Chemical Dynamics at Low Temperatures, Volume 88

Chemical Dynamics at Low Temperatures, Volume 88 PDF

Author: Victor A. Benderskii

Publisher: John Wiley & Sons

Published: 2009-09-09

Total Pages: 400

ISBN-13: 0470142006

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The first unified treatment of experimental and theoreticaladvances in low-temperature chemistry Chemical Dynamics at LowTemperatures is a landmark publication. For the first time, thecumulative results of twenty years of experimental and theoreticalresearch into low-temperature chemistry have been collected andpresented in a unified treatment. The result is a text/referencethat both offers an overview of the subject and contains sufficientdetail to guide practicing researchers toward fertile ground forfuture research. Topics covered include: * Developmental history * Formulation of general problems and the main approximations usedto solve them * Specific features of tunneling chemical dynamics * One-dimensional tunneling in the path integral formalism * Special problems of two- and multidimensional tunneling * An extended presentation of pertinent experimental results

Chemical Dynamics at Low Temperatures, Volume 88

Chemical Dynamics at Low Temperatures, Volume 88 PDF

Author: Ilya Prigogine

Publisher: Wiley-Interscience

Published: 1958

Total Pages: 406

ISBN-13:

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The first unified treatment of experimental and theoretical advances in low-temperature chemistry Chemical Dynamics at Low Temperatures is a landmark publication. For the first time, the cumulative results of twenty years of experimental and theoretical research into low-temperature chemistry have been collected and presented in a unified treatment. The result is a text/reference that both offers an overview of the subject and contains sufficient detail to guide practicing researchers toward fertile ground for future research. Topics covered include: Developmental history Formulation of general problems and the main approximations used to solve them Specific features of tunneling chemical dynamics One-dimensional tunneling in the path integral formalism Special problems of two- and multidimensional tunneling An extended presentation of pertinent experimental results

Low Temperatures and Cold Molecules

Low Temperatures and Cold Molecules PDF

Author: Ian W. M. Smith

Publisher: Imperial College Press

Published: 2008

Total Pages: 578

ISBN-13: 1848162103

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This book brings together, for the first time, the results of recent research in areas ranging from the chemistry of cold interstellar clouds (10-20 K), through laboratory studies of the spectroscopy and kinetics of ions, radicals and molecules, to studies of molecules in liquid helium droplets, to attempts to create molecular (as distinct from atomic) Bose-Einstein condensates.

Modern Methods for Multidimensional Dynamics Computations in Chemistry

Modern Methods for Multidimensional Dynamics Computations in Chemistry PDF

Author: Donald Leo Thompson

Publisher: World Scientific

Published: 1998

Total Pages: 764

ISBN-13: 9789810233426

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This volume describes many of the key practical theoretical techniques that have been developed to treat chemical dynamics problems in many-atom systems. It contains thorough treatments of fundamental theory and prescriptions for performing computations. The selection of methods, ranging from gas phase bimolecular reactions to complex processes in condensed phases, reflects the breadth of the field.The book is an excellent reference for proven and accepted methods as well as for theoretical approaches that are still being developed. It is appropriate for graduate students and other ?novices? who wish to begin working in chemical dynamics as well as active researchers who wish to acquire a wider knowledge of the field.

Cities and Their Vital Systems

Cities and Their Vital Systems PDF

Author: Advisory Committee on Technology and Society

Publisher: National Academies Press

Published: 1989

Total Pages: 1298

ISBN-13: 9780309037860

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Cities and Their Vital Systems asks basic questions about the longevity, utility, and nature of urban infrastructures; analyzes how they grow, interact, and change; and asks how, when, and at what cost they should be replaced. Among the topics discussed are problems arising from increasing air travel and airport congestion; the adequacy of water supplies and waste treatment; the impact of new technologies on construction; urban real estate values; and the field of "telematics," the combination of computers and telecommunications that makes money machines and national newspapers possible.

Thermal Fluctuations And Relaxation Processes In Nanomagnets

Thermal Fluctuations And Relaxation Processes In Nanomagnets PDF

Author: William T Coffey

Publisher: World Scientific

Published: 2020-05-21

Total Pages: 709

ISBN-13: 9811217297

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Presenting in a coherent and accessible fashion current results in nanomagnetism, this book constitutes a comprehensive, rigorous and readable account, from first principles of the classical and quantum theories underlying the dynamics of magnetic nanoparticles subject to thermal fluctuations.Starting with the Larmor-like equation for a giant spin, both the stochastic (Langevin) equation of motion of the magnetization and the associated evolution (Fokker-Planck) equation for the distribution function of the magnetization orientations of ferromagnetic nanoparticles (classical spins) in a heat bath are developed along with their solution (using angular momentum theory) for arbitrary magnetocrystalline-Zeeman energy. Thus, observables such as the magnetization reversal time, relaxation functions, dynamic susceptibilities, etc. are calculated and compared with the predictions of classical escape rate theory including in the most general case spin-torque-transfer. Regarding quantum effects, which are based on the reduced spin density matrix evolution equation in Hilbert space as is described at length, they are comprehensively treated via the Wigner-Stratonovich formulation of the quantum mechanics of spins via their orientational quasi-probability distributions on a classically meaningful representation space. Here, as suggested by the relevant Weyl symbols, the latter is the configuration space of the polar angles. Hence, one is led, by mapping the reduced density matrix equation onto that space, to a master equation for the quasi-probability evolution akin to the Fokker-Planck equation which may be solved in a similar way. Thus, one may study in a classical-like manner the evolution of observables with spin number ranging from an elementary spin to molecular clusters to the classical limit, viz. a nanoparticle. The entire discussion hinges on the one-to-one correspondence between polarization operators in Hilbert space and the spherical harmonics allied to concepts of spin coherent states long familiar in quantum optics.Catering for the reader with only a passing knowledge of statistical and quantum mechanics, the book serves as an introductory text on a complicated subject where the literature is remarkably sparse.