Classical and Geometrical Theory of Chemical and Phase Thermodynamics

Classical and Geometrical Theory of Chemical and Phase Thermodynamics PDF

Author: Frank Weinhold

Publisher: John Wiley & Sons

Published: 2009-02-17

Total Pages: 506

ISBN-13: 0470435054

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Because it is grounded in math, chemical thermodynamics is often perceived as a difficult subject and many students are never fully comfortable with it. The first authoritative textbook presentation of equilibrium chemical and phase thermodynamics in a reformulated geometrical framework, Chemical and Phase Thermodynamics shows how this famously difficult subject can be accurately expressed with only elementary high-school geometry concepts. Featuring numerous suggestions for research-level extensions, this simplified alternative to standard calculus-based thermodynamics expositions is perfect for undergraduate and beginning graduate students as well as researchers.

Principles Of Classical Thermodynamics: Applied To Materials Science

Principles Of Classical Thermodynamics: Applied To Materials Science PDF

Author: Didier De Fontaine

Publisher: World Scientific

Published: 2019-06-04

Total Pages: 390

ISBN-13: 9813222700

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The aim of this book is to present Classical Thermodynamics in a unified way, from the most fundamental principles to non-uniform systems, thereby requiring the introduction of coarse graining methods, leading for instance to phase field methods. Solutions thermodynamics and temperature-concentration phase diagrams are covered, plus also a brief introduction to statistical thermodynamics and topological disorder. The Landau theory is included along with a general treatment of multicomponent instabilities in various types of thermodynamic applications, including phase separation and order-disorder transitions. Nucleation theory and spinodal decomposition are presented as extreme cases of a single approach involving the all-important role of fluctuations.In this way, it is hoped that this coverage will reconcile in a unified manner techniques generally presented separately in physics and materials texts.

Mesoscopic Thermodynamics for Scientists and Engineers

Mesoscopic Thermodynamics for Scientists and Engineers PDF

Author: Mikhail A. Anisimov

Publisher: John Wiley & Sons

Published: 2024-07-02

Total Pages: 340

ISBN-13: 1394241968

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Provides comprehensive coverage of the fundamentals of mesoscopic thermodynamics Mesoscopic Thermodynamics for Scientists and Engineers presents a unified conceptual approach to the core principles of equilibrium and nonequilibrium thermodynamics. Emphasizing the concept of universality at the mesoscale, this authoritative textbook provides the knowledge required for understanding and utilizing mesoscopic phenomena in a wide range of new and emerging technologies. Divided into two parts, Mesoscopic Thermodynamics for Scientists and Engineers opens with a concise summary of classical thermodynamics and nonequilibrium thermodynamics, followed by a detailed description of fluctuations and local (spatially-dependent) properties. Part II presents a universal approach to specific meso-heterogeneous systems, illustrated by numerous examples from experimental and computational studies that align with contemporary research and engineering practice. Bridges the gap between conventional courses in thermodynamics and real-world practice Provides in-depth instruction on applying thermodynamics to current problems involving meso- and nano-heterogeneous systems Contains a wealth of examples of simple and complex fluids, polymers, liquid crystals, and supramolecular equilibrium and dissipative structures Includes practical exercises and references to textbooks, monographs, and journal articles in each chapter Mesoscopic Thermodynamics for Scientists and Engineers is an excellent textbook for advanced undergraduate and graduate students in physics, chemistry, and chemical, mechanical, and materials science engineering, as well as an invaluable reference for engineers and researchers engaged in soft-condensed matter physics and chemistry, nanoscience and nanotechnology, and mechanical, chemical, and biomolecular engineering.

A New Perspective on Thermodynamics

A New Perspective on Thermodynamics PDF

Author: Bernard H. Lavenda

Publisher: Springer

Published: 2009-11-25

Total Pages: 207

ISBN-13: 1441914307

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This book introduces a new outlook on thermodynamics. It brings the theory up to the present time and indicates areas of further development with the union of information theory and the theory of means and their inequalities.

Many-Electron Approaches in Physics, Chemistry and Mathematics

Many-Electron Approaches in Physics, Chemistry and Mathematics PDF

Author: Volker Bach

Publisher: Springer

Published: 2014-07-01

Total Pages: 410

ISBN-13: 3319063790

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This book provides a broad description of the development and (computational) application of many-electron approaches from a multidisciplinary perspective. In the context of studying many-electron systems Computer Science, Chemistry, Mathematics and Physics are all intimately interconnected. However, beyond a handful of communities working at the interface between these disciplines, there is still a marked separation of subjects. This book seeks to offer a common platform for possible exchanges between the various fields and to introduce the reader to perspectives for potential further developments across the disciplines. The rapid advances of modern technology will inevitably require substantial improvements in the approaches currently used, which will in turn make exchanges between disciplines indispensable. In essence this book is one of the very first attempts at an interdisciplinary approach to the many-electron problem.

Classical Thermodynamics of Fluid Systems

Classical Thermodynamics of Fluid Systems PDF

Author: Juan H. Vera

Publisher: CRC Press

Published: 2016-11-25

Total Pages: 438

ISBN-13: 1315399059

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This text explores the connections between different thermodynamic subjects related to fluid systems. Emphasis is placed on the clarification of concepts by returning to the conceptual foundation of thermodynamics and special effort is directed to the use of a simple nomenclature and algebra. The book presents the structural elements of classical thermodynamics of fluid systems, covers the treatment of mixtures, and shows via examples and references both the usefulness and the limitations of classical thermodynamics for the treatment of practical problems related to fluid systems. It also includes diverse selected topics of interest to researchers and advanced students and four practical appendices, including an introduction to material balances and step-by-step procedures for using the Virial EOS and the PRSV EOS for fugacities and the ASOG-KT group method for activity coefficients. The Olivera-Fuentes table of PRSV parameters for more than 800 chemical compounds and the Gmehling-Tochigi tables of ASOG interaction parameters for 43 groups are included.

Molecular Thermodynamics of Fluid-Phase Equilibria

Molecular Thermodynamics of Fluid-Phase Equilibria PDF

Author: John M. Prausnitz

Publisher: Pearson Education

Published: 1998-10-22

Total Pages: 1149

ISBN-13: 0132440504

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The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

Fundamentals of Classical Statistical Thermodynamics

Fundamentals of Classical Statistical Thermodynamics PDF

Author: Denis James Evans

Publisher: John Wiley & Sons

Published: 2016-04-21

Total Pages: 224

ISBN-13: 3527695761

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Both a comprehensive overview and a treatment at the appropriate level of detail, this textbook explains thermodynamics and generalizes the subject so it can be applied to small nano- or biosystems, arbitrarily far from or close to equilibrium. In addition, nonequilibrium free energy theorems are covered with a rigorous exposition of each one. Throughout, the authors stress the physical concepts along with the mathematical derivations. For researchers and students in physics, chemistry, materials science and molecular biology, this is a useful text for postgraduate courses in statistical mechanics, thermodynamics and molecular simulations, while equally serving as a reference for university teachers and researchers in these fields.

Sustainable Utility Systems

Sustainable Utility Systems PDF

Author: Petar Sabev Varbanov

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2020-12-07

Total Pages: 431

ISBN-13: 3110630133

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This book provides a thorough guidance on maximizing the performance of utility systems in terms of sustainability. It covers general structure, typical components and efficiency trends, and applications such as top-level analysis for steam pricing and selection of processes for improved heat integration. Examples are provided to illustrate the discussed models and methods to give sufficient learning experience for the reader.

Modern Thermodynamics

Modern Thermodynamics PDF

Author: Jitao Wang

Publisher: Springer Science & Business Media

Published: 2011-10-15

Total Pages: 290

ISBN-13: 3642113494

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"Modern Thermodynamics- Based on the Extended Carnot Theorem" provides comprehensive definitions and mathematical expressions of both classical and modern thermodynamics. The goal is to develop the fundamental theory on an extended Carnot theorem without incorporating any extraneous assumptions. In particular, it offers a fundamental thermodynamic and calculational methodology for the synthesis of low-pressure diamonds. It also discusses many "abnormal phenomena", such as spiral reactions, cyclic reactions, chemical oscillations, low-pressure carat-size diamond growth, biological systems, and more. The book is intended for chemists and physicists working in thermodynamics, chemical thermodynamics, phase diagrams, biochemistry and complex systems, as well as graduate students in these fields. Jitao Wang is a professor emeritus at Fudan University, Shanghai, China.