Constitutive Modeling of Nanotube-reinforced Polymer Composite Systems

Constitutive Modeling of Nanotube-reinforced Polymer Composite Systems PDF

Author: Gregory M. Odegard

Publisher:

Published: 2001

Total Pages: 20

ISBN-13:

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In this study, a technique has been proposed for developing constitive models for polymer composite systems reinforced with single-walled carbon nanotubes (SWNT). Since the polymer molecules are on the same size scale as the nanotubes, the interaction at the polymer/nanotube interface is highly dependent on the local molecular structure and bonding. At these small length scales, the lattice structures of the nanotube and polymer chains cannot be be considered continuous, and the bulk mechanical properties of the SWNT/polymer composites can no longer be determined through traditional micromechanical approaches that are formulated using continuum mechanics. It is proposed herein that the nanotube, the local polymer near the nanotube, and the nanotube/polymer interface can be modeled as an effective continuum fiber using an equivalent-continuum modeling method.

Constitutive Modeling of Nanotube-Reinforced Polymer Composites

Constitutive Modeling of Nanotube-Reinforced Polymer Composites PDF

Author: National Aeronautics and Space Administration (NASA)

Publisher: Createspace Independent Publishing Platform

Published: 2018-05-29

Total Pages: 36

ISBN-13: 9781720451501

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In this study, a technique is presented for developing constitutive models for polymer composite systems reinforced with single-walled carbon nanotubes (SWNT). Because the polymer molecules are on the same size scale as the nanotubes, the interaction at the polymer/nanotube interface is highly dependent on the local molecular structure and bonding. At these small length scales, the lattice structures of the nanotube and polymer chains cannot be considered continuous, and the bulk mechanical properties can no longer be determined through traditional micromechanical approaches that are formulated by using continuum mechanics. It is proposed herein that the nanotube, the local polymer near the nanotube, and the nanotube/polymer interface can be modeled as an effective continuum fiber using an equivalent-continuum modeling method. The effective fiber serves as a means for incorporating micromechanical analyses for the prediction of bulk mechanical properties of SWNT/polymer composites with various nanotube lengths, concentrations, and orientations. As an example, the proposed approach is used for the constitutive modeling of two SWNT/polyimide composite systems.Odegard, G. M. and Gates, T. S. and Wise, K. E. and Park, C. and Siochi, E. J. and Bushnell, Dennis M. (Technical Monitor)Langley Research CenterCARBON NANOTUBES; POLYMERS; MOLECULAR STRUCTURE; BONDING; COMPOSITE STRUCTURES; CONTINUUM MODELING; MATHEMATICAL MODELS; MECHANICAL PROPERTIES; MOLECULAR CHAINS; POLYIMIDES

Constitutive Modeling of Nanotube-Reinforced Polymer Composite Systems

Constitutive Modeling of Nanotube-Reinforced Polymer Composite Systems PDF

Author: National Aeronautics and Space Administration (NASA)

Publisher: Createspace Independent Publishing Platform

Published: 2018-06-20

Total Pages: 32

ISBN-13: 9781721268702

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In this study, a technique has been proposed for developing constitutive models for polymer composite systems reinforced with single-walled carbon nanotubes (SWNT). Since the polymer molecules are on the same size scale as the nanotubes, the interaction at the polymer/nanotube interface is highly dependent on the local molecular structure and bonding. At these small length scales, the lattice structures of the nanotube and polymer chains cannot be considered continuous, and the bulk mechanical properties of the SWNT/polymer composites can no longer be determined through traditional micromechanical approaches that are formulated using continuum mechanics. It is proposed herein that the nanotube, the local polymer near the nanotube, and the nanotube/polymer interface can be modeled as an effective continuum fiber using an equivalent-continuum modeling method. The effective fiber retains the local molecular structure and bonding information and serves as a means for incorporating micromechanical analyses for the prediction of bulk mechanical properties of SWNT/polymer composites with various nanotube sizes and orientations. As an example, the proposed approach is used for the constitutive modeling of two SWNT/polyethylene composite systems, one with continuous and aligned SWNT and the other with discontinuous and randomly aligned nanotubes. Odegard, Gregory M. and Harik, Vasyl M. and Wise, Kristopher E. and Gates, Thomas S. Langley Research Center NASA/TM-2001-211044, L-18094, NAS 1.15:211044

Constitutive Modeling of Nanotube-Reinforced Polymer Composites

Constitutive Modeling of Nanotube-Reinforced Polymer Composites PDF

Author: G. M. Odegard

Publisher:

Published: 2002

Total Pages: 38

ISBN-13:

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In this study, a technique is presented for developing constitutive models for polymer composite systems reinforced with single-walled carbon nanotubes (SWNT). Because the polymer molecules are on the same size scale as the nanotubes, the interaction at the polymer/nanotube interface is highly dependent on the local molecular structure and bonding. At these small length scales, the lattice structures of the nanotube and polymer chains cannot be considered continuous, and the bulk mechanical properties can no longer be determined through the traditional micromechanical approaches that are formulated by using continuum mechanics. It is proposed herein that the nanotube, the local polymer near the nanotube, and the nanotube/polymer interface can be modeled as an effective continuum fiber using an equivalent-continuum modeling method. The micromechanical analyses for the prediction of bulk mechanical properties of SWNT/polymer composites with various nanotube lengths, concentrations, and orientations. As an example, the proposed approach is used for the constitutive modeling of two SWNT/polyimide composite systems.

Carbon Nanotube-Reinforced Polymers

Carbon Nanotube-Reinforced Polymers PDF

Author: Roham Rafiee

Publisher: Elsevier

Published: 2017-10-06

Total Pages: 586

ISBN-13: 0323482228

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Carbon Nanotube-Reinforced Polymers: From Nanoscale to Macroscale addresses the advances in nanotechnology that have led to the development of a new class of composite materials known as CNT-reinforced polymers. The low density and high aspect ratio, together with their exceptional mechanical, electrical and thermal properties, render carbon nanotubes as a good reinforcing agent for composites. In addition, these simulation and modeling techniques play a significant role in characterizing their properties and understanding their mechanical behavior, and are thus discussed and demonstrated in this comprehensive book that presents the state-of-the-art research in the field of modeling, characterization and processing. The book separates the theoretical studies on the mechanical properties of CNTs and their composites into atomistic modeling and continuum mechanics-based approaches, including both analytical and numerical ones, along with multi-scale modeling techniques. Different efforts have been done in this field to address the mechanical behavior of isolated CNTs and their composites by numerous researchers, signaling that this area of study is ongoing. Explains modeling approaches to carbon nanotubes, together with their application, strengths and limitations Outlines the properties of different carbon nanotube-based composites, exploring how they are used in the mechanical and structural components Analyzes the behavior of carbon nanotube-based composites in different conditions

Modeling of Carbon Nanotubes, Graphene and their Composites

Modeling of Carbon Nanotubes, Graphene and their Composites PDF

Author: Konstantinos I. Tserpes

Publisher: Springer Science & Business Media

Published: 2013-10-15

Total Pages: 341

ISBN-13: 3319012010

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A large part of the research currently being conducted in the fields of materials science and engineering mechanics is devoted to carbon nanotubes and their applications. In this process, modeling is a very attractive investigation tool due to the difficulties in manufacturing and testing of nanomaterials. Continuum modeling offers significant advantages over atomistic modeling. Furthermore, the lack of accuracy in continuum methods can be overtaken by incorporating input data either from experiments or atomistic methods. This book reviews the recent progress in continuum modeling of carbon nanotubes and their composites. The advantages and disadvantages of continuum methods over atomistic methods are comprehensively discussed. Numerical models, mainly based on the finite element method, as well as analytical models are presented in a comparative way starting from the simulation of isolated pristine and defected nanotubes and proceeding to nanotube-based composites. The ability of continuum methods to bridge different scales is emphasized. Recommendations for future research are given by focusing on what still continuum methods have to learn from the nano-scale. The scope of the book is to provide current knowledge aiming to support researchers entering the scientific area of carbon nanotubes to choose the appropriate modeling tool for accomplishing their study and place their efforts to further improve continuum methods.

Shape Memory Polymer Composites

Shape Memory Polymer Composites PDF

Author: Nilesh Tiwari

Publisher: CRC Press

Published: 2023-12-12

Total Pages: 225

ISBN-13: 1000993779

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Shape Memory Polymer Composites discusses the fabrication of smart polymer composites with their material characterization. It covers shape memory polymer composites with two different types of reinforcement: shape memory polymer nanocomposites and shape memory hybrid composites. Enhancing the mechanical and thermomechanical properties of the shape memory polymers makes them an important class of materials for new age applications ranging from aerospace, biomedical, electronics, to marine engineering. The book discusses how shape memory polymer composites exhibit remarkable mechanical properties, as compared to its corresponding shape memory polymers, without compromising the shape memory behavior. It presents experimental case studies of polymers, polymer composites, and multiphase composites, explaining the effects of each reinforcement on the material properties with corresponding simulation. The book will be a useful reference for industry professionals and researchers involved with the mechanics of shape memory materials.

Modeling and Prediction of Polymer Nanocomposite Properties

Modeling and Prediction of Polymer Nanocomposite Properties PDF

Author: Vikas Mittal

Publisher: John Wiley & Sons

Published: 2012-12-07

Total Pages: 312

ISBN-13: 3527644350

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The book series 'Polymer Nano-, Micro- and Macrocomposites' provides complete and comprehensive information on all important aspects of polymer composite research and development, including, but not limited to synthesis, filler modification, modeling, characterization as well as application and commercialization issues. Each book focuses on a particular topic and gives a balanced in-depth overview of the respective subfi eld of polymer composite science and its relation to industrial applications. With the books the readers obtain dedicated resources with information relevant to their research, thereby helping to save time and money. This book lays the theoretical foundations and emphasizes the close connection between theory and experiment to optimize models and real-life procedures for the various stages of polymer composite development. As such, it covers quantum-mechanical approaches to understand the chemical processes on an atomistic level, molecular mechanics simulations to predict the filler surface dynamics, finite element methods to investigate the macro-mechanical behavior, and thermodynamic models to assess the temperature stability. The whole is rounded off by a look at multiscale models that can simulate properties at various length and time scales in one go - and with predictive accuracy.

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