Chirality and Optical Activity in Organometallic Compounds

Chirality and Optical Activity in Organometallic Compounds PDF

Author: Vi͡acheslav Ivanovich Sokolov

Publisher: Routledge

Published: 1990

Total Pages: 168

ISBN-13:

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This book presents introductory material concerning the classification of both types of chirality and organometallic molecules. It outlines the modern quantum-chemical treatment of the phenomenon of optical activity, special attention being paid to the organometal molecules studied by circular dichroism spectroscopy. It also describes the synthesis and reactivity of chiral and optically active organometallic compounds and discusses their applications in synthesizing complex organic molecules.

Chirality in Transition Metal Chemistry

Chirality in Transition Metal Chemistry PDF

Author: Hani Amouri

Publisher: John Wiley & Sons

Published: 2008-11-20

Total Pages: 260

ISBN-13: 047072160X

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Chirality in Transition Metal Chemistry is an essential introduction to this increasingly important field for students and researchers in inorganic chemistry. Emphasising applications and real-world examples, the book begins with an overview of chirality, with a discussion of absolute configurations and system descriptors, physical properties of enantiomers, and principles of resolution and preparation of enantiomers. The subsequent chapters deal with the the specifics of chirality as it applies to transition metals. Some reviews of Chirality in Transition Metal Chemistry "...useful to students taking an advanced undergraduate course and particularly to postgraduates and academics undertaking research in the areas of chiral inorganic supramolecular complexes and materials." Chemistry World, August 2009 “...the book offers an extremely exciting new addition to the study of inorganic chemistry, and should be compulsory reading for students entering their final year of undergraduate studies or starting a Ph.D. in structural inorganic chemistry.” Applied Organometallic Chemistry Volume 23, Issue 5, May 2009 “...In conclusion the book gives a wonderful overview of the topic. It is helpful for anyone entering the field through systematic and detailed introduction of basic information. It was time to publish a new and topical text book covering the important aspect of coordination chemistry. It builds bridges between Inorganic, organic and supramolecular chemistry. I can recommend the book to everybody who is interested in the chemistry of chiral coordination compounds .” Angew. chem. Volume 48, Issue 18, April 2009 About the Series Chirality in Transition Metal Chemistry is the latest addition to the Wiley Inorganic Chemistry Advanced Textbook series. This series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry.

Chirotechnology

Chirotechnology PDF

Author: Roger A. Sheldon

Publisher: CRC Press

Published: 1993-05-27

Total Pages: 456

ISBN-13: 9780824791438

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This reference provides an introduction to the phenomenon of chirality and its importance in conjunction with biological activity and offers an easy-to-read examination of practical, industrially relevant methods for the synthesis of optically active compounds.;Furnishing hands-on guidelines for the development of economically viable synthetic compounds, Chirotechnology: explains optical isomerism and stereochemistry; gives a general overview of various methods of synthesis; supplies detailed explications of specific techniques, including fermentation, crystallization, the chirality pool, enzymatic methods, and catalytic asymmetric synthesis; illustrates and compares approaches with examples taken directly from industry such as the synthesis of pharmaceuticals, agrochemicals, flavours, and fragrances; and clarifies the importance of determining which approach to use for the synthesis of particular molecules.;With over 1100 literature citations, tables and figures, Chirotechnology is a reference for chemical engineers; industrial, organic and medicinal chemists; and bioprocess technologists, as well as a text for upper-level undergraduate, graduate and continuing-education students in these disciplines.

Stereochemistry

Stereochemistry PDF

Author: M. Nógrádi

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 300

ISBN-13: 1483278654

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Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.

Vibrational Optical Activity

Vibrational Optical Activity PDF

Author: Laurence A. Nafie

Publisher: John Wiley & Sons

Published: 2011-07-12

Total Pages: 373

ISBN-13: 1119977533

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This unique book stands as the only comprehensive introduction to vibrational optical activity (VOA) and is the first single book that serves as a complete reference for this relatively new, but increasingly important area of molecular spectroscopy. Key features: A single-source reference on this topic that introduces, describes the background and foundation of this area of spectroscopy. Serves as a guide on how to use it to carry out applications with relevant problem solving. Depth and breadth of the subject is presented in a logical, complete and progressive fashion. Although intended as an introductory text, this book provides in depth coverage of this topic relevant to both students and professionals by taking the reader from basic theory through to practical and instrumental approaches.

Chirality at the Nanoscale

Chirality at the Nanoscale PDF

Author: David B. Amabilino

Publisher: John Wiley & Sons

Published: 2009-02-11

Total Pages: 380

ISBN-13: 3527625356

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The only standard reference in this exciting new field combines the physical, chemical and material science perspectives in a synergic way. This monograph traces the development of the preparative methods employed to create nanostructures, in addition to the experimental techniques used to characterize them, as well as some of the surprising physical effects. The chapters cover every category of material, from organic to coordination compounds, metals and composites, in zero, one, two and three dimensions. The book also reviews structural, chemical, optical, and other physical properties, finishing with a look at the future for chiral nanosystems.

The Molecule as Meme

The Molecule as Meme PDF

Author: Jeffrey Huw Williams

Publisher: Morgan & Claypool Publishers

Published: 2018-11-26

Total Pages: 146

ISBN-13: 1643272926

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It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.

Chirality in Industry

Chirality in Industry PDF

Author: A. N. Collins

Publisher:

Published: 1992

Total Pages: 430

ISBN-13:

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Looking at the industrial production of optically active materials, this volume deals with "classical", non-biological resolutions to problems; biological methods (both resolution and asymmetric synthesis); non-biological asymmetric synthesis; immobilization and membrane technologies.