Consequences of hydroxyl generation by the silica/water reaction - Part II: Global and local Swelling - Part III: Damage and Young's Modulus

Consequences of hydroxyl generation by the silica/water reaction - Part II: Global and local Swelling - Part III: Damage and Young's Modulus PDF

Author: Fett, Theo

Publisher: KIT Scientific Publishing

Published: 2022-07-11

Total Pages: 226

ISBN-13: 3731511592

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Water diffusing into silica surfaces gives rise for several effects on diffusion behaviour and mechanical properties. In a preceding booklet, we focused on diffusion and fiber strengths and deformations which were obtained by water soaking under external loading. In the present booklet we deal with results and interpretations of strength increase in the absence of applied stresses.

Consequences of hydroxyl generation by the silica/water reaction - Part I: Diffusion and Swelling

Consequences of hydroxyl generation by the silica/water reaction - Part I: Diffusion and Swelling PDF

Author: Fett, Theo

Publisher: KIT Scientific Publishing

Published: 2022-07-11

Total Pages: 226

ISBN-13: 3731511487

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Water diffusing into silica surfaces gives rise for several effectson diffusion behaviour and mechanical properties. Water added to silica glass increases its specific volume so that the silica expands near the surface. Mechanical boundary conditions give rise for compressive “swelling stresses”. This fact provides a tool for the interpretation of many experimental observations from literature.

Alkoxysilanes and the Consolidation of Stone

Alkoxysilanes and the Consolidation of Stone PDF

Author: George Wheeler

Publisher: Getty Publications

Published: 2005

Total Pages: 215

ISBN-13: 0892368152

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Stone is one of the oldest building materials, and its conservation ranks as one of the most challenging in the field. The use of alkoxysilanes in the conservation of stone can be traced as far back as 1861, when A. W. von Hoffman suggested their use for the deteriorating limestone on the Houses of Parliament in London. Alkoxysilane-based formulations have since become the material of choice for the consolidation of stone outdoors.^l This volume, the first to cover comprehensively alkoxysilanes in stone consolidation, synthesizes the subject's vast and extensive literature, which ranges from production of alkoxysilanes in the nineteenth century to the extensive contributions from sol-gel science in the 1980s and 90s. Included are a historical overview, an annotated bibliography, and discussions of the following topics: the chemistry and physics of alkoxysilanes and their gels; the influence of stone type; commercial and noncommercial formulations; practice; lab and field evaluation of service life; and recent developments. This book is designed for conservators, scientists, and preservation architects in the field of stone conservation and will also serve as an indispensable introduction to the subject for students of art conservation and historic preservation.

Polymer Science and Engineering

Polymer Science and Engineering PDF

Author: National Research Council

Publisher: National Academies Press

Published: 1994-01-01

Total Pages: 193

ISBN-13: 0309049989

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Polymers are used in everything from nylon stockings to commercial aircraft to artificial heart valves, and they have a key role in addressing international competitiveness and other national issues. Polymer Science and Engineering explores the universe of polymers, describing their properties and wide-ranging potential, and presents the state of the science, with a hard look at downward trends in research support. Leading experts offer findings, recommendations, and research directions. Lively vignettes provide snapshots of polymers in everyday applications. The volume includes an overview of the use of polymers in such fields as medicine and biotechnology, information and communication, housing and construction, energy and transportation, national defense, and environmental protection. The committee looks at the various classes of polymersâ€"plastics, fibers, composites, and other materials, as well as polymers used as membranes and coatingsâ€"and how their composition and specific methods of processing result in unparalleled usefulness. The reader can also learn the science behind the technology, including efforts to model polymer synthesis after nature's methods, and breakthroughs in characterizing polymer properties needed for twenty-first-century applications. This informative volume will be important to chemists, engineers, materials scientists, researchers, industrialists, and policymakers interested in the role of polymers, as well as to science and engineering educators and students.

Sol-Gel Optics

Sol-Gel Optics PDF

Author: Lisa C. Klein

Publisher: Springer Science & Business Media

Published: 2013-11-27

Total Pages: 589

ISBN-13: 1461527503

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Sol--Gel--Optics encompasses numerous schemes for fabricating optical materials from gels -- materials such as bulk optics, optical waveguides, doped oxides for laser and nonlinear optics, gradient refractive index (GRIN) optics, chemical sensors, environmental sensors, and `smart' windows. Sol--Gel--Optics: Processing and Applications provides in-depth coverage of the synthesis and fabrication of these materials and discusses the optics related to microporous, amorphous, crystalline and composite materials. The reader will also find in this book detailed descriptions of new developments in silica optics, bulk optics, waveguides and thin films. Various applications to sensor and device technology are highlighted. For researchers and students looking for novel optical materials, processing methods or device ideas, Sol--Gel--Optics: Processing and Applications surveys a wide array of promising new avenues for further investigation and for innovative applications. (This book is the first in a new subseries entitled `Electronic Materials: Science and Technology).

CRC Handbook of Metal Etchants

CRC Handbook of Metal Etchants PDF

Author: Perrin Walker

Publisher: CRC Press

Published: 1990-12-11

Total Pages: 1434

ISBN-13: 9781439822531

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This publication presents cleaning and etching solutions, their applications, and results on inorganic materials. It is a comprehensive collection of etching and cleaning solutions in a single source. Chemical formulas are presented in one of three standard formats - general, electrolytic or ionized gas formats - to insure inclusion of all necessary operational data as shown in references that accompany each numbered formula. The book describes other applications of specific solutions, including their use on other metals or metallic compounds. Physical properties, association of natural and man-made minerals, and materials are shown in relationship to crystal structure, special processing techniques and solid state devices and assemblies fabricated. This publication also presents a number of organic materials which are widely used in handling and general processing...waxes, plastics, and lacquers for example. It is useful to individuals involved in study, development, and processing of metals and metallic compounds. It is invaluable for readers from the college level to industrial R & D and full-scale device fabrication, testing and sales. Scientific disciplines, work areas and individuals with great interest include: chemistry, physics, metallurgy, geology, solid state, ceramic and glass, research libraries, individuals dealing with chemical processing of inorganic materials, societies and schools.

Lectures on Materials Science for Architectural Conservation

Lectures on Materials Science for Architectural Conservation PDF

Author: Giorgio Torraca

Publisher:

Published: 2009-12-01

Total Pages: 204

ISBN-13: 9780982766828

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This book is based on Dr. Torraca's 2002 publication, Lezioni di scienza e tecnologia dei materiali per restauro dei monumenti. The English-language Lectures includes new and updated material. An excellent resource for architectural conservators, engineers, and conservation scientists.

Numerical Modeling of AAR

Numerical Modeling of AAR PDF

Author: Victor Saouma

Publisher: CRC Press

Published: 2014-02-05

Total Pages: 326

ISBN-13: 0415636973

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This reference book presents the theory and methodology to conduct a finite element assessment of concrete structures subjected to chemically induced volumetric expansion in general and alkali aggregate reaction in particular. It is limited to models developed by the author, and focuses on how to best address a simple question: if a structure suffers from AAR, how is its structural integrity jeopardized, and when would the reaction end. Subjects treated are: • Brief overview of AAR: nature of the chemical reactions, AAR in both dams and nuclear power plants, and how does it impact the mechanical properties of concrete. • Constitutive model for both the AAR expansion, and concrete nonlinearities (both smeared and discrete crack models). • Validation of the model along with a parametric study to assess what are the critical parameters in a study. • Selection of material properties for an AAR finite element simulation, followed by applications in dams and massive reinforced concrete structures. • Micro Model for improved understanding of the essence of the reaction, along with a newly proposed mathematical model for the kinetics of the reaction. • Review of relevant procedures to estimate the residual expansion of a structure suffering from AAR, along with a proposed approach to determine when the reaction will end. The book is extensively illustrated with numerous figures and provides guidance to engineers confronted with swelling in concrete infrastructures.