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Classical Thermodynamics of Fluid Systems

Author: Juan H. Vera

Publisher: CRC Press

Published: 2016-11-25

Total Pages: 438

ISBN-13: 1315399059

This text explores the connections between different thermodynamic subjects related to fluid systems. Emphasis is placed on the clarification of concepts by returning to the conceptual foundation of thermodynamics and special effort is directed to the use of a simple nomenclature and algebra. The book presents the structural elements of classical thermodynamics of fluid systems, covers the treatment of mixtures, and shows via examples and references both the usefulness and the limitations of classical thermodynamics for the treatment of practical problems related to fluid systems. It also includes diverse selected topics of interest to researchers and advanced students and four practical appendices, including an introduction to material balances and step-by-step procedures for using the Virial EOS and the PRSV EOS for fugacities and the ASOG-KT group method for activity coefficients. The Olivera-Fuentes table of PRSV parameters for more than 800 chemical compounds and the Gmehling-Tochigi tables of ASOG interaction parameters for 43 groups are included.

Classical and Molecular Thermodynamics of Fluid Systems

Author: Claudio Olivera-Fuentes

Publisher:

Published: 2024-10-24

Total Pages: 0

ISBN-13: 9781032557342

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"There are many good books of classical and molecular thermodynamics, some more suitable for teaching, some for research purposes, some focusing more on fundamentals and others more on applications. The book "Classical and Molecular Thermodynamics of Fluid Systems: Principles and Applications" is a new and significantly revised version of the book of a similar title by professor Juan H. Vera and Dr. Grazyna Wilczek-Vera. This new edition, now co-authored by four very experienced academics, is extended to include "molecular" as well as classical thermodynamics as well as applications and special topics covering a wider range of mixtures and models"--

Molecular Thermodynamics of Fluid-Phase Equilibria

Author: John M. Prausnitz

Publisher: Pearson Education

Published: 1998-10-22

Total Pages: 1149

ISBN-13: 0132440504

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The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

The Thermodynamics of Fluid Systems

Author: Leslie Colin Woods

Publisher: Oxford University Press, USA

Published: 1985

Total Pages: 388

ISBN-13:

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This classic account stresses the role of time-scales in determining the nature and extent of state space, an approach that makes clear the unity of classical, kinetic, statistical, and process thermodynamics. "Superb....It has no equal....Should be read by anyone who wants to understand what thermodynamics--regarded as a branch of physics--is all about....No one concerned with thermodynamics, and not merely that of fluid systems, can afford to be without this book, be he undergraduate student, graduate student or research worker." --Journal of Fluid Mechanics/

Molecular Thermodynamics of Fluid-phase Equilibria

Author: J. M. Prausnitz

Publisher: Prentice Hall

Published: 1969

Total Pages: 556

ISBN-13:

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97774-4 The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics ofFluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and oth

Lectures in Classical Thermodynamics with an Introduction to Statistical Mechanics

Author: Daniel Blankschtein

Publisher: Springer Nature

Published: 2021-03-15

Total Pages: 758

ISBN-13: 3030491986

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This textbook facilitates students’ ability to apply fundamental principles and concepts in classical thermodynamics to solve challenging problems relevant to industry and everyday life. It also introduces the reader to the fundamentals of statistical mechanics, including understanding how the microscopic properties of atoms and molecules, and their associated intermolecular interactions, can be accounted for to calculate various average properties of macroscopic systems. The author emphasizes application of the fundamental principles outlined above to the calculation of a variety of thermodynamic properties, to the estimation of conversion efficiencies for work production by heat interactions, and to the solution of practical thermodynamic problems related to the behavior of non-ideal pure fluids and fluid mixtures, including phase equilibria and chemical reaction equilibria. The book contains detailed solutions to many challenging sample problems in classical thermodynamics and statistical mechanics that will help the reader crystallize the material taught. Class-tested and perfected over 30 years of use by nine-time Best Teaching Award recipient Professor Daniel Blankschtein of the Department of Chemical Engineering at MIT, the book is ideal for students of Chemical and Mechanical Engineering, Chemistry, and Materials Science, who will benefit greatly from in-depth discussions and pedagogical explanations of key concepts. Distills critical concepts, methods, and applications from leading full-length textbooks, along with the author’s own deep understanding of the material taught, into a concise yet rigorous graduate and advanced undergraduate text; Enriches the standard curriculum with succinct, problem-based learning strategies derived from the content of 50 lectures given over the years in the Department of Chemical Engineering at MIT; Reinforces concepts covered with detailed solutions to illuminating and challenging homework problems.

Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition

Author: Berkeley John M. Prausnitz - University of California

Publisher:

Published: 1998

Total Pages: 864

ISBN-13:

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Applied Statistical Thermodynamics

Author: Klaus Lucas

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 529

ISBN-13: 3662016486

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The book guides the reader from the foundations of statisti- cal thermodynamics including the theory of intermolecular forces to modern computer-aided applications in chemical en- gineering and physical chemistry. The approach is new. The foundations of quantum and statistical mechanics are presen- ted in a simple way and their applications to the prediction of fluid phase behavior of real systems are demonstrated. A particular effort is made to introduce the reader to expli- cit formulations of intermolecular interaction models and to show how these models influence the properties of fluid sy- stems. The established methods of statistical mechanics - computer simulation, perturbation theory, and numerical in- tegration - are discussed in a style appropriate for newcom- ers and are extensively applied. Numerous worked examples illustrate how practical calculations should be carried out.

Molecular Thermodynamics and Transport Phenomena

Author: Michael H. Peters

Publisher: McGraw Hill Professional

Published: 2005-03-07

Total Pages: 194

ISBN-13: 0071588906

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Many newly developing fields of science and engineering, including nanotechnology, protein engineering, microfluidics, etc., require an in-depth molecular understanding and description of matter. Molecular Thermodynamics and Transport Phenomena: Complexities of Scales in Space and Time provides a rigorous molecular and statistical mechanical basis for the classical fundamental molecular description of matter. The author uniquely explores the disparities in spatial and temporal time scales in molecular mechanical dynamics and interactions that lead to the different observed behavior of matter, including equilibrium vs. nonequilibrium behavior, phase states, and irreversibility. This book provides a modern, comprehensive foundation for the classical molecular theory of matter that is demanded of today’s advancing fields of science and technology.

Molecular Thermodynamics of Complex Systems

Author: Xiaohua Lu

Publisher: Springer Science & Business Media

Published: 2009

Total Pages: 282

ISBN-13: 3540691146

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In Molecular Thermodynamics of Complex Systems, the chapter authors critically examine not only the current state of the art in chemical research into structure and bonding, but also look at the direction the subject might take as it develops in future years.