Arsenic and Old Mustard: Chemical Problems in the Destruction of Old Arsenical and `Mustard' Munitions

Arsenic and Old Mustard: Chemical Problems in the Destruction of Old Arsenical and `Mustard' Munitions PDF

Author: J.F. Bunnett

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 217

ISBN-13: 9401591156

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More than ten million `poison gas' shells, mortar bombs, etc., lie hidden in Europe, many of them relics from World War I. Some were fired and failed to detonate, others were abandoned in old ammunition dumps. Most retain their load of chemical warfare (CW) agents. They are turned up daily in the course of farming and construction. Many European nations have permanent departments concerned with their collection and destruction. Old munitions, when discovered, are usually heavily corroded and difficult to identify. Is it a CW munition? Or an explosive? If CW, what agent does it contain? Once identified, one has to select a destruction method. Some of the methods that have been proposed are less than perfect, and are often complicated by the presence of extraneous chemicals, either mixed with the CW agents during manufacture or formed over decades in the ground. Of particular interest are the insiders' reports on the German CW programmes of both World Wars, and the current status of Russian chemical armaments.

Evaluation of Alternative Technologies for Disposal of Liquid Wastes from the Explosive Destruction System

Evaluation of Alternative Technologies for Disposal of Liquid Wastes from the Explosive Destruction System PDF

Author: National Research Council

Publisher: National Academies Press

Published: 2002-01-20

Total Pages: 76

ISBN-13: 0309082692

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Chemical warfare materiel (CWM) encompasses diverse items that were used during 60 years of efforts by the United States to develop a capability for conducting chemical warfare. Non-Stockpile CWM (NSCWM) is materiel not included in the current U.S. inventory of chemical munitions and includes buried materiel, recovered materiel, components of binary chemical weapons, former production facilities, and miscellaneous materiel. Because NSCWM is stored or buried at many locations, the Army is developing transportable treatment systems that can be moved from site to site as needed. Originally, the Army planned to develop three transportable treatment systems for nonstockpile chemical materiel: the rapid response system (RRS), the munitions management device (MMD), and the explosive destruction system (EDS). This report supplements an earlier report that evaluated eight alternative technologies for destruction of the liquid waste streams from two of the U.S. Army's transportable treatment systems for nonstockpile chemical materiel: the RRS and the MMD. This report evaluates the same technologies for the destruction of liquid waste streams produced by the EDS and discusses the regulatory approval issues and obstacles for the combined use of the EDS and the alternative technologies that treat the EDS secondary waste streams. Although it focuses on the destruction of EDS neutralent, it also takes into consideration the ability of posttreatment technologies to process the more dilute water rinses that are used in the EDS following treatment with a reagent.

Is Arsenic an Aphrodisiac?

Is Arsenic an Aphrodisiac? PDF

Author: William R Cullen

Publisher: Royal Society of Chemistry

Published: 2008-04-22

Total Pages: 429

ISBN-13: 1847558607

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Sex, drugs, rocks, gold, murder, war, mass poisonings, the deaths of Napoleon, Tchaikovsky, Mozart, and others are all linked by one element - arsenic! Arsenic has been around since the beginning of time and the word has become a metaphor for poison with associated shock value. The general public are fearful of any possible exposure to it and yet it holds a certain dark and eerie fascination! The average person has only one idea about arsenic - it is poison - and this reputation has a sound base. Some arsenic compounds are very toxic and have been used with criminal intent from the time of the ancient Romans to the present day. Up until now, there has been no book that covers arsenic with such breadth. This book is a general appreciation of how much the element, arsenic, has become part of our lives in an entertaining style covering the years 1000 BC to the present day. The coverage of the chemistry, toxicology, and medicinal aspects is deliberately kept at a level for the general reader to understand. It covers the way in which this ubiquitous element and its compounds have influenced the lives of the people of the world. The author's objective in writing this book was not to elaborate on the vast chemistry of the element, but to try to reveal to the general reader how the element and its compounds have become embedded in our social fabric, for good and for ill. No other element comes close in this regard and he uses the word sociochemistry to describe this interface between society and chemistry. The book covers a broad range of topics including the use of arsenic in human medicine in many cultures from Chinese medicine to the beginning of chemotherapy. This peaked in the western world in the early 20th century, with Ehrlich's discovery of salvarsan, an arsenic-based cure for syphilis that gave rise to the field of chemotherapy. Salvarsan and related compounds were eventually displaced by antibiotics such as penicillin. Arsenic trioxide has staged a comeback, however, and is being used as a successful treatment for a form of leukemia. Other chapters cover arsenic compounds which were widely used in agriculture and wood preservation during the 20th century and their associated myths as well as arsenic compounds as chemical warfare agents and the resulting stockpile. The topic of arsenic in the environment is discussed in depth - arsenic is all around us - in our soil, our water, and our food, and our bodies have adapted to its presence and it does not usually pose a problem. However, the natural presence of high concentrations of arsenic in drinking water currently threatens the lives of millions of people in India, Bangladesh, Mexico and elsewhere. It also covers mining and pesticide manufacturing which can lead to high local arsenic concentrations in soils, slag heaps and mine tailings which, when located close to human activities, can produce human health risks. Other chapters cover a variety of topics including: " A proposed connection between arsenic and Cot Death (SIDS) which caused panic " The high concentration of arsenic in kelp products-is this harmful? " What about the 237,000 tonnes of arsenic trioxide stored in a mine in Canada? " How toxic is arsenic anyway, and how do you assess the risks of exposure? " How did Napoleon die? These and many other topics are addressed at a level that will result in understanding without delving into too much technical detail or requiring a degree in chemistry. Essential reading for everyone with a general interest in science, this illuminating text covers a broad range of topics.

Chemical Warfare Agents

Chemical Warfare Agents PDF

Author: Brian J. Lukey

Publisher: CRC Press

Published: 2019-04-11

Total Pages: 1197

ISBN-13: 0429631472

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The first edition of this book, Chemical Warfare Agents: Toxicity at Low Levels, was published just prior to the terrorist attacks of September 11, 2001. The second edition titled, Chemical Warfare Agents: Pharmacology, Toxicology, and Therapeutics, included new epidemiological and clinical studies of exposed or potentially exposed populations; new treatment concepts and products; improved organization of the national response apparatus addressing the potential for CWA terrorism; and improved diagnostic tests that enable rapid diagnosis and treatment. Since the second edition, the chemical warfare agent community has worked hard to advance research for protection and treatment and develop/improve response approaches for individuals and definitive care. Consequently, in addition to updating previous chapters, Chemical Warfare Agents: Biomedical and Psychological Effects, Medical Countermeasures, and Emergency Response, Third Edition features several new chapters that address the Syrian War, chemical destruction, the Organisation for the Prohibition of Chemical Weapons, biomarkers for chemical warfare agent exposure, field sensors, aircraft decontamination, lung/human on a chip, chemical warfare response decision making, and other research advancements. Features: Describes the newest medical interventions, and the latest technologies deployed in the field, as well as developments in the international response to CW usage highlighting recent events in the Middle East Discusses the latest in organizational/interagency partitioning in terms of responsibilities for emergency response, not just in the United States but at the international level—whether prevention, mitigation, medical care, reclamation, or medico-legal aspects of such response Contains the most current research from bench-level experts The third edition contains the most up-to-date and comprehensive coverage of the question of chemical warfare agent employment on the battlefield or in terrorism. Edited by workers that have been in the field for 35+ years, it remains faithful to the scientific "constants," while evaluating and crediting the advances by the industry that have made us safer.

Review of the Army Non-Stockpile Chemical Materiel Disposal Program

Review of the Army Non-Stockpile Chemical Materiel Disposal Program PDF

Author: National Research Council

Publisher: National Academies Press

Published: 2000-01-03

Total Pages: 149

ISBN-13: 0309068797

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This study is a review and evaluation of the U.S. Army's Report to Congress on Alternative Approaches for the Treatment and Disposal of Chemical Agent Identification Sets (CAIS). CAIS are test kits that were used to train soldiers from 1928 to 1969 in defensive responses to a chemical attack. They contain samples of chemicals that had been or might have been used by opponents as chemical warfare agents. The Army's baseline approach for treating and disposing of CAIS has been to develop a mobile treatment system, called the Rapid Response System (RRS), which can be carried by several large over-the-road trailers.

Environmental Consequences of War and Aftermath

Environmental Consequences of War and Aftermath PDF

Author: Tarek A. Kassim

Publisher: Springer

Published: 2009-03-24

Total Pages: 332

ISBN-13: 3540879633

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and used in munitions. Rather the requirements for the agent’s military effects took precedence. In addition, the interaction among the political, technical, and legal challenges connected with the known or possible risks posed by CW agents is complex and sometimes not well understood. This is usually because technical considerations, when acted on, are almost invariably informed by political ones, such as various legal requirements. The book contains nine chapters covering different aspects of the research on environmental consequences of war and its aftermath and covers in one additional chapter more general issues such as prevention of war and its environmental c- sequences, the legal, political, and technical background to selected environmental and human health effects of CW agents, and the atmospheric transport and depo- tion of persistent organic pollutants under warfare conditions to more specific ones related to two main tragic examples: the war in the Balkans and the Gulf War. Aspects of the war in the Balkans cover contamination by heavy metals in Serbian national parks, the impact of NATO strikes on the Danube river basin, and the problems associated with transuranium elements. The Gulf War in Kuwait covers other problems related to the impact of oil contamination, the impact on grou- water resources, and the soil damage of ground fortifications among other envir- mental and health problems.

Historical Dictionary of Nuclear, Biological, and Chemical Warfare

Historical Dictionary of Nuclear, Biological, and Chemical Warfare PDF

Author: Benjamin C. Garrett

Publisher: Rowman & Littlefield

Published: 2017-08-25

Total Pages: 411

ISBN-13: 1538106841

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The history of biological weapons (BW), chemical weapons (CW), and nuclear weapons is complicated. It can be disturbing, tragic, and occasionally encouraging. It is rarely amusing, although the names selected for certain weapons suggest a casualness toward the consequences of their use: Atomic Annie, Blue Peacock, Dew of Death, Fat Man, Flying cow, George, Gilda, Helen of Bikini, Hurricane, Katie, Little Boy, Lulu, Mike, Red Beard, Sewer Pipe, Squirt. Use of BW and CW in warfare has produced mixed results in terms of effecting the outcome of a battle or campaign; despite this mixed record, both weapon types have attracted intense interest and strong advocacy for further use. The sole experience with use of nuclear weapons in warfare is viewed as hastening surrender by Japan, created competition among nations to develop more such weapons, and influenced efforts to ban any use or even stockpiling of such weapons. Each of these three weapon types has its own peculiar history, as recounted in this dictionary. This second edition of Historical Dictionary of Nuclear, Biological and Chemical Warfare contains a chronology, an introduction, and an extensive bibliography. The dictionary section has over 700 cross-referenced entries onterms related to NBC warfare, ranging from basic descriptions of substances used to details on incidents and episodes where NBC weapons were used, historical events, persons important to NBC warfare, countries where such weapons have been developed or used, and international treaties and treaty-related organizations.

The A to Z of Nuclear, Biological and Chemical Warfare

The A to Z of Nuclear, Biological and Chemical Warfare PDF

Author: Benjamin C. Garrett

Publisher: Scarecrow Press

Published: 2009-09-16

Total Pages: 302

ISBN-13: 0810870401

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Human experience with nuclear, biological, and chemical (NBC) warfare has been limited, especially in comparison to conventional forms of warfare. Our experience with nuclear warfare is confined to a period of less than one week during the end of World War II, when the United States successfully used two nuclear weapons against targets in Japan. The course of biological warfare and modern use of biological weapons are difficult to track owing to the difficulty of differentiating deliberate use from natural outbreaks. However, the keen potential of biological weapons in acts of terror was shown in the mass disruption caused in the fall 2001 experience in the U.S. with the release of anthrax through the American postal system. Chemical weapons have been used in a handful of conflicts since their introduction to modern warfare during World War I, most recently during the Iran-Iraq War during the 1980s. Despite this limited experience, NBC warfare continues to exert a certain fascination among states. The A to Z of Nuclear, Biological, and Chemical Warfare covers the development and use of NBC weapons as well as efforts to limit or control the use of these weapons through a chronology, a bibliography, an introductory essay, and dictionary entries. Over 500 cross-referenced dictionary entries provide a unique selection of terms related to NBC warfare, ranging from basic descriptions of substances used in NBC warfare to details on incidents and episodes where NBC weapons were used. Entries are structured around historical events, persons important to NBC warfare, countries where such weapons have been developed or used, and international treaties and treaty-related organizations.

Advocating Weapons, War, and Terrorism

Advocating Weapons, War, and Terrorism PDF

Author: Ian E. J. Hill

Publisher: Penn State Press

Published: 2018-08-17

Total Pages: 241

ISBN-13: 027108278X

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Technē’s Paradox—a frequent theme in science fiction—is the commonplace belief that technology has both the potential to annihilate humanity and to preserve it. Advocating Weapons, War, and Terrorism looks at how this paradox applies to some of the most dangerous of technologies: population bombs, dynamite bombs, chemical weapons, nuclear weapons, and improvised explosive devices. Hill’s study analyzes the rhetoric used to promote such weapons in the nineteenth and twentieth centuries. By examining Thomas R. Malthus’s Essay on the Principle of Population, the courtroom address of accused Haymarket bomber August Spies, the army textbook Chemical Warfare by Major General Amos A. Fries and Clarence J. West, the life and letters of Manhattan Project physicist Leo Szilard, and the writings of Ted “Unabomber” Kaczynski, Hill shows how contemporary societies are equipped with abundant rhetorical means to describe and debate the extreme capacities of weapons to both destroy and protect. The book takes a middle-way approach between language and materialism that combines traditional rhetorical criticism of texts with analyses of the persuasive force of weapons themselves, as objects, irrespective of human intervention. Advocating Weapons, War, and Terrorism is the first study of its kind, revealing how the combination of weapons and rhetoric facilitated the magnitude of killing in the nineteenth and twentieth centuries, and illuminating how humanity understands and acts upon its propensity for violence. This book will be invaluable for scholars of rhetoric, scholars of science and technology, and the study of warfare.