Total Pages: 298

ISBN-13: 3527346414

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Explains the correlation between the physical properties and structure of polymer gels This book elucidates in detail the physics of polymer gels and reviews their unique properties that make them attractive for innumerable applications. Geared towards experienced researchers and entrants to the field, it covers rubber elasticity, swelling and shrinking, deformation and fracture of as well as mass transport in polymer gels, enabling the readers to purposefully design polymer gels fit for specific purposes. Divided into two parts, Physics of Polymer Gels starts by explaining the statistical mechanics and scaling of a polymer chains, and that of polymer solutions. It then introduces the structure of polymer gels and explains the rubber elasticity, which predicts the solid-like nature of polymer gels. Next, it describes swelling/deswelling, which can be understood by combining the rubber elasticity and the osmotic pressure of a polymer solution. Large deformation and fracture, and the diffusion of substances in polymer gels, which are essential for practical applications, are also introduced. The last half of the book contains the authors' experimental results using Tetra-PEG gels and provides readers with the opportunity to examine and compare it with the first half in order to understand how to utilize the models to experiments. This title: * Is the first book dedicated to the physics of polymer gels * Describes in detail the properties of polymer gels and their underlying physics, facilitating the development of novel, polymer gel-based applications * Serves as a reference for all relevant polymer gel properties and their underlying physics * Provides a unified treatment of the subject, explaining the physical properties of polymer gels within a common nomenclature framework Physics of Polymer Gels is a must-have book for experienced researchers, such as polymer chemists, materials scientists, organic chemists, physical chemists, and solid-state physicists, as well as for newcomers to the field.

Transport and Mixing in Laminar Flows

Author: Roman Grigoriev

Publisher: John Wiley & Sons

Published: 2012-01-09

Total Pages: 178

ISBN-13: 3527639756

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This book provides readers from academia and industry with an up-to-date overview of important advances in the field, dealing with such fundamental fluid mechanics problems as nonlinear transport phenomena and optimal control of mixing at the micro- and nanoscale. The editors provide both in-depth knowledge of the topic as well as vast experience in guiding an expert team of authors. The review style articles offer a coherent view of the micromixing methods, resulting in a much-needed synopsis of the theoretical models needed to direct experimental research and establish engineering principles for future applications. Since these processes are governed by nonlinear phenomena, this book will appeal to readers from both communities: fluid mechanics and nonlinear dynamics.

Interfacial Electroviscoelasticity and Electrophoresis

Author: Jyh-Ping Hsu

Publisher: CRC Press

Published: 2010-03-17

Total Pages: 194

ISBN-13: 9781439803530

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In the 20 years since the pilot plant experiments used to develop the concept of electroviscoelasticity, inroads have been made in the understanding of its many related processes. Interfacial Electroviscoelasticity and Electrophoresis meets a massive scientific challenge by presenting deeper research and developments in the basic and applied science and engineering of finely dispersed particles and related systems. Introducing more profound and in-depth treatises related to the liquid-liquid finely dispersed systems (i.e., emulsions and double emulsions), this book describes a new theory developed through the authors’ work. These findings are likely to impact other research and applications in a wide array of other fields, considering that the modeling of liquid-liquid interfaces is key to numerous chemical manufacturing processes, including those used for emulsions, suspensions, nanopowders, foams, biocolloids, and plasmas. The authors cover phenomena at the micro, nano, and atto-scales, and their techniques, theory, and supporting data will be of particular interest to nanoscientists, especially with regard to the breaking of emulsions. This groundbreaking book: Takes an interdisciplinary approach to elucidate the momentum transfer and electron transfer phenomena Covers less classical chemical engineering insight and modern molecular and atomic engineering Reviews basic theory of electrokinetics, using the electrophoresis of rigid particles as an example Built around the central themes of hydrodynamic, electrodynamic, and thermodynamic instabilities that occur at interfaces, this book addresses recently developed concepts in the physics, chemistry, and rheological properties of those well-studied interfaces of rigid and deformable particles in homo- and hetero-aggregate dispersed systems. The book also introduces the key phenomenon of electrophoresis, since it is widely adopted either as an analytical tool to characterize the surface properties of colloid-sized particles or in the separation and purification process of both laboratory and industrial scales. The applications and implications of the material presented in the book represent a major contribution to the advanced fundamental, applied, and engineering research of interfacial and colloidal phenomena.

Microclimate for Cultural Heritage

Author: Dario Camuffo

Publisher: Elsevier

Published: 2019-06-28

Total Pages: 582

ISBN-13: 0444641076

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Microclimate for Cultural Heritage: Measurement, Risk Assessment, Conservation, Restoration, and Maintenance of Indoor and Outdoor Monuments, Third Edition, presents the latest on microclimates, environmental issues and the conservation of cultural heritage. It is a useful treatise on microphysics, acting as a practical handbook for conservators and specialists in physics, chemistry, architecture, engineering, geology and biology who focus on environmental issues and the conservation of works of art. It fills a gap between the application of atmospheric sciences, like the thermodynamic processes of clouds and dynamics of planetary boundary layer, and their application to a monument surface or a room within a museum. Sections covers applied theory, environmental issues and conservation, practical utilization, along with suggestions, examples, common issues and errors. Incorporates research on the effects of climate change from Climate for Culture, the EU funded, five-year project focusing on climate change’s impact on cultural heritage preservation Covers green lighting technology, like LED and OLED, it’s impacts on indoor microclimates, preservation and color rendering Includes a case study on sea level issues and cultural heritage in Venice

Electroseparations in Thermoplastic Microfabricated Channels. Fluorescence Detection Strategies and Effects of Electroosmosis

Author: Shau-Chun Wang

Publisher:

Published: 2000

Total Pages: 218

ISBN-13:

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Polymer Interfaces and Emulsions

Author: Kunio Esumi

Publisher: CRC Press

Published: 2020-08-13

Total Pages: 588

ISBN-13: 1000146243

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"Presents the latest knowledge on a wide range of topics in polymer science, including the dynamics, preparation, application, and physiochemical properties of polymer solutions and colloids; the adsorption characteristics at polymer surfaces; and the adhesion properties (including acid-base) of polymer surfaces."

Capillary Electrophoresis of Nucleic Acids

Author: Keith R. Mitchelson

Publisher: Springer Science & Business Media

Published: 2008-02-05

Total Pages: 481

ISBN-13: 1592590551

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The development of PCR, which enables extremely small amounts of DNA to be amplified, led to the rapid development of a multiplicity of a- lytical procedures that permit use of this new resource for the analysis of genetic variation and for the detection of disease-causing mutations. The advent of capillary electrophoresis (CE), with its power to separate and a- lyze very small amounts of DNA, has also stimulated researchers to develop analytical procedures for the CE format. The advantages of CE in terms of speed and reproducibility of analyses are manifold. Furthermore, the high s- sitivity of detection, and the ability to increase sample throughput with par- lel analysis, has led to the creation of a full range of analysis of DNA molecules, from modified DNA adducts and single-strand oligonucleotides through PCR-amplified DNA fragments and whole chromosomes. Capillary Elect- phoresis of Nucleic Acids focuses on analytical protocols that can be used for detection and analysis of mutations and modification, from precise DNA loci through entire genomes of organisms. Important practical considerations for CE, such as the choice of separation media, electrophoresis conditions, and the influence of buffer additives and dyes on DNA mobility, are discussed in several key chapters and within particular applications.