Cumulenes in Click Reactions

Cumulenes in Click Reactions PDF

Author: Henri Ulrich

Publisher: John Wiley & Sons

Published: 2009-11-19

Total Pages: 562

ISBN-13: 9780470747933

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Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields – features characteristic of “click reactions”. Cumulenes in Click Reactions presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their “click-like” nature. The chapters are structured according to the number of carbon atoms in the system, including coverage of: introduction to the chemistry of cumulenes one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes, and diarsaallenes 1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes 1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides 1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry.

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry PDF

Author:

Publisher: Academic Press

Published: 2016-01-28

Total Pages: 324

ISBN-13: 0128048468

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Advances in Heterocyclic Chemistry is the definitive series in the field—one of great importance to organic chemists, polymer chemists, and many biological scientists. Because biology and organic chemistry increasingly intersect, the associated nomenclature also is being used more frequently in explanations. Written by established authorities in the field from around the world, this comprehensive review combines descriptive synthetic chemistry and mechanistic insight to yield an understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds. Considered the definitive serial in the field of heterocyclic chemistry Serves as the go-to reference for organic chemists, polymer chemists, and many biological scientists Provides the latest comprehensive reviews written by established authorities in the field Combines descriptive synthetic chemistry and mechanistic insight to enhance understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds

Polyurethanes

Polyurethanes PDF

Author: Mark F. Sonnenschein

Publisher: John Wiley & Sons

Published: 2020-12-11

Total Pages: 524

ISBN-13: 1119669472

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This book, cohesively written by an expert author with supreme breadth and depth of perspective on polyurethanes, provides a comprehensive overview of all aspects of the science and technology on one of the most commonly produced plastics. Covers the applications, manufacture, and markets for polyurethanes, and discusses analytical methods, reaction mechanisms, morphology, and synthetic routes Provides an up-to-date view of the current markets and trend analysis based on patent activity and updates chapters to include new research Includes two new chapters on PU recycling and PU hybrids, covering the opportunities and challenges in both

Organic Azides

Organic Azides PDF

Author: Stefan Bräse

Publisher: John Wiley & Sons

Published: 2011-09-23

Total Pages: 536

ISBN-13: 0470682523

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Most current state-of-the-art overview of this important class of compounds, encompassing many new and emerging applications The number of articles on organic azides continues to increase tremendously; on average, there are more than 1000 new publications a year Covers basic chemistry as well as state-of-the-art applications in life science and materials science World-ranked authors describe their own research in the wider context of azide chemistry Includes a chapter on safe synthesis and handling (azides can decompose explosively)

Best Synthetic Methods: Acetylenes, Allenes and Cumulenes

Best Synthetic Methods: Acetylenes, Allenes and Cumulenes PDF

Author: Lambert Brandsma

Publisher: Elsevier

Published: 2003-12-16

Total Pages: 502

ISBN-13: 9780080542201

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There is a vast and often bewildering array of synthetic methods and reagents available to organic chemists today. The Best Synthetic Methods series allows any scientist who is interested in the chemical transformations of molecules to choose between all the alternatives and assess their real advantages and limitations. With the emphasis on laboratory use, these volumes represent a comprehensive and practical guide to modern synthetic organic chemistry. Best Synthetic Methods: Acetylenes, Allenes and Cumulenes is the product of the author's many years practical experience and reading of the original literature. It contains a valuable distillation and critical evaluation of the Best Synthetic Methods for the formation and reaction of molecules containing carbon-carbon triple bonds or cumulative carbon-carbon double bonds. A brief review of each area is provided, but the emphasis in all cases is on describing efficient practical methods to effect the transformations described. The reader can therefore use this book to rapidly review and select the best methods of performing a synthetic conversion to create or modify a molecule containing an acetylene, allene or cumulene functionality. In addition, the documentation of a large number of experimental recipes enables the user to synthesise an unsaturated molecule without the need to access to the original literature. Reviews and evaluates the various methods for the formation and reaction of acetylenes, cumulenes and allenes Provides detailed practical experimental for many important reactions General tips and analytical data are provided from the author's own extensive research in this area

Progress in Heterocyclic Chemistry

Progress in Heterocyclic Chemistry PDF

Author: Gordon W. Gribble

Publisher: Newnes

Published: 2012-11-29

Total Pages: 587

ISBN-13: 0080968074

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Annotation 'Progress in Heterocyclic Chemistry' is an annual review commissioned by the International Society of Heterocyclic Chemistry. The volumes contain both highlights of the previous year's literature on heterocyclic chemistry and articles on emerging topics of particular interest to heterocyclic chemists.

Synthesis of Heterocycles via Cycloadditions I

Synthesis of Heterocycles via Cycloadditions I PDF

Author: Alfred Hassner

Publisher: Springer

Published: 2008-04-10

Total Pages: 239

ISBN-13: 3540783717

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Heterocyclic chemistry is the biggest branch of chemistry covering two-thirds of the chemical literature. This series covers hot topics of frontier research summarized by reputed scientists in the field.

Strained Hydrocarbons

Strained Hydrocarbons PDF

Author: Helena Dodziuk

Publisher: John Wiley & Sons

Published: 2009-03-30

Total Pages: 492

ISBN-13: 3527627146

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In clearly structured chapters, this book covers the fascinating world of hydrocarbons, providing an insight into the fundamental principles of chemistry. The monograph covers modern aspects of the topic, such as carbon nanotubes, molecular flask inclusion, and fullerenes, with new synthetic procedures for the build up of the structural lattice included.

Fullerenes and Other Carbon-Rich Nanostructures

Fullerenes and Other Carbon-Rich Nanostructures PDF

Author: Jean-François Nierengarten

Publisher: Springer

Published: 2014-05-16

Total Pages: 262

ISBN-13: 3642548547

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Yanfei Shen and Takashi Nakanishi Exotic Self-Organized Fullerene Materials Based on Uncommon Hydrophobic–Amphiphilic Approach Yuming Zhao and Guang Chen C60 Fullerene Amphiphiles as Supramolecular Building Blocks for Organized and Well-Defined Nano scale Objects Anna Troeger, Vito Sgobba and Dirk M. Guldi Multilayer Assembly for Solar Energy Conversion Delphine Felder-Flesch Self- or Induced Organization of [60]Fullerene Hexakisadducts Andrés de la Escosura, Olga Trukhina, and Tomás Torres Dual Role of Phthalocyanines in Carbon Nano structure-Based Organic Photovoltaics Riccardo Marega, Davide Giust and Davide Bonifazi Supramolecular Chemistry of Carbon Nano tubes at Interfaces: Toward Applications Stephanie Frankenberger, Johanna A. Januszewski and Rik R. Tykwinski Oligomers from sp-Hybridized Carbon: Cumulenes and Polyynes.

Molecular Vibrations

Molecular Vibrations PDF

Author: E. Bright Wilson

Publisher: Courier Corporation

Published: 2012-05-11

Total Pages: 418

ISBN-13: 0486137155

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Pedagogical classic and essential reference focuses on mathematics of detailed vibrational analyses of polyatomic molecules, advancing from application of wave mechanics to potential functions and methods of solving secular determinant.